全文获取类型
收费全文 | 626篇 |
免费 | 22篇 |
国内免费 | 3篇 |
专业分类
化学 | 425篇 |
晶体学 | 4篇 |
力学 | 6篇 |
数学 | 57篇 |
物理学 | 159篇 |
出版年
2020年 | 17篇 |
2018年 | 15篇 |
2017年 | 9篇 |
2016年 | 24篇 |
2015年 | 25篇 |
2014年 | 15篇 |
2013年 | 33篇 |
2012年 | 14篇 |
2011年 | 21篇 |
2010年 | 23篇 |
2009年 | 18篇 |
2008年 | 20篇 |
2007年 | 21篇 |
2006年 | 28篇 |
2005年 | 14篇 |
2004年 | 20篇 |
2003年 | 13篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 9篇 |
1995年 | 11篇 |
1994年 | 5篇 |
1993年 | 12篇 |
1992年 | 15篇 |
1991年 | 13篇 |
1990年 | 12篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1983年 | 5篇 |
1981年 | 8篇 |
1980年 | 11篇 |
1978年 | 6篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1973年 | 4篇 |
1972年 | 6篇 |
1971年 | 4篇 |
1970年 | 4篇 |
1969年 | 7篇 |
1968年 | 9篇 |
1967年 | 7篇 |
1966年 | 7篇 |
1965年 | 4篇 |
1960年 | 4篇 |
排序方式: 共有651条查询结果,搜索用时 15 毫秒
1.
2.
Marilena Vasilescu Titus Constantinescu Mariana Voicescu Helge Lemmetyinen Elina Vuorimaa 《Journal of fluorescence》2003,13(4):315-322
The spectrophotometric study of luminol (LH2) in dimethyl sulfoxide (DMSO), DMSO-water solutions, and alkaline DMSO and DMSO-water solutions has been done, focusing on the effect of the KOH additon on LH2 absorption and fluorescence properties. The absorption spectra indicate an acid-base equilibrium, and the luminol dianion (L2–) formation at 3 × 10–4 – 2.4 × 10–3
M KOH. The decrease of the fluorescence intensity and the variation of the excitation spectra of LH2-DMSO-KOH solutions with KOH concentration have been similarly explained. The acid-base process is reversible. The addition of HCl to the solution with 3.0 × 10–3 M KOH leads to an increase of the fluorescence intensity to its highest value, observed in pure DMSO. The addition of HCl to the LH2-DMSO solution leads to the decrease of the fluorescence intensity as a result of the LH+
3 cation formation. In LH2-DMSO-water, the fluorescence band is shifted from 405 nm to 424 nm and increased in the intensity. In the presence of KOH (in LH2-DMSO-water-KOH solution) a new band appears, with the maximum at 485 nm and the band at 405 nm decreased. The changes in fluorescence lifetimes also evidence the different chemical species formed. 相似文献
3.
The exciton-exciton interaction is investigated for spatially indirect excitons in coupled quantum wells. The Hartree-Fock and Heitler-London approaches are improved by a full two-exciton calculation including the van der Waals effect. Using these potentials for the singlet and triplet channel, the two-body scattering matrix is calculated and employed to derive a modified relation between exciton density and blue shift. Such a relation is of central importance for gauging exciton densities on the way toward Bose condensation. 相似文献
4.
P. Thomsen-Schmidt K. Hasche G. Ulm K. Herrmann M. Krumrey G. Ade J. Stümpel I. Busch S. Schädlich A. Schindler W. Frank D. Hirsch M. Procop U. Beck 《Applied Physics A: Materials Science & Processing》2004,78(5):645-649
High-accuracy film thickness measurements in the range below 100 nm can be made by various complex methods like spectral ellipsometry (SE), scanning force microscopy (SFM), grazing incidence X-ray reflectometry (GIXR), or X-ray fluorescence analysis (XRF). The measurement results achieved with these methods are based on different interactions between the film and the probe. A key question in nanotechnology is how to achieve consistent results on a level of uncertainty below one nanometre with different techniques.Two different types of thickness standards are realised. Metal film standards for X-ray techniques in the thickness range 10 to 50 nm are calibrated by GIXR with monochromatised synchrotron radiation of 8048 eV. The results obtained at four different facilities show excellent agreement. SiO2 on Si standards for SE and SFM in the thickness range 6 to 1000 nm are calibrated by GIXR with monochromatised synchrotron radiation of 1841 eV and with a metrological SFM. Consistent results within the combined uncertainties are obtained with the two methods. Surfaces and interfaces of both types of standards are additionally investigated by transmission electron microscopy (TEM). PACS 61.10.Kw; 68.55.Jk; 06.20.Fn; 06.60.Mr; 07.79.Lh 相似文献
5.
W. Schindler 《Computational Geometry》1994,4(6):327-343
Stochastic simulations on manifolds usually are traced back to
n via charts. If a group G is acting on a manifold M and if the respective distribution v is invariant under this group action then in many cases of practical interest there exists a more convenient approach which uses equivariant mappings. The concept of equivariant mappings will be discussed intensively at the instance of the Grassman manifold in which case G equals the orthogonal group. Further advantages of this concept will be demonstrated by applying it to a probabilistic problem from the field of combinatorial geometry. 相似文献
6.
Adler J Becker JJ Blaylock GT Bolton T Brient J Browder T Brown JS Bunnell KO Burchell M Burnett TH Cassell RE Coffman D Cook V Coward DH DeJongh F Dorfan DE Drinkard J Dubois GP Eigen G Einsweiler KF Eisenstein BI Freese T Gatto C Gladding G Grab C Hamilton RP Hauser J Heusch CA Hitlin DG Izen JM Kim PC Köpke L Li A Lockman WS Mallik U Matthews CG Mincer AI Mir R Mockett PM Mozley RF Nemati B Odian A Parrish L Partridge R Pitman D Plaetzer SA Richman JD Sadrozinski HF Scarlatella M Schalk TL 《Physical review letters》1989,62(16):1821-1824
7.
Blaylock GT Bolton T Brown JS Bunnell KO Burnett TH Cassell RE Coffman D Cook V Coward DH Dorfan DE Dubois GP Eigen G Eisenstein BI Freese T Gladding G Grab C Heusch CA Hitlin DG Izen JM Köpke L Li A Lockman WS Mallik U Matthews CG Mir R Mockett PM Mozley RF Nemati B Odian A Parker J Parrish L Partridge R Pitman D Sadrozinski HF Scarlatella M Schalk TL Schindler RH Seiden A Simopoulos C Stockdale IE Stockhausen W Thaler JJ Toki W Tripsas B Villa F Wasserbaech S Wattenberg A Weinstein AJ 《Physical review letters》1987,58(21):2171-2174
8.
9.
The intrinsic acidity constant Kint. of surface silanol groups has been determined by coulometric titration of silicagel at 25° in solutions of the constant ionic strength 0,1M consisting primarily of sodium perchlorate. The experimental data are consistent with 相似文献
10.
Title compound 1 was synthesized by a published route which had to be modified (seven steps from readily obtainable starting materials). Characterization of 1 was achieved by spectroscopic means (FAB-MS, 1H-NMR, including 2D-COSY). Furthermore, commercially available reference material purchased for comparison, was unequivocally established to be 10 , i.e. incompletely deprotected 1 . 相似文献