全文获取类型
收费全文 | 525篇 |
免费 | 13篇 |
国内免费 | 4篇 |
专业分类
化学 | 276篇 |
晶体学 | 5篇 |
力学 | 43篇 |
数学 | 134篇 |
物理学 | 84篇 |
出版年
2023年 | 10篇 |
2022年 | 17篇 |
2021年 | 12篇 |
2020年 | 14篇 |
2019年 | 20篇 |
2018年 | 13篇 |
2017年 | 10篇 |
2016年 | 27篇 |
2015年 | 17篇 |
2014年 | 25篇 |
2013年 | 35篇 |
2012年 | 28篇 |
2011年 | 35篇 |
2010年 | 20篇 |
2009年 | 12篇 |
2008年 | 27篇 |
2007年 | 32篇 |
2006年 | 28篇 |
2005年 | 28篇 |
2004年 | 29篇 |
2003年 | 19篇 |
2002年 | 18篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 9篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1989年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 3篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1957年 | 1篇 |
1938年 | 1篇 |
1937年 | 1篇 |
1911年 | 1篇 |
1910年 | 1篇 |
1907年 | 1篇 |
1906年 | 2篇 |
1905年 | 1篇 |
1903年 | 1篇 |
1877年 | 1篇 |
1868年 | 1篇 |
排序方式: 共有542条查询结果,搜索用时 15 毫秒
1.
2.
On the characterisation of paired monotone metrics 总被引:1,自引:1,他引:0
Paolo Gibilisco Tommaso Isola 《Annals of the Institute of Statistical Mathematics》2004,56(2):369-381
Hasegawa and Petz introduced the notion of paired monotone metrics. They also gave a characterisation theorem showing that
Wigner-Yanase-Dyson metrics are the only members of the paired family. In this paper we show that the characterisation theorem
holds true under hypotheses that are more general than those used in the above quoted references. 相似文献
3.
In this article, local optimality in multiobjective combinatorial optimization is used as a baseline for the design and analysis
of two iterative improvement algorithms. Both algorithms search in a neighborhood that is defined on a collection of sets
of feasible solutions and their acceptance criterion is based on outperformance relations. Proofs of the soundness and completeness
of these algorithms are given. 相似文献
4.
María?Belén?Sierra Marcela?A.?Morini Pablo?C.?SchulzEmail author María?Luján?Ferreira 《Colloid and polymer science》2005,283(9):1016-1024
Following the studies on the effect of double bonds in the surfactant hydrophobic tail on the formation of mixed surfactant aggregates, we studied the viscosity and density of the system Sodium 10-undecenoate (SUD)–decyltrimethylammonium bromide (DTAB)–water. We found that the partial molar volume (pmv) and intrinsic viscosity of both, micellised and unmicellised mixtures, are non-ideal, dependent on the mixture composition and related to structural changes in micelles. These phenomena are caused by the presence of the double bond at the distal extreme of the SUD molecule, which has some affinity with water by formation of hydrogen bonds. In particular, as far as we know, this is the first report on non-ideal behavior of the pmv in mixed micelles. 相似文献
5.
The aqueous cationic system sodium undecenoate-dodecyltrimethylammonium bromide at low concentration
Maria?Belén?Sierra Marcela?A.?Morini Pablo?C.?SchulzEmail author 《Colloid and polymer science》2004,282(6):633-641
The aqueous sodium undecenoate (SUD) –dodecyltrimethylammonium bromide (DTAB) catanionic system was studied at low concentration. The system did not precipitate, even at a 1:1 SUD:DTAB proportion, but showed the formation of a coacervate in a range of surfactant mixture compositions. Micelles have a preferential composition of 0.37 mole fraction of SUD. This behavior is attributed to the presence of the double bond at the distal extreme of the SUD molecule, which can form hydrogen bonds with water. Consequently, the –CH=CH2 group is situated at the interface between the hydrocarbon micelle core and water, reducing the interfacial free energy. Structural computations demonstrate that the mentioned SUD proportion produces complete coverage of the micelle surface by the double bonds. 相似文献
6.
Marco Berettoni Giovanna De Chiara Tommaso Iacoangeli Paola Lo Surdo Rinaldo Marini Bettolo Lorenzo Montagnini Di Mirabello Luca Nicolini Rita Scarpelli 《Helvetica chimica acta》1996,79(7):2035-2041
A novel preparation of methyl (13S)-13-hydroxyisoatisiren-18-oate ( 4 ), a key-intermediate in a synthesis of (+)-methyl trachyloban-18-oate ((+)- 1 ), from (?)-abietic acid, is described. Since (?)- 1 has been previously converted into (?)-methyl 16-oxo-17-norkauran-18-oate ((?)- 16 ), our preparation of 4 constitutes also a formal total synthesis, from (?)-abietic acid, of (+)- 16 . Key steps in this approach were the allene photoaddition to podocarp-8(14)-en-13-one ( 5 ) and the conversion of the endo-toluene-4-sulfonate 11 into the exo-benzoate 12b . 相似文献
7.
Tommaso Carofiglio Euro Solari Carlo Floriani Angiola Chiesi-Villa Corrado Rizzoli 《Polyhedron》1996,15(24):4435-4440
The UV-stabilizer 2-(2′-hydroxy-5′-methylphenyl)benzotriazole (Tinuvin P, LH) has been used as a monoanionic bidentate ligand for complexing oxocations. Displacement of acacH from [VO(acac)2] and [MoO2(acac)2] gave [*VO(acac)2*(μ-L)] (2) and [cis-O2Mo(acac)L] (3) respectively, as crystalline compounds. Their structure has been determined by an X-ray analysis showing the structural changes occurring upon coordination. The UV spectrum of Tinuvin P is significantly affected by complexation. 相似文献
8.
Paula?Messina Marcela?A.?Morini Pablo?C.?SchulzEmail author 《Colloid and polymer science》2003,281(7):695-698
The hydration of micellised sodium dehydrocholate molecules was determined by viscosity measurements. It was found that there are 39 water molecules for each micellised surfactant molecule. About ten water molecules may be attributed to the hydration of the sodium carboxylate group. By assignation of two water molecules to each of the three carbonyl groups, the total hydration of a micellised sodium dehydrocholate molecule was estimated as about 16 water molecules. The remaining 23 water molecules per micellised sodium dehydrocholate molecule may be attributed to water trapped in the structure of micelles. 相似文献
9.
Bianco G Schmitt-Kopplin P Crescenzi A Comes S Kettrup A Cataldi TR 《Analytical and bioanalytical chemistry》2003,375(6):799-804
The glycoalkaloid content of transgenic potatoes was evaluated by an optimised method based on non-aqueous capillary electrophoresis coupled on-line with electrospray ionization-mass spectrometry (NACE-ESI-MS). The potato material consisted of tubers from a conventional cv. Désirée and from three lines of modified plants resistant, intermediate and susceptible to infection by potato virus Y (PVY). The main glycoalkaloids were confirmed to be alpha-solanine and alpha-chaconine with parent ion masses m/z 852 and 868, respectively. In addition, an unknown minor peak at m/z 850.6 was found both in conventional (control) and susceptible line potato tubers. Such a compound exhibited an MS(2) spectrum with fragments ions at 704 and 396 m/z derived by loss of two ions, i.e. m/z 146 and 307, most likely corresponding to a rhamnose unit and a [glucose-(rhamnose)(2)] moiety, respectively. Up to 30-80-fold higher concentrations of total glycoalkaloids were found in the peel compared to flesh samples of all tubers examined. TGA content was nearly doubled in peel samples of resistant compared to control lines, and these levels were lower than the limit recommended for food safety, i.e. 20-60 mg of TGA per 100 g fresh weight. Moreover, it was established that tubers produced by virus-resistant clones are substantially equivalent in glycoalkaloid contents to those produced by conventional potato varieties. 相似文献
10.
Giovannelli Tommaso Liuzzi Giampaolo Lucidi Stefano Rinaldi Francesco 《Computational Optimization and Applications》2022,82(2):293-327
Computational Optimization and Applications - In this paper, mixed-integer nonsmooth constrained optimization problems are considered, where objective/constraint functions are available only as the... 相似文献