全文获取类型
收费全文 | 109篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 113篇 |
数学 | 2篇 |
物理学 | 3篇 |
出版年
2022年 | 1篇 |
2020年 | 1篇 |
2019年 | 2篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2015年 | 5篇 |
2014年 | 2篇 |
2013年 | 13篇 |
2012年 | 2篇 |
2011年 | 2篇 |
2009年 | 1篇 |
2008年 | 12篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 7篇 |
2004年 | 6篇 |
2003年 | 2篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 5篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1979年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有118条查询结果,搜索用时 15 毫秒
1.
Hoang The Ban Kei Nishii Yasuo Tsunogae Takeshi Shiono 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2765-2773
This article reports a synthetic method for a norbornene–ethylene–styrene (N‐E‐S) terpolymer, which has not been well investigated so far, via incorporation of styrene (S) into vinyl‐type norbornene–ethylene (N‐E) copolymers catalyzed by a substituted ansa‐fluorenylamidodimethyltitanium [Me2Si(3,6‐tBu2Flu)(tBuN)]TiMe2 catalyst ( I ) activated with a [Ph3C][B(C6F5)4]/Al(iBu)3 cocatalyst at room temperature in toluene. The resulting terpolymerization product contained the targeted N‐E‐S terpolymer and the contaminated homopolymers, which were then able to be completely removed by solvent fractionation techniques. While homopolystyrene was easily extracted by fractionation with methylethylketone as a soluble part, homopolyethylene and a trace amount of homopolynorbornene could be perfectly separated by fractionation with chloroform as insoluble parts. The detail characterizations of a chloroform‐soluble polymer with gel permeation chromatography, nuclear magnetic resonance, and differential scanning calorimetry analyses proved that it contained a true N‐E‐S terpolymer with long N‐E sequences incorporated with isolated or short styrene sequences. The homogeneity of the morphology together with a single glass transition temperature that proportionally decreased with the increase of the styrene contents indicated that the N‐E‐S terpolymer obtained in this work is a random polymer with an amorphous structure. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2765–2773, 2007 相似文献
2.
3.
The bienzyme system consisting of glucose oxidase and gluconolactonase was investigated using a conventional diffusion-kinetics model for an enzyme-modified field-effect transistor (FET) to clarify the effect of gluconolactonase coimmobilization in a glucose oxidase membrane on the steady-state response amplitude of a glucose sensor based on a FET. The model includes spontaneous and enzymatic hydrolysis reactions of d-glucono-δ-lactone and it elucidated the following experimental results: a glucose sensor with a membrane (about 1 μm in thickness) coimmobilizing these enzymes showed a sufficient response amplitude, whereas without coimmobilization of gluconolactonase no detectable response was observed up to 3 mM glucose; and the response amplitude depended strongly on the amount of lactonase in the membrane. The model also predicted an optimum enzyme ratio for coimmobilization in a membrane. 相似文献
4.
Junzo Otera Masaki Kishi Koichi Kanehira Shigeaki Suzuki Manzo Shiono Yoshiji Fujita 《合成通讯》2013,43(4):347-352
A sequence of ene-type chlorination, palladium catalyzed dehydrochlorination, and the intramolecular Diels-Alder reaction afforded a new method for conversion of prenyl derivatives into bicyclic compounds. 相似文献
5.
Unmodified and SiCl4-modified spherical zirconia-supported methylaluminoxane were used as cocatalyst for propylene polymerization as well as ethylene/1-hexene copolymerization in combined with Me2Si(η3-C13H8)(η1-NtBu)TiMe2 (1) at 0 °C. The modification with SiCl4 improved the catalytic activity. The improvement was clearer in ethylene/1-hexene copolymerization than in propylene polymerization. The number average molecular weight (Mn) of polypropylenes increased linearly against the polymerization time regardless the cocatalyst used to give polymers with narrow molecular weight distribution (Mw/Mn < 1.32), indicating the living nature of the catalytic systems. Thus, propagation rate constant (kp) and the number of active centers (C*) were evaluated from Mn and the number of polymer-chains. When the zirconia was modified with SiCl4, the kp value decreased and the C* increased. The latter effect was more significant to enhance the catalytic activity. 相似文献
6.
Takehiro Arnano Kensei Yoshikawa Tatsuhiko Sano Yutaka Ohuchi Manzo Shiono Michihiro Ishiguro 《合成通讯》2013,43(5):499-507
Various types of α-arylpropionic acid esters were effectively obtained by the coupling reaction of aryl Grignard reagents and α-bromopropionic acid esters in the presence of nickel catalysts. α-Arylpropionitriles, precursors of α-arylpropionic acids, were also synthesized by the reaction of α-methanesulfonyloxypropionitrile and arylcopper reagents prepared from equimolar amount of arylmagnesium halides and copper(I) bromide. 相似文献
7.
Masaru Asari Kumiko Oka Tomohiro Omura Chikatoshi Maseda Yoshikazu Tasaki Hiroshi Shiono Kazuo Matsubara Mitsuyoshi Matsuda Keiko Shimizu 《Electrophoresis》2013,34(3):448-455
Amplification/hybridization‐based genetic analyses using primers containing locked nucleic acids (LNAs) present many benefits. Here, we developed a novel design for universal fluorescent PCR using LNAs. Universal fluorescent PCR generates intermediate nonlabeled fragments and final fluorescent fragments in a two‐step amplification process that uses locus‐specific primers with universal tails and universal fluorescent primers. In this study, a few standard nucleotides were replaced with LNAs only in the fluorescent universal primers. The sequence of the fluorescent universal primer significantly affected the amplification efficiency. For primers with three LNAs, the fluorescent primers with stable M13(‐47) sequences provided the most efficient signal (approximately tenfold higher than the primers with M13(‐21) sequences at lower Tm values). Moreover, AT‐rich LNA substitutions in the fluorescent primers produced much lower amplification efficiencies than GC‐rich substitutions. GC‐rich LNAs produced greater differences in Tm values among primers, and resulted in the preferential production of fluorescently labeled amplicons. The specificity and sensitivity of LNA‐containing fluorescent primers were assessed by genotyping eight STRs in Japanese individuals, and full STR profiles could be generated using as little as 0.25 ng of genomic DNA. The method permitted clear discrimination of alleles and represents sensitive STR genotyping at a reduced cost. 相似文献
8.
Yiliang Wu Jun-Ichi Mamiya Osamu Tsutsumi Akihiko Kanazawa Takeshi Shiono Tomiki Ikeda 《Liquid crystals》2013,40(6):749-753
Photoinduced alignment in a polymer liquid crystal prepared from 6-{1-[4-(2-cyano-4-nitrophenylazo)phenyl]piperazino}hexyl acrylate and 4'-[6-(methacryloyloxy)hexyloxy]-4-cyanobiphenyl was investigated for the first time on irradiation with a polarized He-Ne laser beam at 633 nm. The azobenzene moieties as well as the inert cyanobiphenyl mesogenic units were aligned with the molecular long axis perpendicular to the polarization direction of the irradiation light. Alignment induced on short irradiation was reversible, while that induced under prolonged irradiation was irreversible due to the occurrence of crosslinking which might be caused by photoinduced decomposition of the azobenzene moieties during the photoirradiation process. 相似文献
9.
10.