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Ozonolysis of a Series of Methylated Alkenes: Reaction Rate Coefficients and Gas‐Phase Products
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Tristan Braure Véronique Riffault Alexandre Tomas Romeo Iulian Olariu Cecilia Arsene Yuri Bedjanian Patrice Coddeville 《国际化学动力学杂志》2015,47(9):596-605
The gas‐phase ozonolysis of three methylated alkenes, i.e., trans‐2,2‐dimethyl‐3‐hexene (22dM3H), trans‐2,5‐dimethyl‐3‐hexene (25dM3H), and 4‐methyl‐1‐pentene (4M1P), has been investigated in the presence of sufficient hydroxyl radical scavenger in a laminar flow reactor at ambient temperature (296 ± 2 K) and P = 1 atm of dry air (RH ≤ 5%). Ozone levels in the reactor were monitored by an automatic analyzer. Alkene and gas‐phase product concentrations were determined via online sampling either on three‐bed adsorbent cartridges followed by thermodesorption and GC/FID‐MS analysis or on 2,4‐dinitrophenylhydrazine (DNPH) cartridges for subsequent HPLC/UV analysis. Reaction rate coefficients of (3.38 ± 0.12) × 10?17 for 22dM3H and (2.71 ± 0.26) × 10?17 for 25dM3H, both in cm3 molecule?1 s?1 units, have been obtained under pseudo–first‐order conditions. Primary carbonyl products have been identified for the three investigated alkenes, and branching ratios are reported. In the case of 4M1P ozonolysis, the yield of a Criegee intermediate was indirectly determined. Kinetics and product study results are compared to those of literature when available. This work represents the first investigation of reaction products in the ozonolysis of 22dM3H, 25dM3H, and 4M1P in a flow reactor. 相似文献
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J. B. Lewis E. L. Baldeschwieler L. D. Tabern E. F. Shelberg D. Hillis S. Cromer I. F. Bingham S. Givaudon M. Aubert M. R. Moutte A. Andant P. Lambert J. Lecomte J. Tausz H. Wolf B. Gordon W. Dachnow I. Perrier M. Lobunetz M. O. Chaikin C. Engler D. Holde 《Analytical and bioanalytical chemistry》1940,119(7-8):307-310
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R. Grac M. Pugnet J.H. Collet B. Lambert C. De Matos H. L'Haridon A. Le Corre J.O. White 《Superlattices and Microstructures》1997,22(4):505-509
We report new results on the diffraction properties of photoinduced gratings in InGaAs/InGaAsP MQW structures. The original feature of this device is that the QWs are enclosed in an asymmetric Fabry–Perot microcavity in order to increase the diffraction efficiency. We observe oscillations in the diffraction efficiency due to resonant effects in the microcavity. The experimental spectra are compared with theory. Diffraction efficiency at 1.55 μm attains a maximum value of 2.7% at a write beam fluence of 260 μ J cm−2, and then decreases at higher fluences. We explain this phenomenon by an absorption saturation at high excitation. 相似文献
5.
Il Bong Jung Alan Lambert Jan Stochel 《Proceedings of the American Mathematical Society》2004,132(8):2291-2302
The concept of backward extension for subnormal weighted shifts is generalized to arbitrary subnormal operators. Several differences and similarities in these contexts are explored, with emphasis on the structure of the underlying measures.
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Improved quantitation of 13-cis- and all-trans-acitretin in human plasma by normal-phase high-performance liquid chromatography. 总被引:1,自引:0,他引:1
E Meyer W E Lambert A P De Leenheer J P Bersaques A H Kint 《Journal of chromatography. A》1991,570(1):149-156
A reliable analytical method has been developed for measurement of 13-cis- and all-trans-acitretin (Neotigason) in human plasma by normal-phase high-performance liquid chromatography, with ultraviolet detection. Human plasma was obtained after centrifugation of whole blood samples and deproteinized by ethanolic denaturation. After liquid-liquid extraction with water-n-hexane, and aliquot ws chromatographed on a silica column using isocratic elution with n-hexane-methylsalicylate-acetic acid (200:18:0.6, v/v). The wavelength was set at 360 nm, and for plasma samples a limit of quantification of 3-4 ng/ml was obtained. All manipulations were carried out under dim light conditions to prevent photoisomerization. 相似文献
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O. Volkova K. Klimov O. Savelieva N. Tristan E. Goodilin B. Buechner A. Vasiliev 《Journal of magnetism and magnetic materials》2006
Magnetic and transport properties of double distorted perovskites CaCuMn6O12 and CaCu2Mn5O12 are studied in a range 2–300 K. The leading role in magnetism of these compounds belongs to antiferromagnetic exchange interaction of Cu2+ in square coordination with Mn3+/Mn4+ in octahedral coordination. The values of saturation magnetization indicate that Mn3+ ions in square coordination are coupled ferromagnetically with Mn3+/Mn4+ in octahedral coordination. The colossal magnetoresistance in the pellet samples is due assumingly to intergranular spin-polarized tunneling of current carriers. 相似文献
10.
For several physically interesting Calabi-Yau manifolds, we count and parametrize gauge-neutral matter particles occurring in corresponding superstring compactifications. To this end, we use the technique of exact and spectral sequences and then describe and discuss our results in the more familiar tensor notation.Supported by the Robert A. Welch Foundation and the NSF Grant: PHY 8605978. On leave of absence from the Ruder Bokovi Institute, Bijenika 54, YU-41000 Zagreb, Croatia, Yugoslavia 相似文献