隧洞进口平板门边缘漏水激振的研究——Naudascher振动模型

应用水力学和线性系统理论对问题进行分析,得出发生激振的临界条件式。就平移和旋转振型、有调压井和无调压井作示例计算,得到临界稳定曲线。解释了小缝隙漏水时更容易发生激振,与实际经验一致。计算了特征方程的根,获得振动频率和增长或衰减系数。     

弹性水锤对水电站调节稳定性的影响

过去文献当考虑弹性水锤对调节稳定性影响时,仅针对某单一个工作点应用频率反应判定运转是否稳定。本文应用水锤连续和动量方程导得通用的临界稳定曲线式,由此曲线在同一图上给出任何工作点是否稳定的判定。对三个无调压井的水电站和二个有调压井的水电站(其中一个是有支洞的),进行了计算,得出了定量的结果。若就定性的而言,考虑弹性影响的稳定域总比不考虑的为小;调压井有使弹性影响稍减小的趋势。     

Synthesis and Crystal Structure of a N,N,N＇-tri（2-hydroxy-5-methylbenzyl）-l,2-ethanediamine

An aminophenol ligand, N,N,N＇-tri（2-hydroxy-5-methylbenzyl）-l,2-ethanediamine, was prepared through the Marmich reaction, and structurally characterized by NMR, IR, MS and single-crystal X-ray diffract...     

Synthesis and Crystal Structure of a N,N,N′-tri(2-hydroxy-5-methylbenzyl)-1,2-ethanediamine

An aminophenol ligand, N,N,N′-tri(2-hydroxy-5-methylbenzyl)-1,2-ethanediamine, was prepared through the Mannich reaction, and structurally characterized by NMR, IR, MS and single-crystal X-ray diffraction. The title compound (C26H32N2O3, Mr = 420.54) belongs to the monoclinic system, space group P21/n with a = 8.6233(14), b = 10.2655(16), c = 26.017(4) ′, β = 95.797(2)o, V = 2291.3(6) ′3, Z = 4, the final R = 0.0461 and wR = 0.1139 for 4267 unique reflections (Rint = 0.028) with 11691 observed ones (I > 2σ(I)).     

地震时变倾斜度坝面上的异重水压力

本文提出了在坡度和密度为任意变化情形下求压力数值解的通用解法,作了多种变化因素和实际工程应用的计算,有一些与精确解作了对比。     

Selective derivatization of oxime-blocked tolylene-2,4-diisocyanate

A selective reaction of cyclohexanone oxime-blocked tolylene-2,4-diisocyanate（2,4-TDI）with amino siloxane was observed,in which amines were capable of discriminating two reactive groups in the 2,4-TDI molecule.Thus,tolylene-2-tert-butyldimethylsilyloxyethyl carbamide-4-cyclohexanone oxime carbamate was synthesized and its precise structure was determined by single-crystal X-ray diffraction.Moreover,it was found that oxime-blocked isocyanate could react selectively with the–NH2group with the–OH group unprotected in ethanolamine.