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M. V. Gorev V. S. Bondarev I. N. Flerov Ph. Sciau J. -M. Savariault 《Physics of the Solid State》2005,47(12):2304-2308
The temperature dependence of the heat capacity of two compositions in the solid solution system BaTi1?xZrxO3 (x = 0.25, 0.35) was measured using adiabatic calorimetry. In the T-x phase diagram, these compounds occupy positions near the crossover from conventional ferroelectric behavior to the relaxor state. Both compounds reveal diffuse heat capacity anomalies: two anomalies in the temperature ranges 250–350 and 150–200 K at x = 0.35 and one anomaly within the range ~150–320 K at x = 0.25. The results obtained are discussed together with structural and dielectric measurements. 相似文献
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The chemical preparation, the calorimetric studies and the crystal structure are given for two new organic sulfates NH3(CH2)5NH3SO4 1.5H2O (DAP-S) and NH3(CH2)9NH3SO4·H2O (DAN-S). DAP-S is monoclinic P21/n with unit cell dimensions: a=11.9330(2) Å; b=10.9290(2) Å; c=17.5260(2) Å; β=101.873(1)°; V=2236.77(6) Å3; and Z=8. Its atomic arrangement is described as inorganic layers of units and water molecules separated by organic chains. DAN-S is monoclinic P21/c with unit cell parameters: a=5.768(2) Å; b=25.890(10) Å; c=11.177(5) Å; β=115.70(4)°; V=1504.0(11) Å3 and Z=4. Its structure exhibits infinite chains, parallel to the [100] direction where the organic cations are interconnected. In both structures a network of strong and weak hydrogen bonds connects the different components in the building of the crystal. 相似文献
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Hosni K Msaâda K Ben Taârit M Chahed T Marzouk B 《Natural product communications》2011,6(11):1731-1734
The chemical composition of the essential oils obtained by hydrodistillation from the aerial parts of the Tunisian Hypericum perforatum and H. ericoides ssp. roberti was elucidated by a combination of GC and GC-MS analyses. The main constituents of the oil of H. perforatum were alpha-pinene (11.8%), alpha-ylangene (10.4%), germacrene-D (9.5%), n-octane (6.5%) and alpha-selinene (5.9%). The oil of H. ericoides ssp. roberti exhibited a higher amount of aliphatic and branched hydrocarbons and the main constituents were n-octane (29.1%), alpha-pinene (10.9%), pulegone (7.7%) and acetophenone (7%). Both qualitative and quantitative differences were observed between the studied oils. This chemical variability seems likely to result from the genetic variability, since samples of both species were collected at the same location and processed under the same conditions. 相似文献
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Hamadi Jerbi Thouraya Kharrat Faouzi Omri 《Mediterranean Journal of Mathematics》2016,13(5):2507-2524
In this paper, we consider a class of bilinear systems in dimension three which can be an extension of another one in \({\mathbbm{R}^{2}}\). We prove that there exists some homogeneous feedback of degree zero stabilizing the considered class if and only if these feedbacks are constants. 相似文献
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β‐Keto‐amides react with 2‐dimethylaminomethylene‐1,3‐bis(dimethylimonio)propane diperchlorate salt to give the corresponding 3‐acetyl‐5‐formylpyridin‐2‐ones. The annulation reactions proceed with excellent yields. 相似文献
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Cruz LP Rocha J Pedrosa de Jesus JD Savariault JM Galy J 《Solid state nuclear magnetic resonance》1999,15(3):153-158
Pb(Mg1/3Nb2/3)O3 (PMN), a well-known relaxor ferroelectric material, and a related pyrochlore phase have been studied by single- and triple-quantum 93Nb MAS NMR spectroscopy. The assignment of the NMR resonances has been attempted. 相似文献
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Alain Serafini Jean -Michel' Savariault Patrick Cassoux Jean -François Labarre 《Theoretical chemistry accounts》1975,36(3):241-247
An extension of the CNDO/2 formalism, similar to the method of Clack, Hush and Yandle but with a different parametrisation, is proposed for investigating the electronic structure of transition metal complexes. The results for Ni(CO)4 and Ni(PF3)4 agree well with those ofab initio calculations and with some experimental data. Such a semi-empirical approach may be performed, usingab initio results as reference data, in order to interpret the physical and chemical behaviour of largeseries of complexes in their ground state. 相似文献