首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   716篇
  免费   24篇
  国内免费   2篇
化学   548篇
晶体学   3篇
力学   4篇
数学   53篇
物理学   134篇
  2022年   2篇
  2021年   6篇
  2020年   12篇
  2019年   9篇
  2018年   5篇
  2017年   4篇
  2016年   12篇
  2015年   13篇
  2014年   17篇
  2013年   32篇
  2012年   42篇
  2011年   58篇
  2010年   26篇
  2009年   24篇
  2008年   59篇
  2007年   42篇
  2006年   36篇
  2005年   46篇
  2004年   45篇
  2003年   25篇
  2002年   24篇
  2001年   13篇
  2000年   16篇
  1999年   13篇
  1998年   5篇
  1997年   8篇
  1996年   10篇
  1995年   6篇
  1994年   6篇
  1993年   3篇
  1992年   10篇
  1991年   7篇
  1990年   7篇
  1989年   2篇
  1988年   3篇
  1987年   9篇
  1986年   5篇
  1985年   9篇
  1984年   10篇
  1983年   10篇
  1982年   5篇
  1981年   11篇
  1980年   8篇
  1979年   3篇
  1978年   7篇
  1977年   5篇
  1976年   2篇
  1975年   2篇
  1973年   4篇
  1959年   1篇
排序方式: 共有742条查询结果,搜索用时 15 毫秒
1.
Let N+ denote the Smirnov class on the open unit disc D. It is easy to see that for any outer function g in N+, there exists a function G in N+ such that |g|; ≤ ReG on δ. We describe such a G. In general, G may not be outer. In this paper, a necessary and sufficient condition on g is given for the existence of an outer function G such that |;g|; < ReG. When g belongs to the Hardy space H1, G is trivially given as the Herglotz integral of |;g|;.  相似文献   
2.
A Q-algebra can be represented as an operator algebra on an infinite dimensional Hilbert space. However we don’t know whether a finite n-dimensional Q-algebra can be represented on a Hilbert space of dimension n except n = 1, 2. It is known that a two dimensional Q-algebra is just a two dimensional commutative operator algebra on a two dimensional Hilbert space. In this paper we study a finite n-dimensional semisimple Q-algebra on a finite n-dimensional Hilbert space. In particular we describe a three dimensional Q-algebra of the disc algebra on a three dimensional Hilbert space. Our studies are related to the Pick interpolation problem for a uniform algebra.  相似文献   
3.
4.
In proportion to the environmental pollution problems caused by organotin compounds, the genotoxicities of tin compounds in the environments have become of interest so as to estimate their safety in recent years. In this work, isolated λ-DNA (double-strand DNA) was incubated with inorganic tin(II) and tin(IV) and five organotin compounds [n-butyltin trichloride, di(n-butyltin) dichloride, methyltin trichloride, dimethyltin dichloride and trimethyltin chloride] in reaction systems both with and without hydrogen peroxide (H2O2) content. The tin compounds tested in this study did not induce DNA breakage in the absence of hydrogen peroxide. Divalent inorganic tin (SnCl2) and tetravalent inorganic tin (SnCl4) caused DNA breakage in the presence of hydrogen peroxide (10 mM), and the DNA damage activity of inorganic tin was much more potent in divalent inorganic tin (SnCl2) than in tetravalent inorganic tin (SnCl4). Divalent inorganic tin (SnCl2) induced DNA breakage in a concentration-dependent fashion at concentrations greater than 0.1 mM of SnCl2 in the presence of hydrogen peroxide (10 mM). DNA breakage was not caused by n-butyltin compounds and methyltin compounds either in the presence or in the absence of hydrogen peroxide.  相似文献   
5.
6.
0IntroductionThefirstmolecule鄄basedmagnetswerereportedin1986[1].Duringthelasttwodecades,moreandmoreattentionhasbeenpaidtothesynthesisofmolecule鄄basedmagnets,especiallytoPrussianBlueanalogu鄄es[2].TheoldPrussianBlueanalogueshavebeenbroughtuptodateduetoth…  相似文献   
7.
Summary {\rtf1\ansi\ansicpg1250\deff0\deflang1038\deflangfe1038\deftab708{\fonttbl{\f0\froman\fprq2\fcharset238{\*\fname Times New Roman;}Times New Roman CE;}} \viewkind4\uc1\pard\f0\fs20 New explanations are given for two types of irregular thermogravimetric (TG) data. A TG relationship between mass and temperature is derived on the basis of migration behavior of bubbles generated in bulk of sample system, and superposed on that derived on the basis of kinetics of the 4\super th\nosupersub order event, which is superposed on the experimental TG data obtained from three reference papers. This suggests that these TG data are reflecting migration of bubbles. A dependence of TG behavior on heating rate, which is contrary to usual that, is shown and is explained in terms of event-rate determination by boiling. \par }  相似文献   
8.
Treatment of trifluoroacetaldehyde N,O-acetal with diazoacetate in the presence of a Lewis acid furnished CF3-substituted aziridinecarboxylates in good yields. Both cis and trans isomers were obtained stereoselectively by the proper choice of the ester substituents. Use of a chiral diazoacetate derived from (R)-pantolactone led to highly diastereoselective aziridination (94% de).  相似文献   
9.
Ab initio Calculations of the isomerization reaction of diphosphene 1-sulfide (2′) to thiadiphosphirane (3′) suggest that the energy barrier of the reaction in the ground state is 25 kcal/mol and that 2′ lies 21 kcal/mol above 3′, while the calculations show that there exists one local minimum on the lowest triplet energy surface.  相似文献   
10.
We have demonstrated that the 6.0% polyacrylamide disc gel electrophoresis (PAGE) method in the presence of 1% Triton X-100 clearly separated both normal molecular mass intestinal alkaline phosphatase (NIAP) and bone alkaline phosphatase (BAP) in serum regardless of the ABO blood group and the secretor status of the subjects. From the results under the usual 7.5% PAGE condition, overlapping mobilities of NIAP and BAP were found in particular in nonsecretor subjects after a high-fat meal. Under the above conditions, the apparent BAP percentage three hours after a meal was higher in nonsecretors than in subjects under fasting conditions, because NIAP activity in serum rose sharply following a high-fat meal. In contrast, under our 6.0% PAGE method, the NIAP and BAP were clearly separated from each other regardless of whether the subjects were fasting or had ingested a high-fat meal. In addition, an elevated level of the circulating NIAP can be another marker for patients with liver cirrhosis. Considering all these factors, the 6.0% PAGE method proposed by us is not only a useful method for the separation of intestinal alkaline phosphatase (IAP) isoforms, but can also be useful for the analysis of other usual AP isozymes.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号