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Deerenberg S Schrekker HS van Strijdonck GP Kamer PC van Leeuwen PW Fraanje J Goubitz K 《The Journal of organic chemistry》2000,65(16):4810-4817
A series of chiral phosphine-phosphite ligands 1-6 have been synthesized and used in the enantioselective palladium-catalyzed reaction of rac-1,3-diphenyl-2-propenyl acetate with dimethyl malonate as nucleophile. Ligands 1a, 2, 3, 5a, 6a, and 6b have been synthesized starting from racemic tert-butylphenylphosphinoborane. The use of dynamically resolved Li phosphide (-)-sparteine provided the optically pure ligands. Crystals of the allylpalladium (6a) complex were obtained, suitable for X-ray crystal structure determination. The X-ray crystal structure of the allylpalladium (6a) complex revealed a longer palladium-carbon bond distance trans to the phosphine moiety indicating that the attack of the nucleophile takes place at the carbon trans to the phosphine moiety. This was confirmed by the fact that the phosphine moiety did not affect the enantioselectivity directly. Under mild reaction conditions, enantioselectivities up to 83% were obtained (25 degrees C) with ligand 1e. Systematic variation of the ligand bridge and the phosphite moiety showed that the configuration of the product is controlled by the atropisomerism of the biphenyl substituent at the phosphite moiety. The conformation of the biphenyl group, in turn, is controlled by the substituent at the chiral carbon in the bridge. Ligands with large bite angles yielded higher enantioselectivities. 相似文献
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Gardolinski JE Ramos LP de Souza GP Wypych F 《Journal of colloid and interface science》2000,221(2):284-290
Well-crystallized kaolinite (K) was initially reacted at 60 degrees C with a water/dimethylsulfoxide (DMSO) mixture and the resulting intercalation derivative (K-DMSO) was characterized by powder X-ray diffractometry (PXRD), thermal analysis (simultaneous TG and DSC), and Fourier-transformed infrared spectroscopy (FTIR). Benzamide crystals were then melted with the K-DMSO derivative at 140 degrees C for 4 days, when a gradual displacement of DMSO by benzamide was observed within the interlayer spacing of the modified kaolinite. The resulting material, after extensive washing with acetone, was characterized and compared to the results obtained previously for the K-DMSO composite. Benzamide intercalation proceeded by gradual displacement of DMSO molecules until completion. The structural stabilization of the K-BZ derivative was explained through the establishment of hydrogen bonds between the carbonyl oxygen atoms of the intercalated benzamide and aluminol groups present at the surface of the kaolinite layer. The interlamellar spacing of K-BZ was shown to be possibly occupied by benzamide molecules that were located at a 68 degrees orientation in relation to the layer surface. Unlike most intercalation molecules such as DMSO, variations in the interplanar spacing of kaolinite were consistent with the nonkeying of any other part of the molecule between the aluminosilicate interlayers. Copyright 2000 Academic Press. 相似文献
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Roberto Grisorio Claudia Piliego Paola Fini Pinalysa Cosma Piero Mastrorilli Giuseppe Gigli Gian Paolo Suranna Cosimo Francesco Nobile 《Journal of polymer science. Part A, Polymer chemistry》2008,46(18):6051-6063
The synthesis of new random poly(2,7‐fluorenylene‐vinylene)s was achieved by a Suzuki–Heck cascade polymerization reaction. The poly(fluorenylene‐vinylene) base structure was modified by the regio‐random incorporation of 1‐cyano‐2,5‐phenylene as electron withdrawing unit ( CN‐PFV1 ) and its properties were compared with terpolymers also embodying 1,4‐dioctyloxy‐2,5‐phenylene ( CN‐PFV2 ) or 3,6‐N‐octylcarbazole ( CN‐PFV3 ) as electron‐donating moieties. Thermal analysis revealed a high thermal stability (Td > 389 °C) and the absence of glass transitions for all polymers. Cyclic voltammetry indicated a high electron affinity of the materials (2.96–3.21 eV) attributed to the presence of the cyano‐containing comonomer. In dilute solutions, the copolymers showed a broad green fluorescence with quantum yields ranging from 0.42 to 0.79, while in the solid state, a relatively narrow emission centered at ~ 560 nm, governed by the low‐energy segments within the π‐conjugated backbone, was observed. The electroluminescence properties of the materials were tested in OLED devices of ITO/PEDOT‐PSS/ CN‐PFV1‐3 /Ca/Al or ITO/PEDOT‐PSS/ CN‐PFV1‐3 /Alq3/Ca/Al configurations, showing a bright green‐yellow emission that, in the case of CN‐PFV2 , reached 1403 cd/m2 with efficiencies as high as 0.13 cd/A. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6051–6063, 2008 相似文献
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Roberto Grisorio Pinalysa Cosma Piero Mastrorilli Gian Paolo Suranna Cosimo Francesco Nobile 《Tetrahedron》2008,64(37):8738-8745
The preparation and properties of the first spirocyclohexane-functionalized bifluorene-based monodispersed molecular materials is described. The obtained compounds were characterized by 1H NMR, 13C{1H} NMR, IR, DSC, UV-vis and photoluminescence both in solution and in the solid state. The molecules show emissions ranging from the blue to the blue-green region, and higher glass transition temperatures and spectral stability with respect to the analogous compounds containing 9,9,9′,9′-tetrahexyl-[2,2′]-bifluorene core. The materials were used as active layers in electroluminescent devices with ITO/PEDOT-PSS/SB1-4/Ca/Al and ITO/PEDOT-PSS/SB1-4/BCP/Ca/Al configurations. 相似文献
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A practical synthesis for 9,10-bis(alkoxyphenyl)-2,7-diiodophenanthrenes is described. 9,10-Bis(4-hexyloxyphenyl)-2,7-diiodophenanthrene was selectively obtained by a one-pot reaction of 10,10-bis-(4-hexyloxy-phenyl)-2,7-diiodo-10H-phenanthren-9-one with 1 equiv of triethylsilane in trifluoroacetic acid. The target molecular architecture was demonstrated to be a useful precursor for obtaining the corresponding poly(phenanthrene) and poly(phenanthrylene-vinylene). 相似文献
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Piero Mastrorilli Cosimo Francesco Nobile Gian Paolo Suranna Anna Corradi Cristina Leonelli Paolo Veronesi 《应用有机金属化学》2003,17(9):711-716
Scanning electron microscopy characterization of the materials obtained by homogeneous and heterogeneous catalytic polymerization of phenylacetylene is described. The catalysts used are β‐dioxygenato rhodium(I) complexes. The effects of the reaction medium, presence of a cocatalyst and the type of catalysis (homogeneous or heterogeneous) on the morphology of the polymers obtained have been studied and discussed. Using a supported complex at 0 °C, nanoparticles with a diameter distribution as narrow as 30 to 70 nm were obtained. Polymer nanopowders were found to be unaffected by ageing. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献