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1.
Dr. Sabin Llona‐Minguez Dr. Matthieu Desroses Artin Ghassemian Dr. Sylvain A. Jacques Dr. Lars Eriksson Rebecka Isacksson Tobias Koolmeister Dr. Pål Stenmark Dr. Martin Scobie Prof. Thomas Helleday 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(20):7394-7398
A two‐step synthesis of structurally diverse pyrrole‐containing bicyclic systems is reported. ortho‐Nitro‐haloarenes coupled with vinylic N‐methyliminodiacetic acid (MIDA) boronates generate ortho‐vinyl‐nitroarenes, which undergo a “metal‐free” nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide substrate tolerance and it is applicable in the preparation of more complex “drug‐like” molecules. Interestingly, an ortho‐nitro‐allylarene derivative furnished a cyclic β‐aminophosphonate motif. 相似文献
2.
We build a metric space which is homeomorphic to a Cantor set but cannot be realized as the attractor of an iterated function system. We give also an example of a Cantor set K in R3 such that every homeomorphism f of R3 which preserves K coincides with the identity on K. 相似文献
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5.
Lionel Thibault Nadia Zlateva 《Proceedings of the American Mathematical Society》2005,133(10):2939-2948
Using a quantitative version of the subdifferential characterization of directionally Lipschitz functions, we study the integrability of subdifferentials of such functions over arbitrary Banach space.
6.
Ciprian Borcea Xavier Goaoc Sylvain Lazard Sylvain Petitjean 《Discrete and Computational Geometry》2006,35(2):287-300
We prove that four spheres in ℝ3 have infinitely many real common tangents if and only if they have aligned centers and at least one real common tangent. 相似文献
7.
Using a high resolution Raman spectrometer, we have measured Ar-broadening coefficients in the ν2Q branch of C2H2 for 22 lines at 295 K, 20 lines at 174 K, and 16 lines at 134 K. These lines with J values ranging from 1 to 23 are located in the spectral range 1970.9-1974.3 cm−1. The collisional widths are obtained by fitting each spectral line with a Rautian profile. The resulting broadening coefficients are compared with theoretical values arising from close coupling and coupled states calculations. A satisfactory agreement is obtained at room as well as at low temperatures, especially for odd J lines. By comparing broadening coefficients at 295, 174, and 134 K from a simple power law, the temperature dependence of these broadenings has been determined both experimentally, and theoretically. 相似文献
8.
Sylvain Maillot 《Geometric And Functional Analysis》2007,17(3):839-851
We show that open 3-manifolds that have a locally finite decomposition along 2-spheres are characterized by the existence
of a Riemannian metric with respect to which the second homotopy group of the manifold is generated by small elements.
Received: November 2005 Revision: February 2006 Accepted: May 2006 相似文献
9.
The performances of two Laser Doppler Velocimetry (LDV) systems adapted for measuring the acoustic particle velocities are assessed in enclosed sound field. This assessment is performed by comparing the acoustic velocities measured by means of LDV to reference acoustic velocities estimated from sound pressure measurements. The two LDV systems are based on a single optical bench which delivers an optical signal called Doppler signal. The Doppler signal, which is frequency modulated, is analyzed by means of two signal processing systems, the BSA (Burst Spectrum Analyser from Dantec) on the one hand, and a system specifically developed for the estimation of the acoustic velocity on the other hand. Once the experimental setup has been optimized for minimizing the errors made on the reference velocities, the assessment is performed and shows that both systems can measure the acoustic velocity in enclosed field in two the frequency ranges [0-4 kHz] and [0-2 kHz] respectively for acoustic velocity amplitudes of 10 mm/s and 1 mm/s. 相似文献
10.
In this Note, we return to the theory of characteristic modes which was introduced 30 years ago for electromagnetic scattering problems. A simple mathematical framework is proposed and complete definitions are given. The potential interest of this theory in terms of Radar Cross Section (RCS) analysis is then discussed, especially in the low frequency case. Finally, a 3-D example is presented to illustrate the efficiency of this decomposition. To cite this article: Y. Morel et al., C. R. Mecanique 332 (2004). 相似文献