排序方式: 共有109条查询结果,搜索用时 15 毫秒
1.
In this work a novel graphical method is applied to the presentation of intercomparison results. This is demonstrated with
the results of a recent intercomparison in measuring the 137Cs, 40K, and 90Sr activity concentration in milk powder. The “PomPlot”, an intuitive graphical method, is used for producing a summary overview
of the participants’ results of a common measurand. The “PomPlot” displays (relative) deviations of individual results from
the reference value on the horizontal axis and (relative) uncertainties on the vertical axis. 相似文献
2.
Depraetere S Smet M Dehaen W 《Angewandte Chemie (International ed. in English)》1999,38(22):3359-3361
Next to the "normal" calix[4]pyrrole 1, the N-confused calix[4]pyrrole 2 is formed in substantial amounts (up to 22 % yield) as side product in the acid-catalyzed condensation reaction of ketones and pyrrole. In some cases, doubly N-confused calix[4]pyrroles are also formed. 相似文献
3.
Stefaan J. H. Soenen Linda Desender 《International journal of environmental analytical chemistry》2013,93(10-11):783-796
The complex of diethylenetriaminepentaacetate (DTPA) with the paramagnetic gadolinium ion [Gd(III)] is a well-known blood pool contrast agent for magnetic resonance imaging (MRI). To obtain MRI pictures from other anatomical structures, for instance from tissues containing cells with phagocytic activity, larger colloidal complexes have to be constructed. Therefore, in view of modifying the physiological behaviour, the DTPA chelate was first hydrophobized by covalently linking it to phosphatidylethanolamine (PE), and the resulting conjugate was then incorporated into nanometre-sized, sonicated phospholipid vesicles. Qualitative information on the affinity of the PE–DTPA derivative for Gd(III) ions was derived from competition experiments using the dye Arsenazo. Furthermore, it was found that only the membranotropic adducts residing in the outer shell of the vesicle bilayer are accessible to the lanthanide ion. The vesicular particulate was also used as a vehicle to transport PE–DTPA into the coating of so-called magnetoliposomes which consist of nanometre-sized iron oxide cores onto which a phospholipid bilayer is strongly chemisorbed. After loading the resulting structures with Gd(III), this new type of magnetoliposome may offer unique potentialities as a novel bi-label MRI contrast medium. 相似文献
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Gu R Depraetere S Kotek J Budka J Wagner-Wysiecka E Biernat JF Dehaen W 《Organic & biomolecular chemistry》2005,3(16):2921-2923
The first example of substitution reaction in the free alpha-position of N-confused calix[4]pyrroles is reported: azo-coupling with various arenediazonium salts. The obtained azocompounds were used for studies of their anion-binding properties by UV-Vis spectroscopy. 相似文献
6.
This paper recalls the formalism of H. J. Leisi, which shows an alternative way to understand Perturbed Angular Correlation
Spectroscopy: as a quantum interference effect.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
7.
In this article we provide a complete classification of regular partial difference sets in Abelian groups of order \(4p^2\), p an odd prime. It turns out that the known examples are the only examples. These are, up to complements, the trivial examples, the PCP examples, and a sporadic example in \(\mathbb {Z}_2^2\times \mathbb {Z}_3^2\). 相似文献
8.
Variational Bayesian methods aim to address some of the weaknesses (computation time, storage costs and convergence monitoring) of mainstream Markov chain Monte Carlo based inference at the cost of a biased but more tractable approximation to the posterior distribution. We investigate the performance of variational approximations in the context of the mixed logit model, which is one of the most used models for discrete choice data. A typical treatment using the variational Bayesian methodology is hindered by the fact that the expectation of the so called log-sum-exponential function has no explicit expression. Therefore additional approximations are required to maintain tractability. In this paper we compare seven different possible bounds or approximations. We found that quadratic bounds are not sufficiently accurate. A recently proposed non-quadratic bound did perform well. We also found that the Taylor series approximation used in a previous study of variational Bayes for mixed logit models is only accurate for specific settings. Our proposed approximation based on quasi Monte Carlo sampling performed consistently well across all simulation settings while remaining computationally tractable. 相似文献
9.
Huang C Soenen SJ Rejman J Lucas B Braeckmans K Demeester J De Smedt SC 《Chemical Society reviews》2011,40(5):2417-2434
Stimuli-responsive electrospun nanofibers are gaining considerable attention as highly versatile tools which offer great potential in the biomedical field. In this critical review, an overview is given on recent advances made in the development and application of stimuli-responsive fibers. The specific features of these electrospun fibers are highlighted and discussed in view of the properties required for the diverse applications. Furthermore, several novel biomedical applications are discussed and the respective advantages and shortcomings inherent to stimuli-responsive electrospun fibers are addressed (136 references). 相似文献
10.
Lately many interactive methods to solve multiple objective problems were proposed. One of these, the method developed by S. Zionts and J. Wallenius, looks particularly interesting. This paper takes a closer look at this method and reports on the results of an experiment set up in order to test the method. 相似文献