全文获取类型
收费全文 | 189篇 |
免费 | 53篇 |
国内免费 | 8篇 |
专业分类
化学 | 90篇 |
力学 | 21篇 |
数学 | 12篇 |
物理学 | 127篇 |
出版年
2022年 | 4篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 2篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2012年 | 5篇 |
2011年 | 6篇 |
2010年 | 16篇 |
2009年 | 7篇 |
2008年 | 9篇 |
2007年 | 3篇 |
2006年 | 2篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 2篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 8篇 |
1998年 | 2篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 9篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1971年 | 3篇 |
1966年 | 2篇 |
1965年 | 10篇 |
1964年 | 6篇 |
1963年 | 3篇 |
1959年 | 12篇 |
1958年 | 4篇 |
1955年 | 4篇 |
1954年 | 3篇 |
1939年 | 2篇 |
1935年 | 2篇 |
1890年 | 2篇 |
1881年 | 2篇 |
排序方式: 共有250条查询结果,搜索用时 15 毫秒
1.
P. Stumpf W. Barrett N. Popplewell A.H. Shah S. Balakrishnan 《Experimental Techniques》1994,18(4):34-37
It is common practice in power transmission to use bundled overhead electrical conductors because the lower rate of corona discharge, compared with single conductors, makes the bundle attractive for high voltages. However, secondary problems may arise from the vibrations induced by the aerodynamic forces which act on the leeward conductors as a result of their immersion in the wake of a windward conductor. Thus, in addition to possible aeolian and galloping oscillations observed for a single conductor, bundle conductors may also be subjected to wake-induced oscillations. 1,2 Although extensive research has been done on the aeroelastic behavior of single and bundled conductors which are bare, little is known about the galloping or wake oscillation characteristics of given bundle conductors which, depending upon the environmental conditions during the formation of ice, may have five or so representative shaped cross-sections. One important task involves the aerodynamic quasi-static force and moment measurements in a wind tunnel using full scale conductor cross-sections each of which must be rotated through many angles at different spacings. Such measurements are repetitive as well as tediously time consuming and, hence, are beneficially automated. A reliable, accurate and inexpensive automated apparatus is described in this paper which permits the aerodynamic measurements to be performed efficiently and without intervention. Most importantly, it relieves the operator of the usual responsibility for manually controlling the separation and orientation of the sections as well as the need to manually compensate fluctuations in the free stream air speed. For simplicity, the apparatus is detailed in the context of a twin bundle conductor. 相似文献
2.
Plumb RS Stumpf CL Gorenstein MV Castro-Perez JM Dear GJ Anthony M Sweatman BC Connor SC Haselden JN 《Rapid communications in mass spectrometry : RCM》2002,16(20):1991-1996
The application of liquid chromatography/mass spectrometry (LC/MS) followed by principal components analysis (PCA) has been successfully applied to the screening of rat urine following the administration of three candidate pharmaceuticals. With this methodology it was possible to differentiate the control samples from the dosed samples and to identify the components of the mass spectrum responsible for the separation. These data clearly show that LC/MS is a viable alternative, or complementary, technique to proton NMR for metabonomics applications in drug discovery and development. 相似文献
3.
A method for quantitative measurement of the photochemical decomposition of the anti-inflammatory agent, indoprofen (INP) is descriped. An RPLC-based assay that could determine the extent of degradation of INP in a rapid, sensitive, and accurate manner was developed. The method was validated under photoirradiation. Quantitation was monitored with an Inertsil ODS-3V column using a mobile phase of acetonitril and 1% HOAc solution in deionized H2O. Statistics relevant to the system criteria, peak integrity and resolution among the parent drug and its degradation products were performed. From the intra- and inter-day tests, the coefficients of variation were found to range from 0.59% to 4.25% for the former and from 0.71% to 4.86% for the latter. The good selectivity and specificity of this RPLC-based procedure render it suitable for measurements of INP stability. 相似文献
4.
5.
Silvia Stumpf Gudrun Goretzki Kerstin Gloe Karsten Gloe Wilhelm Seichte Edwin Weber Jan W. Bats 《Journal of inclusion phenomena and macrocyclic chemistry》2003,45(3-4):225-233
The di- and tetra-allyl ethers of tert-butylcalix[4]arene 1 and 2 have been prepared by alkylation of tert-butylcalix[4]arene with allyl bromide and K2CO3 using different reaction times. Solution 1H NMR measurement of the di-allyl ether 1 and X-ray crystal structures of the complexes of 1 with chloroform (1a) or methanol (1b) indicate the cone conformation of 1 in which intramolecular hydrogen bonding can be maximized. The crystalline state conformers 1a and 1b are distorted in different grades depending on the solvent. While methanol is incorporated in the macrocycle, chloroform molecules do not occupy the cage. The solution 1H NMR spectra of tetra-allyl ether 2 show the co-existence of the cone and partial cone conformation. The partial cone conformer of 2 was investigated by X-ray crystallography. In this compound hydrogen bonding is not existent. The conformer distribution is likely affected by steric and template effects. 相似文献
6.
Abstract— The Stern-Volmer constants for fluorescence quenching by tetramethylethylene decrease in the order DMC ≫ DHP > F-2 > 8-MOP. The same order was observed for the quantum yields of [2+2] cycloaddition reaction with tetramethylethylene on direct irradiation. In [2+2] photocycloaddition of F-2 with tetramethylethylene in ethanol, the ratio of quantum yields deduced from singlet and triplet states of F-2; φ3 0 /φ1 0 , is about 5. The excited triplet state is the reactive state for the [2+2] photocycloaddition of F-2 with tetramethylethylene in solution but the excited singlet state of F-2 becomes very important in biological conditions. 相似文献
7.
AntnioF.DeC. Alcntara MariaG.F. Vaz HumbertoO. Stumpf Dorila Pil‐Veloso WagnerB. DeAlmeida 《Helvetica chimica acta》2004,87(2):425-438
Conformational studies of 1,3‐dihydroxy‐4,4,5,5‐tetramethyl‐2‐(pyridin‐1‐yl)imidazolidine ( 1a ) and 1,3‐dihydroxy‐4,4,5,5‐tetramethyl‐2‐(pyridin‐3‐yl)imidazolidine ( 1b ), carried out by using 1D 1H‐ and 13C‐NMR and 2D HMQC, HMBC, and NOESY experiments and with the aid of theoretical calculations, indicate that the OH groups are trans to the pyridinyl substituent. Because the two 1H‐NMR signals of the Me groups are distinguishable and do not change between 290 and 380 K, it is proposed that 1a and 1b have each only one conformation in this temperature range. This behavior was not found with 1,3‐dihydroxy‐4,4,5,5‐tetramethyl‐2‐(pyridin‐2‐yl)imidazolidine ( 1c ) because its Me 1H‐NMR signals cross over at 300 K. Hence, more than one conformation must be present, beyond those produced by simple inversions. Theoretical calculations including temperature and solvent effects were performed to provide further information on the conformational analysis and to help to assign the NMR data. The combination of NMR measurements and quantum‐chemical calculations is shown to be a very promising strategy for conformational analysis studies in solution. 相似文献
8.
Kwok-Pun HO 《数学物理学报(B辑英文版)》2021,(4):1263-1274
Boyd's interpolation theorem for quasilinear operators is generalized in this pa-per,which gives a generalization for both the Marcinkiewicz interpolation theor... 相似文献
9.
10.
This paper is devoted to the quasilinear equation ■where p 2,Ω is a(bounded or unbounded) domain of R~N,w_1,w_2 are nonnegative continuous functions and f is an increasing function. We establish a Liouville type theorem for nontrivial stable solutions of the equation under some mild assumptions on Ω,w_1, w_2 and f, which extends and unifies several results on this topic. 相似文献