全文获取类型
收费全文 | 3687篇 |
免费 | 219篇 |
国内免费 | 18篇 |
专业分类
化学 | 2382篇 |
晶体学 | 20篇 |
力学 | 82篇 |
数学 | 582篇 |
物理学 | 858篇 |
出版年
2023年 | 35篇 |
2022年 | 25篇 |
2021年 | 58篇 |
2020年 | 76篇 |
2019年 | 89篇 |
2018年 | 49篇 |
2017年 | 50篇 |
2016年 | 152篇 |
2015年 | 144篇 |
2014年 | 152篇 |
2013年 | 208篇 |
2012年 | 264篇 |
2011年 | 302篇 |
2010年 | 154篇 |
2009年 | 136篇 |
2008年 | 239篇 |
2007年 | 175篇 |
2006年 | 179篇 |
2005年 | 158篇 |
2004年 | 150篇 |
2003年 | 115篇 |
2002年 | 104篇 |
2001年 | 80篇 |
2000年 | 60篇 |
1999年 | 43篇 |
1998年 | 35篇 |
1997年 | 41篇 |
1996年 | 58篇 |
1995年 | 56篇 |
1994年 | 51篇 |
1993年 | 45篇 |
1992年 | 46篇 |
1991年 | 32篇 |
1990年 | 31篇 |
1989年 | 29篇 |
1988年 | 20篇 |
1987年 | 21篇 |
1986年 | 22篇 |
1985年 | 28篇 |
1984年 | 19篇 |
1983年 | 11篇 |
1982年 | 16篇 |
1981年 | 8篇 |
1980年 | 12篇 |
1978年 | 16篇 |
1977年 | 12篇 |
1976年 | 12篇 |
1975年 | 9篇 |
1973年 | 12篇 |
1971年 | 7篇 |
排序方式: 共有3924条查询结果,搜索用时 140 毫秒
1.
2.
3.
Andrea Mühlbauer Stephan Seip Alexander Nowak VanSung Tran 《Helvetica chimica acta》2003,86(6):2065-2072
Chemical investigation of the roots of the Vietnamese plant Tacca paxiana resulted in the isolation of five new steroidal compounds, taccalonolide R ( 6 ), S ( 7 ), T ( 8 ), U ( 9 ), and V ( 10 ). Their structures were established on the basis of NMR and mass‐spectral data. In addition, the five known taccalonolides A ( 1 ), B ( 2 ), E ( 3 ), K ( 4 ), and N ( 5 ) were also isolated and identified. 相似文献
4.
Stephan Kreutzer 《Annals of Pure and Applied Logic》2004,130(1-3):61-78
We study the relationship between least and inflationary fixed-point logic. In 1986, Gurevich and Shelah proved that in the restriction to finite structures, the two logics have the same expressive power. On infinite structures however, the question whether there is a formula in IFP not equivalent to any LFP-formula was left open.
In this paper, we answer the question negatively, i.e. we show that the two logics are equally expressive on arbitrary structures. We give a syntactic translation of IFP-formulae to LFP-formulae such that the two formulae are equivalent on all structures.
As a consequence of the proof we establish a close correspondence between the LFP-alternation hierarchy and the IFP-nesting depth hierarchy. We also show that the alternation hierarchy for IFP collapses to the first level, i.e. the complement of any inflationary fixed point is itself an inflationary fixed point. 相似文献
5.
We present a systematic comparison of the correlation contribution at the level of the second-order polarization propagator approximation (SOPPA ) and MP 2 to the static dipole polarizability of (1) Be, BeH?, BH, CH+, MgH?, AIH, SiH+, and GeH+; (2) BH3, CH4, NH3, H2O, HF, BF, and F2; and (3) N2, CO, CN?, HCN, C2H2, and HCHO . Fairly extended basis sets were used in the calculations. We find that the agreement with experimental values is improved in SOPPA and MP .2 over the results at the SCF level. The signs and magnitudes of the correlation contribution in SOPPA are similar to those obtained in analytical derivative MP 2 calculations. However, it is not possible to say, in general, which method gives the largest correlation contribution or the best agreement with experiment, nor is it possible to make a priori prediction of the sign of the correlation contribution. For the first group of molecules, which have a quasi-degenerate ground state, additional CCDPPA and CCSDPPA calculations were performed and compared with polarizabilities obtained as analytical/numerical derivatives of the CCD and CCSD energies. The CCSDPPA results were found to be in better agreement with other calculations than were the SOPPA results, demonstrating the necessity of using methods based on infinite-order perturbation theory for these systems. © 1994 John Wiley & Sons, Inc. 相似文献
6.
S. Heinze P. Kurz D. Wortmann G. Bihlmayer S. Blügel 《Applied Physics A: Materials Science & Processing》2002,75(1):25-36
In this paper we present a density functional theory investigation of complex magnetic structures in ultra-thin films. The
focus is on magnetically frustrated antiferromagnetic Cr and Mn monolayers deposited on a triangular lattice provided by a
Ag (111) substrate. This involves non-collinear magnetic structures, which we treat by first-principles calculations on the
basis of the vector spin-density formulation of the density functional theory. We find for Cr/Ag (111) a coplanar non-collinear
periodic 120° Néel structure, for Mn/Ag (111) a row-wise antiferromagnetic structure, and for Fe/Ag (111) a ferromagnetic
structure as magnetic ground states. The spin-polarized scanning tunneling microscope (SP–STM) operated in the constant-current
mode is proposed as a powerful tool to investigate complex atomic-scale magnetic structures of otherwise chemically equivalent
atoms. We discuss a recent application of this operation mode of the SP–STM on Mn/W (110), which led to the first observation
of a two-dimensional antiferromagnet on a non-magnetic metal. The future potential of this approach is demonstrated by calculating
SP–STM images for different magnetic structures of Cr/Ag (111). The results show that the predicted non-collinear magnetic
ground state structure can clearly be discriminated from competing magnetic structures. A general discussion of the application
of different operation modes of the SP–STM is presented on the basis of the model of Tersoff and Hamann.
Received: 07 May 2001 / Accepted: 23 July 2001 / Published online: 3 April 2002 相似文献
7.
Gabriel N. Gatica Ernst P. Stephan 《Numerical Methods for Partial Differential Equations》2002,18(1):105-128
This article deals with an expanded mixed finite element formulation, based on the Hu‐Washizu principle, for a nonlinear incompressible material in the plane. We follow our related previous works and introduce both the stress and the strain tensors as further unknowns, which yields a two‐fold saddle point operator equation as the corresponding variational formulation. A slight generalization of the classical Babu?ka‐Brezzi's theory is applied to prove unique solvability of the continuous and discrete formulations, and to derive the corresponding a priori error analysis. An extension of the well‐known PEERS space is used to define an stable associated Galerkin scheme. Finally, we provide an a posteriori error analysis based on the classical Bank‐Weiser approach. © 2002 John Wiley & Sons, Inc. Numer Methods Partial Differential Eq 18: 105–128, 2002 相似文献
8.
V Ravindran Pankaj Agrawal Rahul Basu Satyaki Bhattacharya J Blümlein V Del Duca R Harlander D Kosower Prakash Mathews Anurag Tripathi 《Pramana》2006,67(5):983-992
This is the report of the subgroup QCD of Working Group-4 at WHEPP-9. We present the activities that had taken place in the
subgroup and report some of the partial results arrived at following the discussion at the working group meetings. 相似文献
9.
We report the properties of a compact diode-pumped continuous-wave Nd:GdV04 laser with a linear cavity and different Nd-doped laser crystals. In a 0.2at.% Nd-doped Nd:GdVO4 laser, 1.54 W output laser power is achieved at 912nm wavelength with a slope efficiency of 24.8% at an absorbed pump power of 9.4W. With 0.3at.% Nd-doping concentration, we can obtain the either single-wavelength emission at 1064nm or 912nm or the dual-wavelength emission at 1064nm and 912nm by controlling the incident pump power. From an incident pump power of 11.6 W, the 1064nm emission between ^4Fa/2 and ^4I11/2 is suppressed completely by the 912nm emission between ^4Fa/2 and ^4I9/2. We obtain 670 mW output of the 912nm single-wavelength laser emission with a slope efficiency of 5.5% by taking an incident pump power of 18.4 W. Using a Nd:GdV04 laser with 0.4at.% Nd-doping concentration, we obtain either the single-wavelength emission at 1064nm or the dual-wavelength emission at both 1064nm and 912nm by increasing the incident pump power. We observe a strong competition process in the dualavelength laser. 相似文献
10.
Stephan Dahlke Gabriele Steidl Gerd Teschke 《Journal of Fourier Analysis and Applications》2004,10(5):507-539
This article is concerned with frame constructions on domains and manifolds. The
starting point is a unitary group representation which is square integrable modulo a suitable
subgroup and therefore gives rise to a generalized continuous wavelet transform. Then generalized
coorbit spaces can be defined by collecting all functions for which this wavelet transform
is contained in a weighted Lp-space. Moreover, we show that a judicious discretization of the
representation leads to an atomic decomposition and to Banach frames for these coorbit spaces. 相似文献