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1.
S. Meenakshi B.K. Godwal I. Orgzall S. Tkachev 《Journal of Physics and Chemistry of Solids》2006,67(8):1660-1667
We report the results of an X-ray diffraction study of CdAl2Se4 and of Raman studies of HgAl2Se4 and ZnAl2Se4 at room temperature, and of CdAl2S4 and CdAl2Se4 at 80 K at high pressure. The ambient pressure phase of CdAl2Se4 is stable up to a pressure of 9.1 GPa above which a phase transition to a disordered rock salt phase is observed. A fit of the volume pressure data to a Birch-Murnaghan type equation of state yields a bulk modulus of 52.1 GPa. The relative volume change at the phase transition at ∼9 GPa is about 10%. The analysis of the Raman data of HgAl2Se4 and ZnAl2Se4 reveals a general trend observed for different defect chalcopyrite materials. The line widths of the Raman peaks change at intermediate pressures between 4 and 6 GPa as an indication of the pressure induced two stage order-disorder transition observed in these materials. In addition, we include results of a low temperature Raman study of CdAl2S4 and CdAl2Se4, which shows a very weak temperature dependence of the Raman-active phonon modes. 相似文献
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Matveeva E. D. Podrugina T. A. Grishin Yu. K. Tkachev V. V. Zhdankin V. V. Aldoshin S. M. Zefirov N. S. 《Russian Journal of Organic Chemistry》2003,39(4):536-541
A mixed phosphonium-iodonium ylide, phenyliodoniumethoxycarbonylmethylenetriphenylphosphorane borofluoride, was synthesized. Its structure was established by means of X-ray diffraction analysis. Temperature dependence of 1H, 13C, and 31P spectra of the ylide synthesized was investigated. A dynamic equilibrium between Z and E-isomers was observed. 相似文献
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A. V. Tkachev 《Chemistry of Natural Compounds》1987,23(4):393-412
A review is given of the literature over the period from the middle of the 1950s to the beginning of the 1980s on the distribution in nature, the biological activity, the conformation, and the chemical transformations of sesquiterpenes of the caryophyllene type. 相似文献
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It is shown that a completely ionized, classical, Coulombian plasma, placed in an adiabatic enclosure, possesses a stationary state. At the same time, a plasma placed in a thermostat recombines through triple collisions, with a velocity satisfactorily accounted for by well-known theoretical results. The results obtained by numerical modeling have shown that, for a plasma placed in an adiabatic enclosure, the ergodic assumption is not valid. Various possible kinetic mechanisms, ensuring the existence of a stationary state of the adiabatically enclosed plasma, are considered.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 3–34, November, 1991. 相似文献
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A heat wave resulting from the absorption of laser radiation in the core of an optical fiber is studied using a nonstationary
2D heat conduction equation. The velocity of the wave as a function of the laser intensity is determined, and the threshold
intensity generating the heat wave is calculated. At high intensities, the velocity of the wave can be qualitatively described
by a well-known formula from combustion theory; i.e., the velocity is shown to be proportional to the square root of the radiation
intensity. The analytical threshold laser intensities closely agree with the available experimental data. 相似文献
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