The nonlinear stability of a heavy rigid plate supported by flexible columns

A heavy rigid platform is supported by thin elastic legs. The governing equations for large deformations are formulated and solved numerically by homotopy and quasi-Newton methods. Nonlinear phenomena such as nonuniqueness, catastrophe and hysteresis are found. A global critical load for nonlinear stability is introduced.     

Magnetohydrodynamic flow past a porous rotating disk in a circular magnetic field

This paper studies the effects of a circular magnetic field on the flow of a conducting fluid about a porous rotating disk. Using modern quasi-Newton and globally convergent homotopy methods, numerical solutions are obtained for a wide range of magnetic field strengths, suction and injection velocities and Alfven and disk speeds. Results are presented graphically in terms of three non-dimensional parameters. There is excellent agreement with previous work and asymptotic formulae.     

A Tunneling Model for Afterglow Suppression in CsI:Tl,Sm Scintillation Materials

Combined radioluminescence, afterglow and thermoluminescence experiments on single-crystal samples of co-doped CsI:Tl,Sm suggest that samarium electron traps scavenge electrons from thallium traps and that electrons subsequently released by samarium recombine non-radiatively with trapped holes, thus suppressing afterglow. Experiments on single crystals support the inference that electrons tunnel freely between samarium ions and are trapped preferentially as substitutional Sm⁺ near V_KA(Tl⁺) centers where non-radiative recombination is the rate-limiting step. Afterglow in microcolumnar films of CsI:Tl,Sm is enhanced by inhomogeneities which impede tunneling between samarium ions, but is partly suppressed by annealing.     

A new ternary Cu (II) complex with 4,7-dimethyl-1,10-phenanthroline and NOO-type tridentate Schiff base ligand: Synthesis,crystal structure,biomacromolecular interactions,and radical scavenging activities

NOO-type tridentate Schiff base, N-salicylidene-2-aminobenzoic acid, (H₂L), and its ternary Cu (II) complex containing H₂L Schiff base and 4,7-dimethyl-1,10-phenanthroline (4,7-dmphen), [Cu(4,7-dmphen)(H₂L)]₂7H₂O, have been synthesized and characterized by CHN analysis, ESI-MS, FTIR, and single-crystal X-ray diffraction techniques. The interaction of alone H₂L Schiff base ligand and ternary Cu (II) complex with biomacramolecules {calf thymus DNA (CT-DNA) and bovine serum albumin (BSA)} has been investigated by electronic absorption and fluorescence spectroscopy. The experimental results indicate that H₂L Schiff base ligand and ternary Cu (II) complex bind to CT-DNA by means of a moderate intercalation mode. Furthermore, the fluorescence quenching mechanism between H₂L Schiff base ligand and ternary Cu (II) complex with BSA possesses a static quenching process. Radical scavenging activity of H₂L Schiff base ligand and ternary Cu (II) complex was measured in terms of EC₅₀, using the DPPH and H₂O₂ methods. Biomacromolecule interactions and scavenging activity studies revealed that ternary Cu (II) complex yielded better results than H₂L Schiff base ligand alone.     

Experimental characterization of flow unsteadiness in the centerline plane of an Ahmed body rear slant

This study presents the results of an experimental analysis of the unsteady features of the flow around the rear part of an Ahmed body with rear slant angle of 25°. This analysis focuses on the 3D separated and reattaching zone that develops on the rear slanted surface and provides new information, improving the understanding of the flow unsteadiness. Flow investigations were performed using particle image velocimetry, hot wire anemometry, and unsteady flush-mounted pressure transducers in the plane of symmetry above the rear slanted surface. Spectral analysis and proper orthogonal decomposition of the output signals show the emergence of low frequency unsteadiness and high frequencies activity. Characteristic timescales of both instabilities are provided and the physical effect of the low frequency unsteadiness is related to a flapping motion of the separated shear layer, while the high frequency activity is associated with a large-scale vortex emission. The results focus on the centerline plane of the rear slant and more specifically demonstrate relevant similarities with the unsteady mechanisms of 2D recirculated flow.     

A Re-evaluation of Factors Controlling the Nature of Complementary Hydrogen-Bonded Networks

The energy profiles of hydrogen-bonded heterocyclic aromatics have been decomposed into atomistic energy contributions using the Interacting Quantum Atoms (IQA) method. The resulting energy contributions have been sequenced by the Relative Energy Gradient (REG) approach to determine their influence upon the shape of these energy profiles. The results show inadequacies in Jorgensen's secondary interaction hypothesis (SIH). A novel method of finding a condensed analogy for the interaction between the molecules is presented. The findings of this work further doubt the validity of the SIH, and reinforce previous warnings against its misguided use.