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1.
2.
Minimalistic Ditopic Ligands: An α‐S,N‐Donor‐Substituted Alkyne as Effective Intermetallic Conjugation Linker
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Julia Rüger Christopher Timmermann Dr. Alexander Villinger Alexander Hinz Dr. Dirk Hollmann Prof. Dr. Wolfram W. Seidel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(32):11191-11195
The capability of donor‐substituted alkynes to link different metal ions in a side‐on carbon donor‐chelate coordination mode is extended from the donor centers S and P to the second period element N. The complex [Tp′W(CO)2{η2‐C2(S)(NHBn)}] (Tp′=hydrido‐tris(3,5‐dimethylpyrazolyl)borate, Bn=benzyl) bearing a terminal sulfur atom and a secondary amine substituent is accessible by a metal‐template synthesis. Subsequent deprotonation allowed the formation of remarkably stable heterobimetallic complexes with the [(η5‐C5H5)Ru(PPh3)] and the [Ir(ppy)2] moiety. Electrochemical and spectroscopic investigations (cyclic voltammetry, IR, UV/Vis, luminescence, EPR), as well as DFT calculations, and X‐ray structure determinations of the W–Ru complex in two oxidation states reveal a strong metal–metal coupling but also a limited delocalization of excited states. 相似文献
3.
A high resolution cw dye laser spectrometer with a frequency calibration system of 100 kHz resolution is described. Two examples of measured isotope shifts will be discussed. 相似文献
4.
Gutierrez-Lugo MT Woldemichael GM Singh MP Suarez PA Maiese WM Montenegro G Timmermann BN 《Natural product research》2005,19(7):645-652
Bioassay guided isolation of an antibacterial extract prepared from the fermentation broth of a Micromonospora sp. P1068 led to the isolation of eight compounds identified as (3R) 3,4',7-trihydroxy-isoflavanone (1), 3-hydroxydehydrodaidzein, daidzein (2), 3-methyl-1H-indole-2-carboxylic acid (3), 1H-indole-3-carboxaldehyde (4), 3-(p-hydroxyphenyl)-N-methylpropionamide, N-methylphloretamide (5), phenyl acetic acid (6), 2-hydroxy phenyl acetic acid (7) and 4-hydroxy-5-methoxy-benzoic acid (8). Compounds 1 and 5 were found to be novel chemical entities while 3 was isolated from a natural source for the first time. All compounds were evaluated for their antimicrobial activities against a panel of clinically significant microorganisms. Compound 4 was active against Staphylococcus aureus (MIC, 32 microg/ml), Enterococcus faecium (MIC, 32 microg/ml) and Escherichia coli (MIC, 64 microg/ml). 相似文献
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6.
Horst Timmermann 《Annali di Matematica Pura ed Applicata》1977,114(1):121-139
Sunto è ben noto che, per gli spazi proiettivi basati sopra un corpo commutativo, vale il teorema di Pappo e che, viceversa, per
mezzo di questo teorema tali spazi possono essere coordinatizzati con un corpo commutativo K. Il teorema di Fano ci dice quando
K non può essere di caratteristica p=2. Un altro teorema è: In piani proiettivi sopra corpi K con p=2, e soltanto in questi, si ha che: Le tangenti d'una conica, costruita nel modo sintetico consueto, passano per un punto fisso.
Teoremi del genere per p ≠2 sembrano mancare finora, ma sono necessari per una costruzione pure sintetica della geometria algebrica. Il lavoro seguente
conterrà siffatti teoremi.
Entrata in Redazione il 14 giugno 1976. 相似文献
7.
8.
A cascadic multigrid algorithm for semilinear elliptic problems 总被引:12,自引:0,他引:12
Gisela Timmermann 《Numerische Mathematik》2000,86(4):717-731
Summary. We propose a cascadic multigrid algorithm for a semilinear elliptic problem. The nonlinear equations arising from linear
finite element discretizations are solved by Newton's method. Given an approximate solution on the coarsest grid on each finer
grid we perform exactly one Newton step taking the approximate solution from the previous grid as initial guess. The Newton
systems are solved iteratively by an appropriate smoothing method. We prove that the algorithm yields an approximate solution
within the discretization error on the finest grid provided that the start approximation is sufficiently accurate and that
the initial grid size is sufficiently small. Moreover, we show that the method has multigrid complexity.
Received February 12, 1998 / Revised version received July 22, 1999 / Published online June 8, 2000 相似文献
9.
LC-ESI-MS/MS coupled to DAD analysis was used as an on-line tool for identification of diarylheptanoids in fresh turmeric rhizome extracts. Based on their mass spectra, from both negative and positive mode LC-ESI-MS/MS analysis, and supported by their DAD spectra, 19 diarylheptanoids were identified. Among these 19 compounds, curcumin, demethoxycurcumin, and bisdemethoxycurcumin were identified by comparing their chromatographic and spectral data with those of authentic standard compounds. The other diarylheptanoid compounds were identified or tentatively identified based on comparison to the three curcuminoids and each other. Twelve of the identified diarylheptanoids have not been previously reported from turmeric and six of these are new compounds. 相似文献
10.
Jiang H Sólyom AM Timmermann BN Gang DR 《Rapid communications in mass spectrometry : RCM》2005,19(20):2957-2964
This study sought to determine the utility of liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) coupled with diode array detection in identifying gingerol-related compounds from crude extracts of ginger rhizome. The fragmentation behaviors of compounds in both (-)- and (+)ESI-MS/MS were used to infer and confirm the chemical structures of several groups of compounds, including the gingerols, methylgingerols, gingerol acetates, shogaols, paradols, gingerdiols, mono- and diacetyl gingerdiols, and dehydrogingerdiones. Diode array detection at different wavelengths was used to confirm MS/MS-based identification. In total, 31 gingerol-related compounds were identified from the methanolic crude extracts of fresh ginger rhizome in this study. Three of these compounds were found to be new compounds. This study demonstrated that LC/ESI-MS/MS is a powerful on-line tool for identification of gingerol-related compounds, especially for thermally labile compounds that cannot be readily detected by GC/MS analysis. 相似文献