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Munmaya K. Mishra Subasini Lenka Padma L. Nayak 《Journal of polymer science. Part A, Polymer chemistry》1981,19(10):2457-2464
Photopolymerization of MMA was carried out with quinaldine–bromine (QN–Br2) and lutidine–bromine (LU–Br2) charge-transfer complexes as initiators. The rate of polymerization Rp increased with rising monomer concentration and the monomer exponent was computed as unity. At first the rate of polymerization accelerated and then reduced as the initiator concentration was increased. The initiator exponent was 0.5. The reaction was carried out at three different temperatures and overall activation energy was calculated at 4.0 kcal/mol. The kinetic data and other evidence indicate that the overall polymerization takes place in a radical mechanism. A suitable mechanism is suggested. 相似文献
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Nrusingha C. Pati Subasini Lenka Padma L. Nayak Trijama R. Mohanty 《Journal of polymer science. Part A, Polymer chemistry》1978,16(2):343-351
The aqueous polymerization of acrylonitrile initiated by an acidified bromate–thiourea redox system has been studied under nitrogen atmosphere. The rate of polymerization is independent of thiourea concentration over the range 2–9 × 10?3M and reaches maximum at 9 × 10?3M. The rate varies linearly with [monomer]. The initial rate of polymerization as well as the maximum conversion increases within the range of 4–22.5 × 10?3M KBrO3, but beyond 22.5 × 10?3M the rate of polymerization decreases. The initial rate and the limiting conversion increases with increasing polymerization temperature in the range 30–45°C; and beyond 45°C they decrease. The effect of certain neutral salts, water-soluble solvents, and micelles of cationic, anionic, and nonionic surfactants on the rate of polymerization has been investigated. 相似文献
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Graft copolymerization of methyl methacrylate onto wool was investigated in aqueous solution using the potassium peroxy-diphosphate-thiourea redox system as the initiator. The rate of grafting was determined by varying the monomer, peroxydi-phosphate ion, temperature, and solvent. The graft yield increases with increasing peroxydiphosphate ion up to 80 × 10?-4 mol/L, and with further increase of peroxydiphosphate ion the graft yield decreases. The graft yield increases with increasing monomer concentration. The percentage of grafting decreases with increasing thiourea concentration. The rate of grafting increases with an increase of temperature. The effect of acid and water-soluble solvent and certain salts on graft yield has been investigated and a suitable rate expression has been derived. 相似文献
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The graft copolymerization of methyl methacrylate onto poly-(ethylene terephthalate) using metal complexes of Mn3+, Co3+, and Fe3+ as initiators was studied. The rate of polymerization, Rp, increased with increasing complex concentrations. The rate of polymerization was also studied by varying monomer concentrations. Increasing monomer concentrations, the rate of polymerization increases significantly. The graft yield increases with increasing temperature within the range 60–75°C. The graft yield is medium dependent. A suitable kinetic scheme has been pictured and rate equations have been derived. 相似文献
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The graft copolymerization of methyl methacrylate onto silk fibers in aqueous solution with the use of manganese (IV) ions as initiator was investigated. The rate of grafting was determined by varying monomer, acidity of the medium, temperature, nature of silk, and the reaction medium. The graft yield increases significantly with increase of manganese (IV) concentration up to 15 meq/liter; with further increase of manganese (IV) concentration, the graft yield decreases. The effect of the increase of monomer concentration brings about a significant enhancement in the graft yield up to 7%, and with further increase of monomer concentration the graft yield decreases. The graft yield is considerably influenced by chemical modification prior to grafting. The effect of some inorganic salts and anionic surfactants on the rate of grafting has been investigated. 相似文献
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Subasini Lenka Padma L. Nayak Suparna Ray 《Journal of polymer science. Part A, Polymer chemistry》1984,22(4):959-965
The aqueous polymerization of acrylic acid and acrylamide initiated by peroxydiphosphate–sodium thiosulfate redox system was investigated within the temperature range of 25–35°C. The rates of polymerization were measured at different concentrations of oxidant, activator and monomer. The monomer and the initiator exponents were evaluated to be 1.12 and 0.51. The rate of polymerization decreases with increasing thiosulfate concentration. On the basis of the experimental observation of the dependence of the rate of polymerization, Rp, on various variables, a suitable kinetic scheme has been proposed and the rate parameters have been evaluated. 相似文献
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Subasini Lenka Padma L. Nayak Sanjay K. Nayak 《Journal of polymer science. Part A, Polymer chemistry》1987,25(2):703-709
Aqueous polymerization of methyl methacrylate in visible light was studied using isoquinoline–sulphur dioxide (IQ–SO2) charge–transfer complex as the photoinitiator. Analysis of kinetic and other data indicate that the polymerization proceed via a radical mechanism and the termination is dependent on the initiator concentration. Chain–termination via degradative chain (initiator) transfer appears to be predominant here. 相似文献
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