Phytochemicals,antioxidant, anti-acetyl-cholinesterase,and antimicrobial activities of decoction and infusion of Pelargonium graveolens

Abstract

In Tunisia, Pelargonium graveolens is widely consumed as a food aromatizing hydrosol. Recent studies have shown the potential of plant solvent-free extracts as food and pharmaceutical natural additives. Accordingly, in this study, we investigate the phenolic content, the volatile fractions of green P. graveolens extracts such as infusion and decoction, and we evaluate their biological activities. The total phenolic content of the infusion (27.05?mg GAE/gDM) is significantly different from that of decoction (31.2?mg GAE/gDM). The GC-MS analysis identified about twenty volatile components in both extracts. The DPPH inhibition and the β-carotene bleaching tests of the infusion and the decoction had considerable results. Besides, infusion and decoction exhibited a relatively high anti-acetyl-cholinesterase activity and a considerable antimicrobial activity against S. aureus, among three tested pathogenic bacteria.     

GaAs(111)A/B surface orientation effects on electron density in normal and inverted pseudomorphic HEMTs

We present calculations of the two-dimensional electron density in a Si -doped AlGaAs/InGaAs/GaAs pseudomorphic high electron mobility transistor (P-HEMT), at low temperature, for three different growth directions (001) and (111)A/B. The calculations are made using a self-consistent resolution of Schrödinger and Poisson equations. The presence of a strong built-in piezoelectric field in (111)A/B growth directions causes changes of the confining potential shape and the carrier distribution in the InGaAs channel. We discuss the influence of GaAs substrate orientation on the conduction-band structure and thereafter on the two-dimensional electron gas (2DEG) concentration in the channel. Our results show that the calculated 2DEG concentration in the normal P-HEMT structure grown on a (111)A GaAs substrate is significantly higher than those grown on (001) and (111)B GaAs substrates. We also note an increase of the average separation between the ionized donors and the carriers. On the other hand, the GaAs (111)B substrate orientation appears as inadequate for the type of structure (normal P-HEMT) on account of the charge-transfer reduction in the channel compared with the (001) orientation. In contrast, we demonstrate that the calculated 2DEG Si -doped GaAs/InGaAs/AlGaAs pseudomorphic inverted high electron mobility transistor (PI-HEMT) grown on aGaAs (111)B substrate is appreciably higher than that grown on (001) and afterwards an enhancement of the spatial separation between confined electrons in the channel and ionized dopants occurs. These effects might result in considerably improved devices of great interest regarding high electron mobility. PACS 73.20.Dx; 73.20.At; 73.90.+f; 73.63.Hs; 72.20.Dp     

Tuning vertically stacked InAs/GaAs quantum dot properties under spacer thickness effects for 1.3 μm emission

Coherent InAs islands separated by GaAs spacer (d) layers are shown to exhibit self-organized growth along the vertical direction. A vertically stacked layer structure is useful for controlling the size distribution of quantum dots. The thickness of the GaAs spacer has been varied to study its influence on the structural and optical properties. The structural and optical properties of multilayer InAs/GaAs quantum dots (QDs) have been investigated by atomic force microscopy (AFM), transmission electron microscopy (TEM), and photoluminescence (PL) measurements. The PL full width at half maximum (FWHM), reflecting the size distribution of the QDs, was found to reach a minimum for an inter-dots GaAs spacer layer thickness of 30 monolayers (ML). For the optimized structure, the TEM image shows that multilayer QDs align vertically in stacks with no observation of apparent structural defects. Furthermore, AFM images showed an improvement of the size uniformity of the QDs in the last layer of QDs with respect to the first one. The effect of growth interruption on the optical properties of the optimized sample (E30) was investigated by PL. The observed red shift is attributed to the evolution of the InAs islands during the growth interruption. We show the possibility of increasing the size of the QDs approaching the strategically important 1.3 m wavelength range (at room temperature) with growth interruption after InAs QD deposition.     

Effect of carriers localized in clusters on optical properties of In0.21Ga0.79As/GaAs multiple quantum wells

In_0.21Ga_0.79As multiple quantum wells MQW, with different well thickness L, are grown on [001] and [113] A GaAs growth directions by molecular beam epitaxy MBE. An asymmetric photoluminescence PL line shape denoted LE_A and LE_B in the lower energies side has been observed in both structures. These emissions of deep localized states can be related to the energy potential modulation associated to Indium cluster formation. Temperature dependence of photoluminescence properties has been reported. Localized state ensemble LSE model has investigated atypical behaviors of PL peak energies and the full width at half maximum FWHM of both emissions. These abnormal behaviors are explained by carriers captured by localized recombination centers. Competition processes between localized and delocalized excitons have been occurred to interpret the PL properties. The degree of localization induced by quantum-dot-like states and critical temperatures between different temperatures regions increase as far as away [001] growth direction.     

Piezoelectric field effects on electron density in a δ-doped AlGaAs/InyGa1-yAs/GaAs pseudomorphic HEMT

We have calculated the low-temperature electron density in a -doped AlGaAs/InGaAs/GaAs heterostructure in the presence of a piezoelectric field. Growth of a strained InGaAs layer on (N11) GaAs substrates causes a piezoelectric field to be built into the quantum well of a pseudomorphic high electron mobility transistor (HEMT). The presence of this field modifies the electronic properties of strained-layer heterostructures. A self-consistent analysis is made of these -doping systems to solve simultaneously the Schrödinger and Poisson equations taking into account exchange-correlation and strain effects. Thus, we have found the confining potential, the electron density, the subband energies, the eigenenvelope wavefunctions, and the Fermi-energy level in the quantum well. We have studied the effects of the InGaAs channel width and the indium composition on the electron density. Our results show a larger increase of the electron density when the calculated value is for a (111) GaAs substrate rather than for equivalent (001) and (311) substrates. We have also investigated the effects of the environmental Al concentration seen by the Si -doped on the electron density. PACS 71.76