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1.
Using the appropriate harmonic oscillator states and reasonable approximations, we construct coherent wavepackets corresponding
to the solutions of the Klein-Gordon equation for the attractive potentialV(r)=−k/r, k>0, in two and three space dimensions. We deduce the corresponding classical limit in two dimension by requiring that the
expectation value 〈r〉 of the radial variable is large. In the case of three dimensions, besides the condition of large 〈r〉, we make the uncertainty Δr=[〈r
2〉 − 〈r〉2]1/2 a minimum with respect to certain parameter of the wavepacket. We then investigate the trajectory traversed by the wavepacket
in the classical limit. We find that the classical limit of this relativistic quantal problem gives, in the leading order,
the same expression for the rate of motion of the perihelion as that given by the solution of the corresponding special relativistic
classical dynamical problem. We also briefly discuss some of the subtle aspects of the classical limit of the relativistic
quantal system, in general. 相似文献
2.
Borrowing hydrogen from alcohols, storing it on a catalyst and subsequent transfer of the hydrogen from the catalyst to an in situ generated imine is the hallmark of a transition metal mediated catalytic N-alkylation of amines. However, such a borrowing hydrogen mechanism with a transition metal free catalytic system which stores hydrogen molecules in the catalyst backbone is yet to be established. Herein, we demonstrate that a phenalenyl ligand can imitate the role of transition metals in storing and transferring hydrogen molecules leading to borrowing hydrogen mediated alkylation of anilines by alcohols including a wide range of substrate scope. A close inspection of the mechanistic pathway by characterizing several intermediates through various spectroscopic techniques, deuterium labelling experiments, and DFT study concluded that the phenalenyl radical based backbone sequentially adds H+, H˙ and an electron through a dearomatization process which are subsequently used as reducing equivalents to the C–N double bond in a catalytic fashion.An efficient method is developed for harvesting hydrogen, its storage and catalytic transfer by an odd alternant hydrocarbon. The strategy is reminiscent of transition metals in borrowing hydrogen mediated processes. 相似文献
3.
In the present paper, we study a dynamic reaction model in which (i) the predator is provided with an alternative food in addition to the prey species, (ii) the predator is harvested, and (iii) a tax is imposed to regulate the system. The existence of possible steady states along with their local as well as global stability is discussed for both the exploited and unexploited systems. Boundedness of the system is also discussed. It is seen that the system undergoes a Hopf bifurcation by the addition of alternative prey and the criteria for the Hopf-bifurcation is also discussed. Optimal tax policy is discussed using Pontryagin’s maximal principle. Finally, some numerical simulations are given to show the consistency with theoretical analysis. 相似文献
4.
5.
Ujwal Pratim Saikia Diganta BaruahPallab Pahari Manash Jyoti Borah Amrit GoswamiDilip Konwar 《Tetrahedron letters》2014
A mild and efficient methodology has been developed for the synthesis of spiro-1,3-oxazine derivatives by the microwave assisted cyclization of N-2-(1′-cyclohexenyl)ethyl-acetamides/benzamides. The reaction was catalyzed by in situ generated trimethylsilyl iodide and featured by its very short reaction time. The starting materials were easily obtained by the condensation of substituted acetic/benzoic acids with 2-(1′-cyclohexenyl)ethyl amine. 相似文献
6.
T. K. Kar U. K. Pahari K. S. Chaudhuri 《Journal of Applied Mathematics and Computing》2005,19(1-2):311-326
The paper deals with the problem of selective harvesting in a prey-predator model with predator self limitation. Criteria for local stability and global stability for both the exploited and unexploited system are derived. The effort has been considered as a dynamic variable and taxation as a control instrument to protect the fish populations from over exploitation. Finally, the optimal taxation policy is discussed with the help of control theory. 相似文献
7.
Swagata Chakraborty Susmitha A. L. Ramakrishna V. Hosur 《Magnetic resonance in chemistry : MRC》2012,50(9):587-591
Direct detection of 13C nucleus can be used as a valuable alternative where 1H detection poses a challenge due to relaxation effects, chemical exchange and poor chemical shift dispersion. In this context, we have designed a suite of 2D 13Cα‐detected hNCA experiments that provide sequential correlations of 13Cα with 15N on one hand and efficient spectroscopic labeling of certain groups of residues, namely, Gly, Ala, Ser and Thr, on the other. These residues act as checkpoints in the sequential walk, which in turn offer new possibilities of backbone assignment of small proteins from a set of 2D experiments, thereby providing great economy in terms of spectrometer time. The direct identification of peptide segments around Gly, Ala, Ser and Thr residues along a protein chain will be highly valuable for deriving important information on sites of ligand binding, phosphorylation, inhibitor/substrate binding, understanding protein folding pathways, comprehending local conformational dynamics etc. without having to obtain complete sequence‐specific assignments, which can be time consuming and at times formidable, especially in large proteins. We have illustratively demonstrated the multifaceted applications of these variants of 2D experiments on ubiquitin and M‐crystallin. We foresee that these 2D hNCA experiments will provide economic and efficient strategies for studying the structure and function of proteins. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
8.
Chakraborty S Chaudhuri S Pahari B Taylor J Sengupta PK Sengupta B 《Journal of luminescence》2012,132(6):1522-1528
Hesperitin, a ubiquitous bioactive flavonoid abundant in citrus fruits is known to possess antioxidant, anti-carcinogenic, hypolipidemic, vasoprotective and other important therapeutic properties. Here we have explored the interactions of hesperitin with normal human hemoglobin (HbA), using steady state and time resolved fluorescence spectroscopy, far UV circular dicroism (CD) spectroscopy, combined with molecular modeling computations. Specific interaction of the flavonoid with HbA is confirmed from flavonoid-induced static quenching which is evident from steady state fluorescence as well as lifetime data. Both temperature dependent fluorescence measurements and molecular docking studies reveal that apart from hydrogen bonding and van der Waals interactions, electrostatic interactions also play crucial role in hesperitin-HbA interactions. Furthermore, electrostatic surface potential calculations indicate that the hesperitin binding site in HbA is intensely positive due to the presence of several lysine and histidine residues. 相似文献
9.
Physics of Atomic Nuclei - The rich physics program of CMS experiment depends on the ability to trigger, reconstruct and identify events with electrons and photons with the CMS detector with... 相似文献
10.
Sudip Chaudhuri Biswapathik Pahari Bidisha Sengupta Pradeep K. Sengupta 《Journal of photochemistry and photobiology. B, Biology》2010,98(1):12-19
Recent years have witnessed burgeoning interest in plant flavonoids as novel therapeutic drugs targeting cellular membranes and proteins. Motivated by this scenario, we explored the binding of robinetin (3,7,3′,4′,5′-pentahydroxyflavone, a bioflavonoid with remarkable ‘two color’ intrinsic fluorescence properties), with egg yolk phosphatidylcholine (EYPC) liposomes and normal human hemoglobin (HbA), using steady state and time resolved fluorescence spectroscopy. Distinctive fluorescence signatures obtained for robinetin indicate its partitioning (Kp = 8.65 × 104) into the hydrophobic core of the membrane lipid bilayer. HbA–robinetin interaction was examined using both robinetin fluorescence and flavonoid-induced quenching of the protein tryptophan fluorescence. Specific interaction with HbA was confirmed from three lines of evidence: (a) bimolecular quenching constant Kq ? diffusion controlled limit; (b) closely matched values of Stern–Volmer quenching constant and binding constant; (c) τ0/τ = 1 (where τ0 and τ are the unquenched and quenched tryptophan fluorescence lifetimes, respectively). Absorption spectrophotometric assays reveal that robinetin inhibits EYPC membrane lipid peroxidation and HbA glycosylation with high efficiency. 相似文献