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1.
Vieira Renata Leia Demario Gaglieri Caroline de Oliveira Cristina Soltovski Ferreira Laura Teófilo Schnitzler Egon Bannach Gilbert 《Journal of Thermal Analysis and Calorimetry》2021,144(3):689-697
Journal of Thermal Analysis and Calorimetry - Buckwheat starch is an alternative source to supply the high global demand for starch. The properties of starch can be modified through chemical and... 相似文献
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Thorsten Brand Kyle Ratinac Jeffrey V. Castro Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5706-5713
A method was developed for free‐radical polymerization in the confines of a hollow latex particle. Hollow particles were prepared via the dynamic swelling method from polystyrene seed and divinylbenzene and had hollows of 500–1000 nm. So that these hollow poly(divinylbenzene) particles could function as submicrometer reactors, the particles were filled with a monomer (N‐isopropylacrylamide) via the dispersion of the dried particles in the molten monomer. The monomer that was not contained in the hollows was removed by washing and gentle abrasion. Free‐radical polymerization was then initiated by γ radiolysis in the solid state. Transmission electron microscopy showed that poly(N‐isopropylacrylamide) formed in the hollow interior of the particles, which functioned as submicrometer reactors. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5706–5713, 2004 相似文献
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Phenomena accompanying electrochemical doping of solid fullerene films with potassium were studied by sputter ion depth profiling
(XPS and SIMS). The potassium distribution was determined, and artifacts associated with possible damage of the layer composition
caused by ion impact were investigated and discussed. To compare the charge transfer while reductive doping is taking place
at fullerene/solution interface with doping from gas phase, model layers were prepared and doped by potassium under UHV conditions.
It was found that sputtering by Ar+ primary ions yields both accurate information on the alkaline metal distribution and on its concentration. Sputtering by
O+ ions led to an enrichment of potassium, apparently due to the reactivity of oxygen with the fullerene matrix. It is shown
that the reductive doping starts at the fullerene/solution interface. The concentration of potassium in the doped films was
found to be lower than expected from the charge transferred during the electrochemical reduction. Other phase transformations
such as hydrogenation are discussed.
Received March 4, 2002; accepted July 26, 2002 相似文献
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Eckhard Steffen 《Discrete Mathematics》2004,280(1-3):191-214
Cubic bridgeless graphs with chromatic index four are called uncolorable. We introduce parameters measuring the uncolorability of those graphs and relate them to each other. For k=2,3, let ck be the maximum size of a k-colorable subgraph of a cubic graph G=(V,E). We consider r3=|E|−c3 and
. We show that on one side r3 and r2 bound each other, but on the other side that the difference between them can be arbitrarily large. We also compare them to the oddness ω of G, the smallest possible number of odd circuits in a 2-factor of G. We construct cyclically 5-edge connected cubic graphs where r3 and ω are arbitrarily far apart, and show that for each 1c<2 there is a cubic graph such that ωcr3. For k=2,3, let ζk denote the largest fraction of edges that can be k-colored. We give best possible bounds for these parameters, and relate them to each other. 相似文献
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Franck D'Agosto Marie‐Thrse Charreyre Christian Pichot Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1188-1195
A method is described for synthesizing latex particles with anchored hairs by the grafting of hydrophilic chains, synthesized by reversible addition–fragmentation chain transfer, onto functionalized latex particles. These have the potential to bind biologically active species. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1188–1195, 2003 相似文献
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K A Dowsland M Gilbert G Kendall 《The Journal of the Operational Research Society》2007,58(4):429-438
This paper is concerned with the development of a customized circle packing algorithm for a manufacturer of sprockets for the motor cycle industry. Practical constraints mean that the problem differs somewhat from those tackled elsewhere in the literature. In particular, the layouts need to conform to a given structure. This is achieved by using a local search algorithm with an appropriate starting solution and a series of neighbourhoods designed to preserve the layout structure. Empirical evidence based on real data shows that the quality of the resulting solutions closely matches that of cutting patterns currently produced by human experts. Computation times average around 20–30?s per order as compared to several hours for an equivalent manual solution. 相似文献
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Hyperfine Interactions - A “coherent-path” model for nuclear-resonant scattering of gamma radiation from resonant matter has been developed and is summarized here. The solution provides... 相似文献
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