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排序方式: 共有490条查询结果,搜索用时 15 毫秒
1.
V. A. Sadovnichy V. V. Alexandrov E. Soto T. B. Alexandrova T. G. Astakhova R. Vega N. V. Kulikovskaya V. I. Kurilov S. S. Migunov N. E. Shulenina 《Journal of Mathematical Sciences》2007,146(3):5938-5947
A mathematical model of the system composed of two sensors, the semicircular canal and the sacculus, is suggested. The model
is described by three lines of blocks, each line of which has the following structure: a biomechanical block, a mechanoelectrical
transduction mechanism, and a block describing the hair cell ionic currents and membrane potential dynamics. The response
of this system to various stimuli (head rotation under gravity and falling) is investigated. Identification of the model parameters
was done with the experimental data obtained for the axolotl (Ambystoma tigrinum) at the Institute of Physiology, Autonomous
University of Puebla, Mexico. Comparative analysis of the semicircular canal and sacculus membrane potentials is presented.
__________
Translated from Fundamentalnaya i Prikladnaya Matematika, Vol. 11, No. 7, pp. 207–220, 2005. 相似文献
2.
A rapid method of capillary zone electrophoresis is described to determine the oxidized (GSSG) and reduced (GSH) form of glutathione in plant tissue. In order to separate both analytes in a fused-silica capillary, the pH and composition of the electrolyte solution were optimized. The electrolyte composition was 100 mmol/L, borate 25 mmol/L Tris, and 0.2% w/v metaphosphoric acid (MPA), pH 8.2. Some instrumental conditions used to run the samples were hydrostatic injection for 30 s, 30 kV applied voltage, and UV detection (185 nm) at 25 degrees C. Linearity and useful range obtained for the calibration curves were optimum, with correlation coefficients about 0.999 in the 0-120 micromol/L range. The migration time was highly reproducible, less than 5 min being afforded to run a sample. Electrolyte buffer and samples required a careful pH control for optimal separation of both analytes. This aspect constitutes a critical analytical step when acids are used in the procedure for sample preparation. Simultaneous analysis of GSH and GSSG may provide a useful tool for comparative studies of plants in order to select those species with a potential capacity for detoxification from toxic elements or those appearing promising from phytoremediation for these elements. 相似文献
3.
The photodissociation dynamics of nitromethane (CH(3)NO(2)) starting at the S(3) excited state has been studied at the complete active space self-consistent field level of theory in conjunction with atomic natural orbital type basis sets. In addition, the energies of all the critical points and the energy profiles connecting them have been recomputed with the multiconfigurational second-order perturbation method. It is found that the key step in the reaction mechanism is a radiationless decay through an S(3)S(2) conical intersection. The branching space spanned by the gradient difference and nonadiabatic coupling vectors of this crossing point comprises dissociation into excited nitromethane plus singlet atomic oxygen [CH(3)NO(1A")+O((1)D)] and S(3)-->S(2) deactivation, respectively. Furthermore, deactivated nitromethane S(n (n<3)) can decompose in subsequent steps into CH(3)+NO(2), where NO(2) is generated at least in two different electronic states (1 (2)B(2) and 1 (2)A(1)). It is shown that formation of excited nitric oxide NO(A (2)Sigma) arises from CH(3)NO(1A") generated in the previous step. In addition, four crossings between singlet and triplet states are localized; however, no evidence is found for a relevant role of such crossings in the photochemistry of CH(3)NO(2) initiated at S(3) state in the gas phase. 相似文献
4.
Carlos Seoane Jos L. Soto Pilar Zamorano Margarita Quinteiro 《Journal of heterocyclic chemistry》1981,18(2):309-314
Ring transformations of 4H-pyrans into pyridines are reported. Treatment of 2-amino-4,6-diaryl-3,5-dicyano-4H-pyrans (I) with nitrosylsulfuric acid brings about their transformation into 3,5-dicyano-4,6-diaryl-2-pyridones (VI) which can also be obtained from α-benzoylcinnamonitriles (IX) and cyanoacetamide. Similarly, 2-amino-4,6-diaryl-5-carbethoxy-3-cyano-4H-pyrans (II) lead to 4,6-diaryl-5-carbethoxy-3-cyano-2-pyridones (VII). Treatment of both series of pyrans with sulfuric acid results in the formation of the corresponding 3,4-dihydro-2-pyridones (IV and V). Reaction of pyrans II with ammonium acetate in acetic acid yields 2-amino-4,6-diaryl-5-carbethoxy-3-cyanopyridines (XII). Pyrans I undergo an entirely different type of reaction upon treatment with this reagent leading to 2,4,6-triaryl-3,5-dicyano-1,4-dihydropyridines (XV). 相似文献
5.
Ultra‐high pressure LC for astaxanthin determination in shrimp by‐products and active food packaging
A. Sanches‐Silva T. Ribeiro T. G. Albuquerque P. Paseiro R. Sendón A. Bernaldo de Quirós J. López‐Cervantes D. I. Sánchez‐Machado H. Soto Valdez I. Angulo G. P. Aurrekoetxea H. S. Costa 《Biomedical chromatography : BMC》2013,27(6):757-764
Nowadays, there is increasing interest in natural antioxidants from food by‐products. Astaxanthin is a potent antioxidant and one of the major carotenoids in crustaceans and salmonids. An ultra‐high pressure liquid chromatographic method was developed and validated for the determination of astaxanthin in shrimp by‐products, and its migration from new packaging materials to food simulants was also studied. The method uses an UPLC® BEH guard‐column (2.1 × 5 mm, 1.7 µm particle size) and an UPLC® BEH analytical column (2.1 × 50 mm, 1.7 µm particle size). Chromatographic separation was achieved using a programmed gradient mobile phase consisting of (A) acetonitrile–methanol (containing 0.05 m ammonium acetate)–dichloromethane (75:20:5, v/v/v) and (B) ultrapure water. This method was evaluated with respect to validation parameters such as linearity, precision, limit of detection, limit of quantification and recovery. Low‐density polyethylene films were prepared with different amounts of the lipid fraction of fermented shrimp waste by extrusion, and migration was evaluated into food simulants (isooctane and ethanol 95%, v/v). Migration was not detected under the tested conditions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
6.
7.
Alfonsina E. Andreatta Eva Rodil Alberto Arce Ana Soto 《Journal of solution chemistry》2014,43(2):404-420
New experimental surface tension data have been provided at 283.15, 298.15, 313.15 K and atmospheric pressure for binary mixtures of 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide and 1-octyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide ionic liquids with the alcohols: methanol, ethanol, 1-propanol, 2-propanol, l-butanol and 1-pentanol. The experimental results show that the surface tensions of these mixtures depend systematically on the alkyl chain length of the ionic liquid and alcohol, composition and temperature. Surface tension changes on mixing have been calculated and adequately fitted by the Redlich–Kister polynomial equation. The adjustable parameters and the standard deviations between experimental and calculated values are reported. 相似文献
8.
Zoi G. Lada Amaia Soto Beobide Georgios N. Mathioudakis George A. Voyiatzis 《Molecules (Basel, Switzerland)》2021,26(1)
Polymeric composites constitute an appealing class of materials with applications in various fields. Spin crossover (SCO) coordination complexes are switchable materials with potential use in data storage and sensors. Their incorporation into polymers can be considered an effective method for their wider practical application. In this study, Fe(II) SCO/polylactic acid hybrid polymeric composites have been prepared by film casting. The mononuclear coordination complex [Fe{N(CN)2}2(abpt)2] was incorporated into polylactic acid. The morphological, structural and thermoanalytical characterization of the composite films were performed via scanning electron microscopy (SEM), attenuated total reflectance (ATR/FTIR), Raman spectroscopy and differential scanning calorimetry (DSC). In addition, the migration release study (MRS) of the SCO compound from the polymeric matrix into the food simulant 50% v/v water/ethanol solution was also examined via UV/Vis absorption. Of particular interest was the investigation of the SCO behavior of the coordination complex after its incorporation into the polymer matrix; it was accomplished by temperature-dependent micro-Raman spectroscopy. The described attempt could be considered a preparatory step toward the development of SCO-based temperature sensors integrated into food packaging materials. 相似文献
9.
Imen Ben Atitallah Georgia Antonopoulou Ioanna Ntaikou Amaia Soto Beobide Vassilios Dracopoulos Tahar Mechichi Gerasimos Lyberatos 《Molecules (Basel, Switzerland)》2022,27(4)
The effect of different pretreatment approaches based on alkali (NaOH)/hydrogen peroxide (H2O2) on willow sawdust (WS) biomass, in terms of delignification efficiency, structural changes of lignocellulose and subsequent fermentation toward ethanol, was investigated. Bioethanol production was carried out using the conventional yeast Saccharomyces cerevisiae, as well as three non-conventional yeasts strains, i.e., Pichia stipitis, Pachysolen tannophilus, Wickerhamomyces anomalus X19, separately and in co-cultures. The experimental results showed that a two-stage pretreatment approach (NaOH (0.5% w/v) for 24 h and H2O2 (0.5% v/v) for 24 h) led to higher delignification (38.3 ± 0.1%) and saccharification efficiency (31.7 ± 0.3%) and higher ethanol concentration and yield. Monocultures of S. cerevisiae or W. anomalus X19 and co-cultures with P. stipitis exhibited ethanol yields in the range of 11.67 ± 0.21 to 13.81 ± 0.20 g/100 g total solids (TS). When WS was subjected to H2O2 (0.5% v/v) alone for 24 h, the lowest ethanol yields were observed for all yeast strains, due to the minor impact of this treatment on the main chemical and structural WS characteristics. In order to decide which is the best pretreatment approach, a detailed techno-economical assessment is needed, which will take into account the ethanol yields and the minimum processing cost. 相似文献
10.
Kneller JM Soto RJ Surber SE Colomer JF Fonseca A Nagy JB Pietrass T 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,147(2):261-265
In a typical continuous-flow optical pumping setup, the chemical shift of xenon in the adsorbed phase depends on the gas flow rate due to warming of the sample surface by the gas stream. Calibration of the system using the (207)Pb resonance of solid lead nitrate is necessary to determine the actual sample temperature. Optimum pulse repetition rates are strongly affected by gas flow and spin-lattice relaxation rates. The interplay of flow and pulse repetition rate alters signal intensity ratios and may lead to the complete suppression of signals. 相似文献