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1.
Debendra K. Mohapatra Dhananjoy Mondal Mukund S. Chorghade Mukund K. Gurjar 《Tetrahedron letters》2006,47(52):9215-9219
The non-proteinogenic amino acid 3-hydroxy-4-methylproline (HMP) is an active constituent of some potent antimicrobials including echinocandins, nostopeptins, pneumocandins, sporiofungin and mulundocandins. A synthesis has been achieved in 10 steps with 29% overall yield; the Evans’ aldol reaction using Crimmins’ modified method was pivotal to the success of the strategy. 相似文献
2.
The complete proofs of Krein’s theorem on the spectral shift function and the trace formula are given for a pair of self-adjoint
operators such that either (i) their difference is trace-class or (ii) the difference of their resolvents is trace-class.
The proofs, essentially due to Krein, is based on Herglotz’s theorem on the boundary value of the analytic functions whose
imaginary part is non-negative on the upper half plane, and an almost optimal class of functions are obtained for which the
trace formula is valid. Also an alternative method based on Weyl-von Neumann’s theorem for self-adjoint operators, avoiding
the complex function theory and inspired by Voiculescu’s work, is given for the first case. Furthermore, some applications
of the spectral shift function have been discussed. 相似文献
3.
Starting with the unification hypothesis of mixings of quarks and leptons and small quark-like mixings at the see-saw scale,
we find that two large mixings for νe —νx03BC; andv
μ—v
τ at the weak scale are obtained as a result of renormalization group evolution and radiative magnification if the three neutrinos
are quasi degenerate in masses and possess the same CP parity. We also find thatU
e3
remains small and well within the CHOOZ-Palo Verde bound since the correspondingV
ub
for CKM mixing is very small. Several testable pedictions are pointed out. 相似文献
4.
5.
6.
Mukund K. Gurjar Seetaram Mohapatra Usha D. Phalgune Vedavati G. Puranik Debendra K. Mohapatra 《Tetrahedron letters》2004,45(42):7899-7902
An enantioselective synthesis of the C12-C29 fragment of amphidinolide E is described. Key transformations include an intramolecular mercuriocyclization reaction, stereoselective introduction of methyl group at the C2 position, and Stille coupling for the introduction of the diene side chain. 相似文献
7.
Dilatometry is a technique for precise measurement of thermal dilatation of materials during heating or cooling. A procedure has been presented for calibration of a differential dilatometer operating with electromagnetic heating for metallic specimens both upon heating and cooling as well as under uniaxial compressive and tensile loading. The dilation signal has been calibrated for both heating and cooling and for uniaxial loading (compressive and tensile) using platinum or iron reference specimens, for which recommended dilational data are available. The ferro- to paramagnetic transition (characterised by the Curie temperature) of pure iron or iron-based alloys has been adopted to calibrate the temperature in the dilatometric measurement under different loading modes during heating and cooling. On this basis calibrated data for the thermal expansion coefficients of Fe and Fe-Ni alloys have been obtained. 相似文献
8.
9.
10.
The extraction behaviour of thorium(IV) from aqueous nitric acid employing 3-phenyl-4-benzoyl-5-isoxazolone (HPBI) in the presence of tri-n-octyl phosphine oxide (TOPO) as well as tri-n-butyl phosphate (TBP) in xylene medium was investigated. The extraction constant (log k(ex)) for the binary organic phase species Th(PBI)(4) was determined to be 8.26 which is by far the largest amongst the corresponding values known for other beta-diketones. The overall extraction constant (log K) for the ternary species Th(PBI)(4) TBP and Th(PBI)(4).2TOPO were estimated to be 14.96 and 20.96 respectively. An inverse correlation of the adduct formation constant (log K(s)) with the pK(a) of the beta-diketones, 2-thenoyltrifluoroacetone, 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone and HPBI, was observed. The steric as well as the electronic effects of adduct formation have been discussed. Analytical application of HPBI for the separation of (234)Th radiotracer from natural uranium (99.3% (238)U) has been suggested. 相似文献