全文获取类型
收费全文 | 451篇 |
免费 | 30篇 |
国内免费 | 4篇 |
专业分类
化学 | 313篇 |
晶体学 | 6篇 |
力学 | 10篇 |
综合类 | 1篇 |
数学 | 38篇 |
物理学 | 117篇 |
出版年
2024年 | 3篇 |
2023年 | 4篇 |
2022年 | 23篇 |
2021年 | 50篇 |
2020年 | 23篇 |
2019年 | 22篇 |
2018年 | 26篇 |
2017年 | 19篇 |
2016年 | 29篇 |
2015年 | 28篇 |
2014年 | 24篇 |
2013年 | 41篇 |
2012年 | 33篇 |
2011年 | 31篇 |
2010年 | 17篇 |
2009年 | 14篇 |
2008年 | 21篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 6篇 |
2004年 | 1篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有485条查询结果,搜索用时 15 毫秒
1.
2.
Sulaiman Wadi Harun Nizam Tamchek Mohd Kamil Abd-Rahman Prabakaran Poopalan Harith Ahmad 《Optical Review》2003,10(3):133-135
A multiwavelength Brillouin/erbium fibre laser (BEFL) which operates in the long wavelength (L-band) region is demonstrated for potential applications in an L-band wavelength division multiplexing (WDM) communication system. The laser configuration consists of a long erbium-doped fibre to enable L-band amplification where two 3-dB couplers take a portion of the generated BEFL signal and re-inject it into the single mode fibre to seed a cascaded BEFL line in the same direction as the first BEFL line. A stable and strong laser comb of up to five lines with 10-GHz spacing has been obtained with a Brillouin pump (BP) of 9.2 mW and a 980 nm pump of 92 mW. The BEFL has shown a broad tuning range with a tuning characteristic for line #1 which is flat over a range greater than 9.9 nm. 相似文献
3.
Ahmad VU Zubair M Athar Abbasi M Abid Rashid M Rasool N Nahar Khan S Iqbal Choudhary M Kousar F 《Magnetic resonance in chemistry : MRC》2005,43(6):486-488
The investigation of the chemical constituents of Symplocos racemosa Roxb led to the isolation of two new glycosides, symcomoside A (1) and symcomoside B (2), together with one known glycoside, tortoside C (3), which is reported for the first time from this plant. The structures of the new compounds were determined by 1D and 2D homonuclear and heteronuclear NMR spectroscopy, from chemical evidence and by comparison with published data for closely related compounds. Symcomoside B (2) showed potent inhibitory activity against alpha-glucosidase in a concentration-dependent fashion with an IC50 value of 0.733 +/- 0.033 mM whereas symcomoside A (1) showed very weak inhibitory activity against alpha-glucosidase (9.90% in 0.70 mM). 相似文献
4.
The dependence of the diffusion parameters including slowing down area, neutron diffusion length and migration length on the voided volume fraction in water has been studied experimentally. For this purpose, the PIEAS Neutron Transport Facility (PNTF) comprised of a 10 Ci Am–Be neutron source and a water filled aluminum tank with Perspex voided tubes has been designed and fabricated. A BF3 detector was used for the neutron counting. The slowing down area was determined at the cadmium cutoff level. The diffusion parameters were determined first in the absence of voids. The experimentally measured values of the slowing down area, the diffusion length and the migration length have been found in good agreement with the corresponding values determined by other workers. By varying void volume fraction from 0% to 7.5%, the experimental measurements show a monotonic increase in the slowing down area from 58.71±2.6 to 71.28±3.2 cm2, in the diffusion length from 2.95±0.13 to 3.11±0.13 cm and in the migration length from 8.21±0.165 to 8.99±0.169 cm. Our measurements show that the diffusion parameters exhibit a quadratic dependence on the void volume fraction. 相似文献
5.
S. N. Basahel A. A. El Bellihi H. M. El Diefallah 《Journal of Thermal Analysis and Calorimetry》1993,39(1):87-95
The effects of60Co-gamma radiation and of various sample composition on the reduction of hematite to iron in the graphite-iron(III) oxide system in air were studied using isothermal and dynamic TG techniques. Kinetic analysis of isothermal data were performed according to various theoretical models of heterogeneous reactions and the results showed that the three-dimensional phase boundary model gives the best fit of data. Analysis of dynamic TG data were made using Ozawa integral method, Coats-Redfern method and a composite method based on the modified Coats and redfern equation. The activation parameters were calculated and the results of the different methods were compared and discussed.Radiation apparently did not introduce a change in the reaction model or mechanism. However, there is a decrease in activation energy and frequency factor upon irradiation and a decrease in the half-life time of the reaction which is remarkable at the higher temperatures and higher doses.
Zusammenfassung Mittels isothermer und dynamischer TG wurde im Graphit-Eisen(III)oxidsystem in Luft der Einfluß von60Co-Gammastrahlung und von verschiedenen Probenzusammensetzungen auf die Reduktion von Hämatit zu Eisen untersucht. Entsprechend verschiedener theoretischer Modelle heterogener Reaktionen wurde eine kinetische Analyse der isothermen Daten durchgeführt und die Ergebnisse zeigten, daß das dreidimensionale Phasengrenzenmodell die beste Übereinstimmung liefert. Die Analyse der dynamischen TG-Daten wurde mittels der Integralmethode von Ozawa, der Coats-Redfem-Methode und einer zusammengesetzten Methode auf der Grundlage der modifizierten Coats und Redfern Gleichung durchgeführt. Die Aktivierungsparameter wurden berechnet und die Ergebnisse der verschiedenen Methoden miteinander verglichen und diskutiert.Strahlung scheint keine Änderung des Reaktionsmodelles oder des Mechanismus hervorzurufen. Durch Bestrahlung gibt es aber ein Absinken der Aktivierungsenergie und des Frequenzfaktors sowie ein Absinken der Halbwertszeit der Reaktion, was bei höheren Temperaturen und höherer Dosis bemerkenswert groß ist.相似文献
6.
QUANTITATION OF PYRIMIDINE DIMERS BY IMMUNOSLOT BLOT FOLLOWING SUBLETHAL UV-IRRADIATION OF HUMAN CELLS 总被引:6,自引:0,他引:6
Altaf A. Wani Steven M. D'Ambrosio Nasir K. Alvi 《Photochemistry and photobiology》1987,46(4):477-482
An immunoslot blot assay was developed to detect pyrimidine dimers induced in DNA by sublethal doses of UV (254 nm) radiation. Using this assay, one dimer could be detected in 10 megabase DNA using 200 ng or 0.5 megabase DNA using 20 ng irradiated DNA. The level of detection, as measured by dimer specific antibody binding, was proportional to the dose of UV and amount of irradiated DNA used. The repair of pyrimidine dimers was measured in human skin fibroblastic cells in culture following exposure to 0.5 to 5 J m-2 of 254 nm UV radiation. The half-life of repair was approximately 24, 7 and 6 h in cells exposed to 0.5, 2 and 5 J m-2 UV radiation, respectively. This immunological approach utilizing irradiated DNA immobilized to nitrocellulose should allow the direct quantitation of dimers following very low levels of irradiation in small biological samples and isolated gene fragments. 相似文献
7.
Differential pulse polarographic determination of some organotin(IV) compounds in dimethyl sulfoxide
The differential pulse polarographic behavior of two series of organotin(IV) compounds having the general formula RxSnCl4 − x (R = Me, Ph; x = 1, 2, 3, 4) has been investigated in DMSO. The peaks obtained are recommended for the trace determination of these compounds. Linear calibration curves are obtained over the concentration range 10−4 –10−6 M. 相似文献
8.
Abdullah Y. Obaid Suliman N. Basahel El-Hussieny M. Diefallah 《Journal of Radioanalytical and Nuclear Chemistry》1990,139(2):355-365
60Co-gamma radiolysis of 3-iodotyrosine and 3,5-diiodotyrosine in aqueous-ethanol solutions has shown that the chemical effects are mainly determined by the interaction of radicals from the radiolysis of solvent and controlled by the composition of the solution. The influence of varying solvent composition and radiation dose on the amount of iodoamino acid converted and on the yields of the radiolysis products (I2, I–, IO
3
–
and H2O2) formed in aerated solutions at room termperature were investigated. The formation of I2 is dependent upon the acidity of the solution and is mainly produced as an after-effect due to the interaction of H2O2 with I– ions, both being radiolysis products. The variation of radiation-chemical yields with the solute and solvent composition, and the probable mechanisms for formation of the radiolysis products are discussed. 相似文献
9.
Synthesis,anti‐migration and burning rate catalytic mechanism of ferrocene‐based compounds 下载免费PDF全文
Zain‐ul ‐Abdin Haojie Yu Li Wang Muhammad Saleem Hamad Khalid Nasir M. Abbasi Muhammad Akram 《应用有机金属化学》2014,28(8):567-575
One of the most important components of solid rocket propellant is the burning rate catalysts (BRC) which enhance burning rate of solid composite propellant. Low‐pressure exponents and stable burning rate are the key features of an excellent solid propellant. Addition of BRC to the propellant results in the increase of burning rate of the propellant and decrease in pressure exponents. Among all BRC, ferrocene‐based BRC have attracted much attention because of their better microscopic homogeneities in distribution, ignitability of the propellants and good compatibility with organic binder. However, the main barrier for the development and practical applications of ferrocene‐based BRC is their migration property. This article reviews the field and highlights recent progress. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
10.
We demonstrate a switchable Q-switched and mode-locked erbium-doped fiber laser (EDFL) operating in the L-band region using the nonlinear polarization rotation effect. The switching operation is achieved by controlling intensity-dependent loss using a polarization controller. In Q-switching mode, the EDFL produces a pulse train with a repetition rate of 21.1 kHz, pulse width of 7.7 #s, and pulse energy of 13.6 nJ. The EDFL also generates a multi-wavelength comb with a very narrow and constant wavelength spacing of 0.045 nm and optical signal-to-noise ratio of at least l0 dB. During mode locking, the EDFL produces stretched pulses with 3-dB bandwidth of 26.2 nm, pulse width of 350 fs, repetition rate of 2.38 MHz, and pulse energy of 48.56 pJ. 相似文献