Water vapour density measurement in halogen lamps using near-infrared semiconductor laser spectrometry II Actual lamp bulb measurement

Non-destructive, quantitative measurement for the amount of water vapour included in halogen lamp bulbs has been carried out. Residual water vapour density in lamp bulbs was confirmed as several hundreds of ppm by using a working curve obtained by InGaAsP/InP semiconductor laser spectrometry in the 1.36m spectral region.     

Decoupling by State Feedback in Infinite-Dimensional Systems

This paper studies the decoupling problem in infinite-dimensionalsystem using the so-called geometric approach of Wonham, andpresents necessary and/or sufficient conditions for the problemto be solvable for various cases, including (a) the case forwhich the input operator B satisfies dim (Im B) = k, where kis the number of output blocks, and (b) the case for which thepre-input operator G satisfies rank G = m, where m is the dimensionof the input space.     

Improved Method of Molecular Imprinting of Cyclodextrin on Silica-gel Surface for the Preparation of Stable Stationary HPLC Phase

By using N-(3-triethoxysilyl)propylacrylamide (TPAAm), vinyl groups were introduced onto the surface of silica-gel. On the surface of this silica-gel, β-CyD was molecularly imprinted by using a redox initiator, and the composite was used as stationary phase of high performance liquid chromatography (HPLC). The pump pressure was sufficiently low and did not increase even after continuous elution for 24 h. In order to prepare still more stable columns, a new polymerization process was developed. There, the redox initiator was first mixed with the surface-modified silica-gel and then vinylated β-CyD, crosslinker, and the template were added. This modification promoted the immobilization of β-CyD copolymer to the silica-gel, resulting in still lower pump pressure. Concurrently, the imprinting efficiency was increased in comparison with previous method where the redox initiator was directly added to the mixture of the β-CyD–template complex, crosslinker, and surface-modified silica-gel. The molecularly imprinted β-CyD column, prepared by this new method, efficiently discriminated the enantiomers of N-benzyloxycarbonyltyrosine.     

Ibuprofen-Cyclodextrin Inclusion Complex Formation using Supercritical Carbon Dioxide

Supercritical carbon dioxide (SC-CO₂) processing was performed with mixtures of cyclodextrins (CDs) and ibuprofen (IBP) to create inclusion complexes of ibuprofen and CD. Mixtures of IBP and trimethyl-β-CD showed new powder X-ray diffraction peaks after SC-CO₂ processing, although samples after processing with β-CD showed identical X-ray diffraction patterns with the physical mixture. The differential scanning calorimetry curves of samples after processing with trimethyl-β-CD showed no fusion peak of IBP and a new melting peak at around 185 °C. The physicochemical properties are similar to the co-precipitated samples of IBP and trimethyl-β-CD. Therefore, inclusion complex between IBP and trimethyl-β-CD was successfully prepared using SC-CO₂ technique. No inclusion formation was found when nitrogen was used as the supercritical fluid. Complexation of IBP and CD would not occur only on a high-pressure condition. The solubility of cyclodextrin into SC-CO₂ might play an important role in the formation of the inclusion complex.     

New Aspects in the Chemistry of Three-membered Ring Compounds Containing a Highly Coordinate Main Group Element

The title compounds were synthesized by taking advantage of the Martin ligand. Their structures were determined by X-ray crystallography. Pentacoordinate thiasiliranides were hydrolyzed to give the corresponding thiol. Pentacoordinate chalcogenaphosphiranes were found to have polar P-chalcogen bonds, which were confirmed by their reactions with CF3SO3Me to give the corresponding 1-（methylchalcogena）alkylphosphonium triflates and by the solvent-dependent NMR studies.     

PRODUCTION OF MALONALDEHYDE FROM SQUALENE, A MAJOR SKIN SURFACE LIPID, DURING UV-IRRADIATION

Malonaldehyde (MA), a product of lipid peroxidation, is known to have a number of toxicological effects. Among skin surface components, squalene has been suggested as a significant source of MA following UV exposure. Irradiation of squalene coated on the inside surface of glass tubes served as a simple model to examine skin surface photochemistry. Malonaldehyde produced during UV-irradiation was reacted with methyl hydrazine to form N-methylpyrazole, which was then measured by gas chromatographic analysis. Ultraviolet A-irradiation produced low levels of MA from squalene, with a maximum of 1.0 nmol MA/mumol squalene near 6 h. Malonaldehyde production varied with the energy of irradiation, with levels of 176 nmol/mg squalene and 9 nmol/mg squalene produced after 3 h of irradiation with UVB and UVA, respectively. The thiobarbituric acid (TBA) assay for lipid peroxidation showed large overestimations of MA levels under all irradiation conditions tested. The TBA assay predicted the highest levels of MA with UVC but we did not detect any MA with our assay.     

On Large-Time Behavior of Solutions to the Compressible Navier-Stokes Equations in the Half Space in R 3

 The Navier-Stokes equation for compressible viscous fluid is considered on the half space in R ³ under the zero-Dirichlet boundary condition for the momentum with initial data near an arbitrarily given equilibrium of positive constant density and zero momentum. Time decay properties in L ² norms for solutions of the linearized problem are investigated to obtain the rate of convergence in L ² norms of solutions to the equilibrium when initial data are sufficiently close to the equilibrium in . Some lower bounds are derived for solutions to the linearized problem, one of which indicates a nonlinear phenomenon not appearing in the case of the Cauchy problem on the whole space. (Accepted May 8, 2002) Published online October 18, 2002 Communicated by T.-P. LIU