全文获取类型
收费全文 | 663篇 |
免费 | 25篇 |
国内免费 | 1篇 |
专业分类
化学 | 407篇 |
晶体学 | 4篇 |
力学 | 17篇 |
数学 | 54篇 |
物理学 | 207篇 |
出版年
2023年 | 12篇 |
2022年 | 11篇 |
2021年 | 10篇 |
2020年 | 17篇 |
2019年 | 11篇 |
2018年 | 9篇 |
2016年 | 13篇 |
2015年 | 13篇 |
2014年 | 18篇 |
2013年 | 25篇 |
2012年 | 21篇 |
2011年 | 39篇 |
2010年 | 23篇 |
2009年 | 19篇 |
2008年 | 21篇 |
2007年 | 19篇 |
2006年 | 19篇 |
2005年 | 21篇 |
2004年 | 12篇 |
2003年 | 10篇 |
2002年 | 14篇 |
2001年 | 14篇 |
2000年 | 12篇 |
1998年 | 8篇 |
1997年 | 12篇 |
1996年 | 18篇 |
1995年 | 11篇 |
1994年 | 10篇 |
1993年 | 8篇 |
1992年 | 14篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1988年 | 15篇 |
1987年 | 9篇 |
1986年 | 11篇 |
1985年 | 9篇 |
1984年 | 11篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 9篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 13篇 |
1977年 | 6篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1971年 | 5篇 |
1968年 | 5篇 |
1915年 | 6篇 |
1886年 | 4篇 |
排序方式: 共有689条查询结果,搜索用时 109 毫秒
1.
The Nambu-Jona-Lasinio model as a particular model of quark flavour dynamics is bosonized in the low-energy regime using a generalized heat kernel expansion with local mass scale. The resulting effective meson Lagrangian defines a chiral soliton model, the solutions of which show a partial restoration of chiral symmetry inside the soliton. 相似文献
2.
3.
F. Seiffert R. Schwengner G. Winter L. Funke W. Lieberz R. Reinhardt K. P. Schmittgen D. Weil R. Wrzal K. O. Zell P. von Brentano 《Zeitschrift für Physik A Hadrons and Nuclei》1991,340(2):141-153
Excited states of73Se have been investigated up to spin, 21/2 using techniques of in-beamγ-ray spectroscopy in connection with the70Ge(α, n) reaction. Mean lifetimes of 12 levels have been determined applying Doppler-shift andγ-RF-methods. Five different bands have been identified that reflect a variety of different excitation modes. The decoupled 9/2+ band is likely to correspond to an oblate deformation while the 5/2+ band is interpreted as a strongly coupled prolate band built on the Nilsson configuration [422] 5/2+. The 3/2? band is a strongly coupled band built on the [301] 3/2} configuration.Nuclear reactions:70Ge(α,n),E=14, 16, 18, 19, 20MeV; measuredE γ,I γ,σ(E γ,θ),γγ-coin, linear polarization, DSA,γ(t).75Se deduced levels,I, π, τ, δ(E2/M1), B(σλ). Enriched targets, Ge detectors. 相似文献
4.
C. Reinhardt und W. Mathesius 《Fresenius' Journal of Analytical Chemistry》1886,25(1):114-116
Ohne Zusammenfassung 相似文献
5.
Reinhardt J. Heuer 《Journal of voice》1992,6(4):352-354
This paper presents a general schema for classifying treatment approaches for both functional and organic voice disorders. It's use is illustrated by a review of treatments for Spasmodic Dysphonia. Most behavioral approaches have been found to be unsuccessful except for mild cases. Inhalation speech as a compensatory technique has been reported as somewhat successful for those mild/moderate cases for whom medical/surgical treatment has not been available. The fact that organic treatment levels have been more successful in the treatment of Spasmodic Dysphonia may lend support to an organic etiology 相似文献
6.
7.
Summary The capillary gas chromatographic retention behavior of -pinene and tricyclene has been investigated on stationary phases of different polarities. On all but one of the columns employed, tricyclene eluted before -pinene; only permethylated -cyclodextrins dissolved in moderately polar polisiloxanes gave a reversed elution order. The intermolecular interactions which caused the unexpected retention behavior were investigated in detail, applying methods of computer simulation. To achieve this, we have developed a calculation algorithm on the basis of molecular mechanical optimizations and programmed it in a macro. This makes it possible to systematically investigate a given configuration space in which all the possible interactions can take place. It was shown that permethylated -cyclodextrin as host molecule for both guest molecules offers an optimum cavity size. As a result the number of energetically favorable contacts between host and guest molecules as well as the strength of the interactions in this stationary phase were larger. As a consequence the elution order, normally only influenced by the vapor pressure of the compounds at a given temperature, was changed. Nonspecific interactions played an especially important role for these kinds of substances. 相似文献
8.
9.
Böcking T Kilian KA Hanley T Ilyas S Gaus K Gal M Gooding JJ 《Langmuir : the ACS journal of surfaces and colloids》2005,21(23):10522-10529
Surface modification with oligo(ethylene oxide) functionalized monolayers terminated with reactive headgroups constitutes a powerful strategy to provide specific coupling of biomolecules with simultaneous protection from nonspecific adsorption on surfaces for the preparation of biorecognition interfaces. To date, oligo(ethylene oxide) functionalized monolayer-forming molecules which can be activated for attachment of biomolecules but which can selectively form monolayers onto hydrogen terminated silicon have yet to be developed. Here, self-assembled monolayers (SAMs) containing tetra(ethylene oxide) moieties protected with tert-butyl dimethylsilyl groups were formed by thermal hydrosilylation of alkenes with single-crystal Si(111)-H. The protection group was used to avoid side reactions with the hydride terminated silicon surface. Monolayer formation was carried out using solutions of the alkene in the high-boiling-point solvent 1,3,5-triethylbenzene. The protecting group was removed under very mild acidic conditions to yield a free hydroxyl functionality, a convenient surface moiety for coupling of biological entities via carbamate bond formation. The chemical composition and structure of the monolayers before and after deprotection were characterized by X-ray photoelectron spectroscopy (XPS) and X-ray reflectometry. To demonstrate the utility of this surface for covalent modification, two reagents were compared and contrasted for their ability to activate the surface hydroxyl groups for coupling of free amines, carbonyl diimidazole (CDI), and disuccinimidyl carbonate (DSC). Analysis of XP spectra before and after activation by CDI or DSC, and after subsequent reaction with glycine, provided quantitative information on the extent of activation and overall coupling efficiencies. CDI activated surfaces gave poor coupling yields under various conditions, whereas DSC mediated activation followed by aminolysis at neutral pH was found to be an efficient method for the immobilization of amines on tetra(ethylene oxide) modified surfaces. 相似文献
10.
K. Schiffer A. Dewald A. Gelberg R. Reinhardt K. O. Zell Sun Xianfu P. v. Brentano 《Zeitschrift für Physik A Hadrons and Nuclei》1986,325(4):487-488
The K=3/2 1 T rotational band has been identified in99Y with a band-head energy of 536 keV. This result is in contradiction with previously reported data, but is in agreement with predictions of the IBFM/PTQM model. 相似文献