全文获取类型
收费全文 | 187篇 |
免费 | 11篇 |
国内免费 | 2篇 |
专业分类
化学 | 111篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 73篇 |
物理学 | 13篇 |
出版年
2023年 | 3篇 |
2022年 | 7篇 |
2021年 | 11篇 |
2020年 | 12篇 |
2019年 | 14篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 11篇 |
2015年 | 8篇 |
2014年 | 11篇 |
2013年 | 15篇 |
2012年 | 9篇 |
2011年 | 9篇 |
2010年 | 9篇 |
2009年 | 10篇 |
2008年 | 6篇 |
2007年 | 5篇 |
2006年 | 2篇 |
2005年 | 3篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2002年 | 8篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1987年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 4篇 |
排序方式: 共有200条查询结果,搜索用时 31 毫秒
1.
2.
Summary Cold neutrons at the external neutron guide laboratory (ELLA) of the KFA Jülich are used to demonstrate their profitable application
for multielement characterization of biological materials. The set-up and experimental conditions of the Prompt Gamma Cold
Neutron Activation Analysis (PGCNAA) device is described in detail. Results for C, H, N, S, K, B, and Cd using synthetic standards
and the “ratio” technique for calculation are reported for several reference materials and prove the method to be reliable
and complementary with respect to the elements being determined by INAA.
IAEA fellow at the KFA from 6. 3. 91 to 2. 9. 91 on contract No. VIE/9016R. 相似文献
3.
Sofiane Ben Hamouda Quang Trong Nguyen Pierre Schaetzel 《European Polymer Journal》2006,42(11):2994-3005
Ethylene/ethane sorption characteristics were determined for dry Pebax™ (poly(amide 12-block-tetramethylenoxide) copolymer)/AgBF4 membranes by using an electronic microbalance. The membranes containing 0.7 and 22 wt.% AgBF4 showed a dual-mode sorption isotherm. The ethane isotherms for all the membranes were of the Henry-type, which is the normal sorption for gases in rubbery polymers. The abnormal presence of Langmuir sorption sites only for ethylene in the rubbery copolymer, never reported sofar, is attributed to the silver-based specific complexation sites. The silver salt which dissolved in limited amounts in the rubbery copolymer had a much smaller Langmuir sorption capacity than the salt that crystallized in the copolymer. The sorption kinetics indicate that the crystallized salt did adsorb slowly ethylene according to a zeroth-order kinetics, but not ethane. The gas uptake kinetics resulting from a step of the pressure surrounding the copolymer exhibited one stage for ethane but two stages for ethylene. For the latter, there was first a fast Fickian sorption stage, then a drift of the zeroth-order sorption of ethylene on salt crystals, which contributes for a large part to the total uptake. The zeroth-order sorption suggests that the sorbed ethylene amount in the second-stage is independent of the crystal-surface coverage. The value of the Fickian diffusion coefficient calculated by fitting the kinetics with a solution of the second Fick’s law was 5 × 10−12 m2/s for both ethylene (the first stage) and ethane, and is typical for small organic compounds in a rubbery material. 相似文献
4.
Moncef Cossentini Bernard Deschamps Nguyen Trong Anh Jacqueline Seyden-Penne 《Tetrahedron》1977,33(4):409-412
Reaction of phosphonoester 2 and phosphononitrile 3 with chalcone and p-methoxychaleone in THF-t-BuOK at room temperature gives only the product resulting from CC double bond attack. The same reagents with benzalacetone lead to mixture of products resulting from CC double bond and carbonyl attack, though phosphine oxide 4 gives only the products of CC attack. Dypnone gives products of carbonyl attack with 3 and does not react with 2.These results are discussed in terms of perturbation theory: C4 attack increases with delocalization of the reagent's negative charge and lowering of the α-enone LUMO level. 相似文献
5.
A. Ungureanu H. V. Thang D. Trong On E. Dumitriu S. Kaliaguine 《Journal of Thermal Analysis and Calorimetry》2007,87(2):417-422
UL-ZSM-5 materials have been prepared by templated solid-state crystallization of zeolites starting from the amorphous mesostructured aluminosilicate Al-Meso. Microcalorimetry and FTIR have been employed to characterize their surface acidity. In good agreement with 27Al MAS NMR data, UL-ZSM-5 displayed an improved density and strength of Brönsted acid sites, as compared to Al-Meso, owing to the incorporation of aluminium in a tetrahedral environment similar to that of zeolite ZSM-5. Moreover, they showed an enhanced Brönsted/Lewis relative acid ratio. However, Al-Meso showed the highest concentration of strong Lewis acid sites due to its largest amount of aluminium in extraframework positions. 相似文献
6.
Bello-Cruz Yunier Li Guoyin Nghia Tran Thai An 《Journal of Optimization Theory and Applications》2022,194(1):167-190
Journal of Optimization Theory and Applications - In the previous paper Bello-Cruz et al. (J Optim Theory Appl 188:378–401, 2021), we showed that the quadratic growth condition plays a key... 相似文献
7.
8.
A simple and efficient aerobic oxidative dehydrogenation reaction method for the conversion of 2-(alkylthio)-1,4-dihydropyrimidines to 2-(alkylthio)pyrimidines using copper catalyst with no additives, such as an oxidant, acid, or base, has been developed. The reaction was successful with a wide range of 2-(alkylthio)-1,4-dihydropyrimidine substrates. 相似文献
9.
10.