Light Scattering by Cylindrical Fibers with High Aspect Ratio Using the Null‐Field Method with Discrete Sources

The problem of computing light scattering by cylindrical fibers with high aspect ratio in the framework of the Null‐Field method with discrete sources is treated. Numerical experiments for investigating the scattering properties of two fiber geometries are performed using distributed spherical vector wave functions as discrete sources.     

10.1007/s10955-006-9040-z

We derive hydrodynamic equations describing the evolution of a binary fluid segregated into two regions, each rich in one species,which are separated (on the macroscopic scale) by a sharp interface. Our starting point is a Vlasov-Boltzmann (VB) equation describing the evolution of the one particle position and velocity distributions, f_i (x, v, t), i = 1, 2. The solution of the VB equation is developed in a Hilbert expansion appropriate for this system. This yields incompressible Navier-Stokes equations for the velocity field u and a jump boundary condition for the pressure across the interface. The interface, in turn, moves with a velocity given by the normal component of u.     

Electrodeposition of mercury on gold from very dilute mercury(II) solution

Flameless atomic absorption spectrometry (flameless a.a.s.) was applied to study the state of mercury deposited on a gold plate electrode from very dilute mercury(II) solution by controlled-potential electrolysis. A stable monolayer is formed on the gold electrode by the electrolysis at a potential about 200 mV more positive than the reversible Nernst potential for the reduction of mercury(II) to mercury(0). After the monolayer formation, bulk mercury is deposited on the monolayer at the reversible potential and an adatom layer is also found. The difference of activation free energies between the evaporation of mercury from the monolayer and that from bulk mercury corresponds to the underpotential shift for the electrodeposition of mercury on the gold electrode.     

Ion chromatography of nitrite and carbonate in inorganic matrices on an octadecyl—poly(vinyl alcohol) gel column using acidic eluents

Low levels of carbonate and nitrite contained in inorganic matrices were determined by ion chromatography on an Asahipak ODP-50 poly(vinyl alcohol) gel-based reversed-phase column. With an acidic mobile phase, inorganic matrix anions and cations eluted near the void volume of the column, whereas carbonate and nitrite were retained and separated completely from the matrix ions. After the separation column, the peak response was enhanced using a cation-exchange hollow fibre and 25 mM sodium sulphate or alkaline enhancers. Sea-water samples can be applied directly for the determination of carbonate and added nitrite at ppm levels. The maximum sample volume that can be loaded on the column without peak deformation depended on the pH of the sample solution and the sulphuric acid concentration in the eluent. A 50 μl sea-water sample was applicable with a 2.5 mM acid eluent.