Synthesis and polymerization of racemic and optically active β-substituted β-propiolactones. II: β-monosubstituted and β-disubstituted monomers and polymers with different optical purities

β-(trichloromethyl)-β-propiolactone (CCl₃-PL), β-(trifluoromethyl,methyl)-β-propiolactone (CF₃, Me-PL) and β-(trifluoromethyl,ethyl)-β-propiolactone (CF₃,Et-PL) have been obtained by the reaction of ketene with chloral, 1,1,1-trifluoroacetone and 1,1,1-trifluorobutanone, respectively. Chiral catalysis lead to optically active monomers. The enantiomeric excess of the lactones has been measured by ¹H-NMR spectroscopy, in the presence of 2,2,2-trifluoro-1-(9-anthryl)ethanol or an europium chiral shift reagent. Polymerizations have been carried out in bulk or in toluene, at 60°C or 80°C, using mainly organometallic initiators. The Polymers become insoluble and crystalline at enantiomeric excesses over 80% for CCl₃-PL and 70% for CF₃,Me-PL. Melting temperatures were recorded from 238 to 268°C for poly(CCl₃-PL) and from 78 to 100°C for poly(CF₃,Me-PL), depending upon the molecular weight and the enantiomeric excess. The ¹³C-NMR specroscopy of poly(CCL₃-PL) indicates that the polymerization of the corresponding lactone leads to polymers of increasing degrees of isotacticity with the enantiomeric excess of the monomer.     

Luminescence of borates with yttrium and lutetium cations

Physics of the Solid State - This paper reports on the results of an investigation into the luminescence properties of yttrium and lutetium borates, as well as the Y0.35Lu0.65BO3 solid solution,...     

Mechanisms of nuclear reactions at interaction of cosmic rays with materials and nanostructures

The mechanism of failures of microelectronic elements, caused by ionization of atoms by recoil nuclei and secondary fragments formed at nuclear interactions of cosmic-ray protons and light ions with substance, has been analyzed. Models of nuclear physics are used to calculate the macroscopic failure cross section.     

A study of the (α, t) reaction on 19F, 27Al, 51V and 59Co

The angular distributions of tritons from the (α, t) reaction on ¹⁹F, ²⁷Al, ⁵¹V and ⁵⁹Co nuclei corresponding to the (0⁺) ground states and (2⁺) excited states in the final nuclei have been measured in the angular range between 15° and 170° at α-particle energies of 25 MeV. For reactions on ²⁷Al and ⁵¹V nuclei, the differential excitation functions have also been obtained at different angles of outgoing tritons at E_α from 20 to 25 MeV. The experimental angular distributions are analysed by the DWBA approximation on the assumption of a nucleon stripping mechanism. The analyses of the present results and the data obtained earlier for the (α, t) reaction on the 1 p shell nuclei, A ? 30, reveal that the distinguishing feature of the reaction under study is the presence of backward angle peaks in the reaction cross section, which appear to be associated with exchange processes. For the (α, t) reaction on the heavier nuclei (A > 30), the dominant mechanism is nucleon stripping.     

Single-crystalline films of Ce-doped YAG and LuAG phosphors: advantages over bulk crystals analogues

Luminescent properties of phosphors based on single-crystalline films (SCF) of Y₃Al₅O₁₂:Ce (YAG:Ce) and Lu₃Al₅O₁₂:Ce (LuAG:Ce) garnet have been analyzed in comparison with single-crystal (SC) analogues. It has been shown that the main peculiarity of luminescent properties of YAG:Ce and LuAG:Ce SCF as compared to SC is determined by the extremely low concentration of Y_Al³⁺ and Lu_Al³⁺ antisite defects (AD) in SCF. The advantages of phosphors based on YAG:Ce and LuAG:Ce SCF are caused by the absence in these SCF the additional channels for dissipation of excitation energy connected with AD and vacancy-type defects.     

αγ angular correlations in the inelastic scattering of α particles on 24Mg at Eα = 30.3 MeV

The results from measuring the angular dependence of differential α-scattering cross sections on ²⁴Mg with final nucleus formation in the ground and three lower excited states are presented, along with the double differential ²⁴Mg(α, αγ)²⁴Mg(2⁺, 1.369 MeV) reaction cross sections at E _α = 30.3 MeV. The spin-tensor components of the density matrix of the ²⁴Mg nucleus in the 2⁺(1.369 MeV) state are reconstructed and its orientation characteristics are determined. The experimental results are compared to theoretical results under the assumption of collective excitation and mechanisms for compound nucleus formation.     

Polymerisation von Oxiranylalkylaminen und Thiiranylalkylaminen, die sich von optisch aktiven und racemischen sekund?ren Aminen ableiten

Ohne Zusammenfassung     

Direct processes in the6Li(α, d)8Be reaction

The angular distributions of deuterons from the ⁶Li(α, d)⁸Be reaction corresponding to the 0⁺ ground state and the 2.9 MeV (2⁺) state in⁸Be have been measured at E_α = 17.3, 23.3 and 25.1 MeV. The excitation functions for this reaction have been measured at seven emission angles in the region from 12 up to 25 MeV. The experimental angular distributions are compared with theoretical predictions obtained using DWBA stripping calculations and the plane wave approximation (PWA) for various direct processes. It is shown that the experimental angular distributions can be described throughout the angular region using the simple mechanisms associated with the break-up of the ⁶Li target nuc clusters and heavy-particle stripping. The interference of these processes is taken into account.     

Study of orientation characteristics of the 11B(5/2?, 4.445 MeV) nucleus in the 13C(d, αγ)11B reaction at Ed = 15.3 MeV

Double differential cross sections of the ¹³C(d, αγ)¹¹B(5/2⁻, 4.445 MeV) reaction were measured at E _d = 15.3 MeV. Angular dependences of the even components of density matrix spin tensors, magnetic sublevel populations, and components of multipole moment orientation tensors of the ¹¹B nucleus in this state were obtained. Experimental results were compared with theoretical data calculated under the assumption of different reaction mechanisms: deuteron pickup, heavy particle stripping, two-step mechanism of sequential cluster transfer, and compound nucleus formation.     

Luminescence and energy transfer mechanisms in CaWO4 single crystals

The processes of the excitation energy transfer to the emission centers have been investigated for calcium tungstate crystals taking into account features of the electronic structure of valence band and conduction band. The calculations of the electronic structure of host lattice CaWO₄ were performed in the framework of density functional theory. The underestimation of the bandgap value in the calculations has been corrected according to the experimental data. Luminescence of two samples grown using Czochralski (cz) and hydrothermal (ht) techniques were studied. Intrinsic emission band related to excitons, self-trapped on WO₄ complexes has been observed for the both samples while the additional low-energy emission band related to the defects of crystal structure has been observed only for (ht) sample indicating the enhanced concentration of the defects in the sample. It was shown that the features of the conduction band electronic structure are reproduced in the excitation spectrum of intrinsic luminescence only for the (ht) sample while for (cz) sample the correlation is absent. The enhanced role of the competitive channels in the process of excitation energy transfer to intrinsic emission centers in (ht) sample is responsible for the observed difference.