全文获取类型
收费全文 | 154篇 |
免费 | 2篇 |
国内免费 | 2篇 |
专业分类
化学 | 95篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 42篇 |
物理学 | 19篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 6篇 |
2013年 | 5篇 |
2012年 | 6篇 |
2011年 | 8篇 |
2010年 | 5篇 |
2009年 | 3篇 |
2008年 | 8篇 |
2007年 | 6篇 |
2006年 | 10篇 |
2005年 | 7篇 |
2004年 | 9篇 |
2003年 | 7篇 |
2002年 | 14篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有158条查询结果,搜索用时 46 毫秒
1.
2.
3.
A series of P[N-isopropylacrylamide (NIPAM)] latexes with different contents of cyano groups were successfully prepared by either seeded
or shot-growth polymerizations of an aqueous solution containing acrylonitrile (AN) onto a seed P[NIPAM] latex, respectively, and further characterized by FT-IR, 1H-NMR, elemental analysis, as well as by quasielastic light scattering (QELS) and scanning electron microscopy (SEM). All
prepared surface-cyanofunctionalized P[NIPAM] latexes exhibited the same range of lower critical solution temperature (LCST) as a pure P[NIPAM] latex. The shot polymerization process proved more efficient at yielding cyano derivatized latexes than the seeded
polymerization technique. The amount of incorporated cyano groups onto the particles was determined with a good correlation
both by 1H-NMR and elemental analysis. The higher the amount of initially introduced AN monomer in the reaction mixture, the more cyano
groups were incorporated onto the particles. The surface of the particles with high content of cyano groups appeared quite
rough by SEM in comparison with that of the pure P[NIPAM] particles.
Received: 25 February 1998 Accepted: 23 June 1998 相似文献
4.
Batch method was used to investigate the sorption behavior of radioiodine on organic rich soil, alumina, chlorite-illite clay mixture and bentonite.131I was used as tracer. The grain sizes of the samples used were all below 38 m. A rather slow kinetics was observed for the adsorption of radioiodine on organic rich soil. The distribution ratio increased with increasing solution/solid (V/m) ratio, and the contact time. The pH of the synthetic groundwater did not change the distribution ratio appreciably. The soil biomass however, showed a striking effect on the adsorption of radioiodine. Among the clay minerals, the highest distribution ratio value was found for chlorite-illite clay mixture. All the values were however well below those of the organic rich soil. The sorption data were fitted to Freundlich and Dubinin-Radushkevich types isotherms. Means energies of adsorption, as well as the affinity ratios of the sorption sites to iodine and chlorine were calculated. 相似文献
5.
Z. Buyukmumcu H. N. Erten N. K. Aras 《Journal of Radioanalytical and Nuclear Chemistry》1994,181(1):175-188
Extensive experimental and evaluated yield data are now available for the fragments in low energy nuclear fission. Using these data we re-examined the influence of even nuclear numbers and closed shells on the mass and charge distribution in low energy fission. We used WAHL's Zp model and Ap model. We also examined the effects ofZ=50,N=82 and possiblyN=88 shells. A new method was developed based on two Gaussian curves for the even and odd products. TheEOZ andEON values calculated are based on these different methods and are seen to be consistent with each other in spite of the somewhat different definitions of the even-odd effect. The even-odd effect decreases with an increasing fissility parameter. TheEON values are substantially lower than the correspondingEOZ values, probably due to the effect of washing out the neutron pairing effect by prompt neutron emission. The magnitude of the even-odd effect varies with different mass regions. TheEOZ andEON values decrease as they go from asymmetric to symmetric regions in mass distributions. 相似文献
6.
Turan Ozturk Andrey S. Klymchenko Sule Oncul Sule Taskiran F. Betul Kaynak Alexander P. Demchenko 《Tetrahedron》2007,63(41):10290-10299
Nine new 3-hydroxyflavone derivatives as fluorescent molecular sensors having two well-separated emission bands were synthesized. These sensors can occupy well-determined locations and orientations in macromolecular ensembles, such as micelles due to their finely-tuned designs. These polarity-sensitive dyes can incorporate into the anhydrous hydrophobic core of aqueous micelles. 相似文献
7.
S. Tadjiki H. N. Erten J. Erten 《Journal of Radioanalytical and Nuclear Chemistry》1995,199(4):309-316
Instrumental neutron activation analysis has been used to determine 15 trace elements in twelve blood serum samples taken from healthy students at Bilkent University in Ankara. The method allowed the determination of Sc, Cr, Mn, Fe, Co, Zn, Se, Rb, Cs, Ce, Eu, Tb, Hf, Ta and Hg, which occur at the g.ml–1 to ng.ml–1 levels. There are no values reported for Tb, Hf, Ce, Eu and Ta before. The other results are compared with the values reported in the literature. Most are in the range of the reported values except for Fe, Zn, Se and Cs. 相似文献
8.
3-Alkyl(Aryl)-4-amino-4,5-dihydro-1H-1,2,4-triazol-5-ones (2) reacted with 2-furoyl chloride and thiophene-2-carbonyl chloride to afford the corresponding 3- alkyl(aryl)-4-(2-furoylamino)-4,5-dihydro-1H-1,2,4-triazol-5-ones (3) and 3-alkyl(aryl)- 4-(2-thienylcarbonylamino)-4,5-dihydro-1H-1,2,4-triazol-5-ones (4), respectively. The new compounds synthesized were characterized by using IR, 1H-NMR, 13C-NMR and UV spectral data together with elemental analysis. In addition, to investigate the effects of solvents and molecular structure upon acidity, compounds 3 and 4 were titrated potentiometrically with tetrabutylammonium hydroxide in four non-aqueous solvents (isopropyl alcohol, tert-butyl alcohol, N,N-dimethylformamide and acetonitrile). The half-neutralization potential values and the corresponding pKa values were determined for all cases. 相似文献
9.
N. K. Tunali H. N. Erten S. Kinikoğlu Ş. Gümüş 《Journal of Radioanalytical and Nuclear Chemistry》1979,49(2):225-237
The extraction of iodine and bromine under various conditions from their saturated aqueous solutions by CCl4, C6H6 and o-xylene has been studied. The data obtained from the experiments carried out at various temperatures, for H2O(I2)−CCl4 and H2O(I2)−C6H6 systems, exhibit an Arrhenius behaviour. The overall activation energy calculated for the extraction in the H2O(I2)−CCl4 system, 650±50 cal·mol−1 is lower than that of H2O(I2)−C6H6, 3600±300 cal·mol−1. The use of the solubility parameter for the interpretation of the data in the extraction of iodine is investigated. The
data obtained in multiple extractions are treated by using the analogy between extraction and radioactive decay. The half
number of extraction for each system is determined. The complex curves obtained in the H2O(I2)−CCl4 and H2O(I2) −Br2)−CCl4 systems are resolved into two components. 相似文献
10.
The210Pb and137Cs profiles of sediment cores from two locations in southern Spain, three locations in southern Turkey and two locations in northern Cyprus were determined by direct -ray spectroscopy. Sedimentation rates were derived for all locations using the210Pb data. The rates range from 1.39±0.12 cm · y–1 (0.50±0.04 g · cm–2 · y–1) to 0.08±0.01 cm · y–1 (0.039±0.003 g · cm–2 · y–1). Except for one core, the137Cs profiles were also used to compute sedimentation rates. The results are in good agreement with those of210Pb values. The results of the Constant Initial Concenration and Constant Rate of Supply dating models are in good agreement with each other. The flux of unsupported210Pb varies between 0.11±0.03 to 0.74±0.01 pCi · cm–2. The average depositional flux was found to be considerably lower for cores from the Eastern Mediterranean. 相似文献