Crystallographic report: catena‐Aqua(2,2′‐bipyrimidine)lithium(I) perchlorate

A lithium(I) coordination polymer has been formed from LiClO₄ and the 2,2′‐bipyrimidine (bpym) ligand in which each square pyramidal lithium(I) atom is coordinated in the basal plane by four nitrogen donor atoms derived from two bpym ligands and one water molecule at the apical position. These are connected into a layer structure via hydrogen‐bonding interactions involving the perchlorate anions. Copyright © 2004 John Wiley & Sons, Ltd.     

颗粒增强复合材料热应力分析的双层嵌套模型

建立了一个把增强颗粒球和基体空心球嵌入等效复合介质空腔中的“双层嵌套模型”,研究了颗粒增强材料自高温冷却下来时,不同相中热应力的分布特点。推出了热应力在弹性和弹塑性状态的各种表达式。研究表明,随着温度降低,增强体受到压应力,基体材料中存在的静水应力为拉应力。温度继续下降,将出现自增强颗粒与基体界面向外扩展的屈服区。随增强相体积分数增大,增强颗粒受到的压应力和基体中的静水拉应力减小,增强颗粒与基体界面屈服的起始温差增大,而基体材料全面屈服的温差却减小。     

堵塞效应与“全同带”的微观机制

利用处理推转壳模型的改进了的粒子数守恒方法(严格计及堵塞效应),对原子核的转动惯量进行了计算,计算中无任何自由参数,所得转动惯量(包括¹⁷⁰Yb,¹⁷¹Lu¹⁷¹Yb各转动带)及其奇偶差,与实验非常符合,转动惯量的奇偶差灵敏地依赖于被堵塞的能级位置及其对Coriolis力的响应。     

因特网防御DoS攻击技术评述Ⅰ--攻击分类与特征·包过滤·攻击检测与防御

概述了因特网上DoS攻击的相应分类及基本特征，评述了包过滤、攻击检测及防御技术的最新成果．前一部分介绍了入口过滤、基于路由的过滤网和有效源地址强制协议．后一方面主要讨论了适合于检测攻击包的技术，介绍了新近提出的频谱分析方法和泛滥检测系统．简要评述了已有的防御SYN泛滥攻击的技术措施，介绍了Cisco的TCP拦截技术，提出了改进策略．     

Preparation of AgBiVMoO/-Al2O3 Catalysts for the Partial Oxidation of Propane

A novel mixed sol method was developed for the preparation of supported catalysts. Analyses by means of XRD and BET show that a 40%AgBiVMoO/γ-Al2O3 catalyst prepared by this method possessed high specific surface area and high dispersion of the active phase. As a result, high acrylic acid selectivity of 8.5% was obtained when the catalyst was used in the reaction of propane partial oxidation to acrylic acid in a fixed-bed reactor.     

Photoinduced deformation of amphiphilic azo polymer colloidal spheres

Photoinduced shape deformation of colloidal spheres made of an amphiphilic azo polymer has been demonstrated in this work. The polymer contains the donor-and-acceptor-type azobenzene chromophores and can form uniform colloidal spheres by dropwise adding water into its THF solution. When the colloidal spheres obtained were exposed to the interfering p-polarized Ar+ laser beams (150 mW/cm2), the colloidal spheres changed to prolates (i.e., "rugby-balls"), "spindles", and finally "rods", depending on the irradiation times. The elongated direction of the spheres was observed to be the same as the polarization direction of the laser beam. The average major-to-minor ratio of the ellipsoids could be easily adjusted by controlling the irradiation time. The deformation effect observed in this work can offer a new way to prepare nonspherical colloids from colloidal spheres and will shed new light on the correlation between the photodriven shape deformation and photoinduced surface relief gratings for the same type of polymers.     

1H-imidazo[4,5-b] pyrazines. II. 2-carboxylic acid derivatives

Methods for the preparations of 1H-imidazo[4,5-b]pyrazine-2-carboxylic acid and derivatives are reported.     

An approach to comparative analysis of chromatographic fingerprints for assuring the quality of botanical drugs

The present study was focused on developing the chemometric methods for analysis of the chromatographic fingerprint to control the quality of botanical drugs, which has gained attention in Asia and other countries. We developed a novel approach to generate a set of fingerprint features, called Fisher components (FCs) that were extracted from the chromatographic fingerprint. The method greatly reduces the dimensionality of the fingerprint vector, and the resulting FCs still retain most discriminatory information of the original fingerprint. Choosing an example of relevance to contemporary botanical drugs, we applied the FCs to a set of Shenmai injection samples. We successfully identified the manufacturers of the samples using two classifiers, linear discriminant analysis (LDA) and k-Nearest Neighbor (k-NN) based on the FCs. We also applied a similarity assessment together with the visual analysis using the FCs to exam the products from different manufacturers. We found that the lot-to-lot consistency of products can be accurately determined using the FCs. Finally, we demonstrated that the application of chemometric methods for chromatographic fingerprinting offers reliability to detect suspected fraud samples. In summary, we demonstrated that the presented approaches could be useful to determine the identity, consistency, and authenticity of Shenmai injection through chromatographic fingerprinting. The methods are equally applicable to other botanical drugs.     

Chlorpromazine hydrochloride as an analytical reagent : A new indicator for titrations with very dilute ceric sulphate solutions

Chlorpromazine hydrochloride is proposed as an indicator for the microtitration of iron(II), arsenic(III), ascorbic acid and hydroquinone with 0.0005–0.001 N ceric sulphate; the indicator blanks are small. The colorimetric déterminations of μg quantities of cerium(lV) and arsenic(III) using the same reagent are also described.     

PURIFICATION AND PARTIAL CHARACTERIZATION OF POLYSACCHARIDES FROM THE POLLEN OF TYPHA ANGUSTIFILIA L

Three polysaccharides TAA, TAB and TAC were purified from the pollen of Typha An-gustifilia L..TAA is mainly composed of α-L-arabinofuranose, β-D-galactose and α-D-galac-turonic acid.TAB and TAC contain the backbone mainly composed of (1→5)-linked-L-arabi-nosyl residue.