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排序方式: 共有1877条查询结果,搜索用时 15 毫秒
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Susana Estopiñá-Durán Liam J. Donnelly Euan B. Mclean Bryony M. Hockin Prof. Alexandra M. Z. Slawin Dr. James E. Taylor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(15):3950-3956
A combination of pentafluorophenylboronic acid and oxalic acid catalyses the dehydrative substitution of benzylic alcohols with a second alcohol to form new C−O bonds. This method has been applied to the intermolecular substitution of benzylic alcohols to form symmetrical ethers, intramolecular cyclisations of diols to form aryl-substituted tetrahydrofuran and tetrahydropyran derivatives, and intermolecular crossed-etherification reactions between two different alcohols. Mechanistic control experiments have identified a potential catalytic intermediate formed between the aryl boronic acid and oxalic acid. 相似文献
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Susana Conde Ceide 《Tetrahedron letters》2006,47(26):4415-4418
We herein report that flash heating microwave irradiation is a helpful tool in the formation of arylpyrimidines from the corresponding halopyrimidines. The palladium-catalyzed cross-coupling reactions of 2,4-di- and 2,4,5-trihalopyrimidines with phenylboronic acid under the above conditions are described. By use of the appropriate catalyst and the adequate halopyrimidine, good regioselectivity can be achieved in the 2-, 4-, or 5-positions of the heterocycle. In addition, we show that this methodology is ameneable for the stepwise preparation of mono-, di-, and triphenylpyrimidines. 相似文献
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We analyze the critical length for design purposes of six-dimensional spaces invariant under translations and reflections
containing the functions 1, cos t and sin t. These spaces also contain the first degree polynomials as well as trigonometric and/or hyperbolic functions. We identify
the spaces whose critical length for design purposes is greater than 2π and find its maximum 4π. By a change of variables,
two biparametric families of spaces arise. We call shape preservation region to the set of admissible parameters in order
that the space has shape preserving representations for curves. We describe the shape preserving regions for both families.
To our friend Mariano Gasca on occasion of his 60th birthday
Research partially supported by the Spanish Research Grant MTM2006-03388, by Gobierno de Aragón and Fondo Social Europeo. 相似文献
8.
Nonlocal character of entangled photon pairs generated in spontaneous parametric downconversion is demonstrated. One photon from a pair propagates through a Mach-Zehnder interferometer and is detected in coincidence-count measurement with its twin. Width of the coincidence-count interference pattern (measured for various values of path difference in the Mach-Zehnder interferometer) depends on spectral width of the twin as a result of entanglement of photons in a pair. The experimental setup is analyzed for a Gaussian spectral filter and a Fabry-Perot resonator. It is shown that nonlocal interference is much stronger for cw pumping in comparison with femtosecond pulsed pumping for values of parameters commonly used in spontaneous parametric downconversion experiments. 相似文献
9.
M. Kveder R. Rakoš M. Gavella V. Lipovac G. Pifat S. Pečar M. Schara 《Applied magnetic resonance》2004,27(1-2):77-86
The perturbation of the physical state of cell membranes triggered by an external oxidative stimulus has been studied with sperm cells which were chosen as a model system. Electron paramagnetic resonance (EPR) spectroscopy was applied and three different nitroxides bearing a paramagnetic group on the 5th, 7th and 13th carbon of the stearic acid acyl chain were used to probe different regions of the membrane. The theoretical simulations of the experimental spectra indicate distinct domains in the intact cell plasma membrane where local steric constraints impose different degrees of motional averaging experienced by the reporter group. Upon the external oxidative stimulus the spectral changes were proportional to the accumulated oxidation products and were detected only for the reporter group residing close to the lipid-water interface. The EPR spectra reveal that the motion of the reporter group has slowed down in the oxidized cells and that the oxidatively modified membrane shows up as a more rigid structure as compared with the native state. The results also indicate that the oxidation-induced spectral changes are supressed in the presence of gangliosides. 相似文献
10.
Some Landau's type inequalities for infinitesimal generators 总被引:3,自引:0,他引:3
Summary Lett T(t) be a strongly continuous contraction semigroup on a complex Banach space and letA be its infinitesimal generator. We prove that, forx D(A
3), the following inequalities hold true: Ax3 243/8 x2A
3
x, A
2
x 24 xA
3
x2. Ift T(t) is a contraction group (resp. cosine function) we get the analogous but better inequalities with constants 9/8 and 3 (resp. 81/40 and 72/25) instead of 243/8 and 24. We consider also uniformly bounded semigroups, groups and cosine functions. 相似文献