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1.
2.
Utpal Majumder 《Tetrahedron letters》2005,46(42):7209-7211
The scope and limitations of the Takai-Utimoto reagent to induce the cyclization of olefinic-esters is described. Critical is the steric environment about both the ester and the olefin. Mechanistically, these results support the hypothesis that cyclized product comes from an olefin metathesis, carbonyl-olefination sequence. 相似文献
3.
Abstract Aloe vera leaf contains some bioactive compounds that have a strong binding affinity toward estrogen receptor as compared to standard drug tamoxifen. In this study, we have found that the IC50 of Aloe vera leaf extract against breast cancer cell line (MCF-7) is 23?µg/mL which is much lower than the IC50 (332?µg/mL) of Aloe vera leaf extract against non-cancerous cell line (NIH-3T3). We have also calculated the total concentration of phenolic acid (385.662?µg/mL), flavonoids (160.402?µg/mL) and alkaloids (276.754?µg/mL) in Aloe vera leaf extract. The free radical scavenging activity of Aloe vera leaf extract is 67% to 89% (at 50 to 300?µg/ml). Our virtual molecular docking study suggests that bioactive compounds like Aloe-emodin (?8.8?Kcal/mol), 7-hydroxy-2,5 dimethylchromone (?7.5?Kcal/mol), Beta-sitosterol (?7.3?Kcal/mol) etc. have a greater binding affinity toward estrogen alpha receptor as compared to standard drug Tamoxifen (?6.4?Kcal/mol). 相似文献
4.
Majumder U Armantrout JR Williams RV Shreeve JM 《The Journal of organic chemistry》2002,67(24):8435-8439
The synthesis and characterization of the first stable trialkyl(difluoroamino)silane, R3SiNF2, as well as of R3SiNHF and R3SiN(CH3)F in moderate yields are reported. The (difluoroamino)silane has promise as a new synthon for the introduction of the -NF2 group into a variety of electrophilic inorganic and organic substrates. Activation barriers and relative energies were calculated for the unimolecular decompositions of Me3SiCF3 and t-Bu3SiNF2 using density functional theory (B3LYP/6-31G). The calculated activation energies confirm the long-assumed kinetic stability of Me3SiCF3. 相似文献
5.
A. Mandal A. Koll A. Filarowski D. Majumder S. Mukherjee 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》1999,55(14):2861
A new orthohydroxy Schiff base, 7-ethylsalicylidenebenzylamine (ESBA) has been synthesised. The excited state intramolecular proton transfer (ESIPT) processes have been investigated by means of absorption, emission and nanosecond spectroscopy at room temperature and at 77 K in non polar solvents. The ESIPT is evidenced by a large Stokes shifted emission (11 000 cm−1) only at 77 K. From fluorescence and excitation spectra it is suggested that at least three different species are present in the excited state at room temperature. Our theoretical calculation at AM1 level confirm the cis-isomer to be the only viable form in the ground state. 相似文献
6.
Pyrimido[4,5-d]pyrimidine derivatives 4 have been prepared in an efficient and regioselective manner in water via multi-component reaction of isothiocyanate 1, aromatic aldehyde 2, N,N-dimethyl-6-amino uracil 3 in the presence of p-toluenesulfonic acid (p-TSA) as a Lewis acid catalyst. 相似文献
7.
The nearside distribution of particles at intermediate transverse momentum, associated with a high momentum trigger hadron produced in a high energy heavy-ion collision, is broadened in rapidity compared with the jet cone. This broadened distribution is thought to contain the energy lost by the progenitor parton of the trigger hadron. We show that the broadening can be explained as the final-state deflection of the gluons radiated from the hard parton inside the medium by soft, transversely oriented, turbulent color fields that arise in the presence of plasma instabilities. The magnitude of the effect is found to grow with medium size and density and diminish with increasing energy of the associated hadron. 相似文献
8.
Barun Majumder 《Physics letters. [Part B]》2011,701(4):384-387
Recently Ali et al. (2009) [13] proposed a Generalized Uncertainty Principle (or GUP) with a linear term in momentum (accompanied by Planck length). Inspired by this idea we examine the Wheeler-DeWitt equation for a Schwarzschild black hole with a modified Heisenberg algebra which has a linear term in momentum. We found that the leading contribution to mass comes from the square root of the quantum number n which coincides with Bekenstein?s proposal. We also found that the mass of the black hole is directly proportional to the quantum number n when quantum gravity effects are taken into consideration via the modified uncertainty relation but it reduces the value of mass for a particular value of the quantum number. 相似文献
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10.
We propose an electronic spin-filter device that uses a nonmagnetic triple barrier resonant tunneling diode (TB-RTD). This device combines the spin-split resonant tunneling levels induced by the Rashba spin-orbit interaction and the spin blockade phenomena between two regions separated by the middle barrier in the TB-RTD. Detailed calculations using the InAlAs/InGaAs material system reveal that a splitting of a peak should be observed in the I-V curve of this device as a result of the spin-filtering effect. The filtering efficiency exceeds 99.9% at the peak positions in the I-V curve. 相似文献