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Akira Hirao Masahiro Kitamura Mayumi Hayashi Surapich Loykulnant Kenji Sugiyama 《Macromolecular Symposia》2005,226(1):35-50
Anionic polymerizations of four new dual-functionalized styrene and α-methylstyrene derivatives, 3-(4-(4-isopropenylphenoxy)butyl)styrene ( 4 ), 3-(4-(2-isopropenylphenoxy)butyl)-α-methylstyrene ( 5 ), 4-(4-(4-isopropenylphenoxy)butyl)-α-methylstyrene ( 6 ), and 4-(4-(2-vinylphenoxy)butyl)styrene ( 7 ), were carried out in THF at -78 °C with sec-BuLi as an initiator. Both 4 and 5 underwent anionic polymerization in a living manner to quantitatively afford functionalized polystyrenes and poly(α-methylstyrene)s having α-methylstyrene moiety in each monomer unit and precisely controlled chain lengths. On the other hand, insoluble polymers were obtained by the anionic polymerization of 6 and 7 under the same conditions. The positional effect of substituent on anionic polymerization was discussed. 相似文献
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Akira Hirao Mayumi Hayashi Yumi Negishi Naoki Haraguchi Surapich Loykulnant 《Macromolecular Symposia》2002,181(1):73-94
Novel well-defined chain-end- and in-chain-functionalized polystyrenes with six, eight, twelve, and sixteen benzyl chloride moieties and with four and eight D-glucose residues have been successfully synthesized by developing the methodology based on living anionic polymerization of using new functionalized agents derived from functionalized 1,1-diphenylethylene (DPE) derivatives. They are 1,10-dichloro-4,4-7,7-tetra(3-methoxymethylphenyl)decane, its iodide derivative, the dianion prepared from 1,1-bis(3-methoxymethylphenyl)ethylene and potassium naphthalenide, and 1,1-bis[3′,5′-bis(1,2:5,6-di-O-isopropylidene-α-D-glucofuranose-3-oxymethyl)phenyl]ethylene. The developed methodology involves diverse modes of reactions of polystyryllithium with new functionalized agents and either the subsequent transformation reaction with BCl3 into benzyl chloride moieties or acid-hydrolysis to regenerate D-glucose residues. The resulting chain-multi-functionalized polystyrenes were precisely controlled with respect to chain length and quantitatively functionalized within experimental errors. 相似文献
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