全文获取类型
收费全文 | 2097篇 |
免费 | 173篇 |
国内免费 | 6篇 |
专业分类
化学 | 1559篇 |
晶体学 | 7篇 |
力学 | 43篇 |
数学 | 301篇 |
物理学 | 366篇 |
出版年
2024年 | 2篇 |
2023年 | 35篇 |
2022年 | 50篇 |
2021年 | 68篇 |
2020年 | 120篇 |
2019年 | 99篇 |
2018年 | 40篇 |
2017年 | 40篇 |
2016年 | 151篇 |
2015年 | 113篇 |
2014年 | 103篇 |
2013年 | 123篇 |
2012年 | 152篇 |
2011年 | 200篇 |
2010年 | 109篇 |
2009年 | 78篇 |
2008年 | 139篇 |
2007年 | 127篇 |
2006年 | 101篇 |
2005年 | 110篇 |
2004年 | 77篇 |
2003年 | 51篇 |
2002年 | 47篇 |
2001年 | 12篇 |
2000年 | 20篇 |
1999年 | 13篇 |
1998年 | 11篇 |
1997年 | 6篇 |
1996年 | 9篇 |
1995年 | 7篇 |
1994年 | 9篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 7篇 |
1989年 | 2篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1982年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1970年 | 1篇 |
1969年 | 2篇 |
1967年 | 2篇 |
排序方式: 共有2276条查询结果,搜索用时 15 毫秒
1.
Dr. Sabin Llona‐Minguez Dr. Matthieu Desroses Artin Ghassemian Dr. Sylvain A. Jacques Dr. Lars Eriksson Rebecka Isacksson Tobias Koolmeister Dr. Pål Stenmark Dr. Martin Scobie Prof. Thomas Helleday 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(20):7394-7398
A two‐step synthesis of structurally diverse pyrrole‐containing bicyclic systems is reported. ortho‐Nitro‐haloarenes coupled with vinylic N‐methyliminodiacetic acid (MIDA) boronates generate ortho‐vinyl‐nitroarenes, which undergo a “metal‐free” nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide substrate tolerance and it is applicable in the preparation of more complex “drug‐like” molecules. Interestingly, an ortho‐nitro‐allylarene derivative furnished a cyclic β‐aminophosphonate motif. 相似文献
2.
3.
4.
Tobias P. Kunzler Christoph M. Sprecher Nicholas D. Spencer 《Applied Surface Science》2006,253(4):2148-2153
Gradient surfaces allow rapid, high-throughput investigations and systematic studies in many disparate fields, including biology, tribology and adhesion. We describe a novel method for the fabrication of material-independent morphology gradients, involving a two-step process of particle erosion followed by a chemical polishing procedure that preferentially removes features with a small radius of curvature as a function of time. Gradients are fabricated on aluminium surfaces, but they may be readily transferred to other materials via a replication technique, which allows for the production of identical roughness gradient samples with any chosen surface chemistry. The gradients have been characterized by means of scanning electron microscopy and optical profilometry. Standard roughness parameters (Ra, Rq, Rz, Sm and Sk) were calculated from optical profilometry data. The roughness has also been assessed over different wavelength windows by means of a fast Fourier transformation approach. 相似文献
5.
α,β-Unsaturated nitriles can be hydrogenated with enantioselectivities up to 88% ee using chiral ruthenium-diphenylphosphino bisaryl and bisheteroaryl complexes such as ruthenium(II)-BINAP and ruthenium(II)-BINP. Mechanistic investigations indicate that conversion is accelerated by electron-rich ligands and that an additional coordinative group needs be present in order to promote conversion. The chiral products are useful building blocks for the synthesis of histamine H2 agonists of the arpromidine type. 相似文献
6.
7.
Background
Repeated execution of a tactile task enhances task performance. In the present study we sought to improve tactile performance with unattended activation-based learning processes (i.e., focused stimulation of dermal receptors evoking neural coactivation (CA)). Previous studies show that the application of CA to a single finger reduced the stationary two-point discrimination threshold and significantly increased tactile acuity. These changes were accompanied by an expansion of the cortical finger representation in primary somatosensory cortex (SI). Here we investigated the effect of different types of multifinger CA on the tactile performance of each finger of the right hand. 相似文献8.
We give three formulas expressing the Smale invariant of an immersion f of a (4k−1)-sphere into (4k+1)-space. The terms of the formulas are geometric characteristics of any generic smooth map g of any oriented 4k-dimensional manifold, where g restricted to the boundary is an immersion regularly homotopic to f in (6k−1)-space.The formulas imply that if f and g are two non-regularly homotopic immersions of a (4k−1)-sphere into (4k+1)-space then they are also non-regularly homotopic as immersions into (6k−1)-space. Moreover, any generic homotopy in (6k−1)-space connecting f to g must have at least ak(2k−1)! cusps, where ak=2 if k is odd and ak=1 if k is even. 相似文献
9.
10.
Christian Huber Christian Krause Tobias Werner Otto S. Wolfbeis 《Mikrochimica acta》2003,142(4):245-253
This article describes the preparation and performance of an optical sensor for continuous measurement of chloride at extracellular (serum) levels (20–200mM). The sensor is based on dynamic quenching of the fluorescence of lucigenin which was photo-immobilized on a hydrogel. Quenching occurs via a collisional mechanism, and the decrease in fluorescence intensity on exposure to 100mM chloride typically is –60%. It allows the determination of chloride in the 1 to 200mM concentration range, with a precision of ±3mM at 120mM. Bromide, iodide and salicylate act as interferents, while the effect of pH and oxygen is negligibly small. The sensor displays strong fluorescence intensity, excellent reproducibility, long-term stability, response times in the order of 2–5min, and is used in a commercial serum and blood chloride analyzer.Received January 21, 2003; accepted April 6, 2003
Published online July 28, 2003 相似文献