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1.
Claudia Poloni Marc C. A. Stuart Pieter van der Meulen Wiktor Szymanski Ben L. Feringa 《Chemical science》2015,6(12):7311-7318
The external photocontrol over peptide folding, by the incorporation of molecular photoswitches into their structure, provides a powerful tool to study biological processes. However, it is limited so far to switches that exhibit only a rather limited geometrical change upon photoisomerization and that show thermal instability of the photoisomer. Here we describe the use of an overcrowded alkene photoswitch to control a model β-hairpin peptide. This photoresponsive unit undergoes a large conformational change and has two thermally stable isomers which has major influence on the secondary structure and the aggregation of the peptide, permitting the phototriggered formation of amyloid-like fibrils. 相似文献
2.
Stuart S. Antman 《Journal of Elasticity》2003,70(1-3):55-64
The introduction of artificial viscosity into the partial differential equations of mechanics is often useful for both analytic and numerical studies. The traditional forms of artificial viscosity, originally designed to treat problems for fluids, when applied to problems for solids often lead to equations describing material properties that are not invariant under rigid motions. Consequently, for rapidly rotating bodies, artificial viscosity could produce serious errors. In this paper it is shown how to introduce artificial viscosity in a properly invariant way, and that the resulting systems have a rich and attractive structure, which beckons analysis. 相似文献
3.
Christopher E. Stuart Paul Abraham 《Journal of Mathematical Analysis and Applications》2004,300(2):224-361
Generalizations of the Nikodym boundedness and Vitali–Hahn–Saks theorems for scalar-valued measures on rings of sets that are in general not σ-rings are presented. As a consequence, the rings of subsets of N with density zero and uniform density zero are shown to have the Nikodym property. In addition, vector measure generalizations of the Vitali–Hahn–Saks theorem are given. 相似文献
4.
Stuart P. RomerilVictor Lee Jack E. Baldwin Timothy D.W. ClaridgeBarbara Odell 《Tetrahedron letters》2003,44(42):7757-7761
The absolute configuration of the marine sponge alkaloid pyrinodemin A is established by organic synthesis. 相似文献
5.
For a conformal manifold we introduce the notion of an ambient connection, an affine connection on an ambient manifold of
the conformal manifold, possibly with torsion, and with conditions relating it to the conformal structure. The purpose of
this construction is to realise the normal conformal Tractor holonomy as affine holonomy of such a connection. We give an
example of an ambient connection for which this is the case, and which is torsion free if we start the construction with a
C-space, and in addition Ricci-flat if we start with an Einstein manifold. Thus, for a C-space this example leads to an ambient metric in the weaker sense of Čap and Gover, and for an Einstein space to a Ricci-flat
ambient metric in the sense of Fefferman and Graham.
Current address for first author: Erwin Schr?dinger International Institute for Mathematical Physics (ESI), Boltzmanngasse
9, 1090 Vienna, Austria
Current address for second author: Department of Mathematics, University of Hamburg, Bundesstra?e 55, 20146 Hamburg, Germany 相似文献
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The potential role of ultrasound in differentiating solid and cystic swellings of the true vocal fold 总被引:3,自引:0,他引:3
John S. Rubin Stuart Lee John McGuinness Ian Hore David Hill Leslie Berger 《Journal of voice》2004,18(2):231-235
This study was designed to investigate the potential role of ultrasound in the diagnosis of cysts of the true vocal fold. Materials and Methods: Grayscale ultrasound of the larynx was carried out in 29 patients with a swelling of the true vocal fold and dysphonia. The findings were then compared with those at subsequent microlaryngoscopy, in the majority of cases. Results and Conclusions: Whereas preoperative laryngeal ultrasound correctly predicted the surgical findings of a cystic lesion in only 5 of 11 cases, it correctly identified that no cyst was present in 15 of 16 instances when this had been queried. This study suggests that ultrasound may have some role in investigation of unilateral vocal fold pathology, but that further fine-tuning of the technique may be necessary. 相似文献
10.
M. A. Cohen Stuart G. J. Fleer B. H. Bijsterbosch 《Journal of colloid and interface science》1982,90(2)
The adsorption of the flexible, linear, and nonionic homopolymer poly(vinyl pyrrolidone) from water and from 1,4-dioxane onto pyrogenic silica was studied. Results are reported for the adsorbed amount as a function of adsorption time, molecular mass, and molecular mass distribution (polydispersity). It is found that the adsorption of fractionated samples can be qualitatively explained by the recent theory of Scheutjens and Fleer. However, the influence of the solvent type is larger than predicted by this theory, and an extension of the model to account for this influence is suggested. The polydispersity effects encountered in adsorption isotherms are satisfactorily accounted for by a theory published by Cohen Stuart, Scheutjens, and Fleer. 相似文献