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A catalytic amount of t-BuOK in DMSO allows the addition of ketones or imines to styrenes at 40 degrees C in good to excellent yield. Nitriles add to styrenes in NMP or in DMSO at room temperature. 相似文献
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Tanasri Bunlaksananusorn 《Tetrahedron letters》2007,48(8):1457-1459
Reaction of nitrones with terminal alkynes occurs in the presence of 1 equiv of trimethylaluminum and leads to the corresponding propargylic hydroxylamines in yields ranging from 49 to 90%. 相似文献
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A novel synthesis of effective chiral P,N- and P,P-ligands has been developed by using a t-BuOK-mediated hydrophosphination of chiral alkenylpyridines and alkenylphosphine oxides. Ir complexes of chiral P,N-ligands 1 and 3 gave high enantioselectivities for the hydrogenation of (Z)-alpha-(acetamido)cinnamate 25 and (E)-1,2-diphenylpropene leading to the hydrogenated products with up to 97% ee. 相似文献
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