Comparative study of C(2) epimerization of d-glucose and d-mannose catalyzed by water soluble organometallic complexes with nitrogen ligands

Epimerization of d-glucose and d-mannose, catalyzed by the water soluble complexes of Cu(II), Ni(II), Co(II) and Cd(II) with bisnitrogen ligands 4–7, and by Mo(VI) complexes prepared in situ from ammonium heptamolybdate (AHM) with ligands 4–9 is compared. All examined complexes exhibit lower catalytic activity than AHM: strong coordination of the ligands by both (N,O) heteroatoms to metal ions, presumably affords catalytically less active species. Some free ligands and their metal (II) complexes catalyze both C(2) epimerization and isomerization of aldoses to d-fructose.     

Primitive symmetric designs with up to 2500 points

By this article we conclude the construction of all primitive ( v, k,λ ) symmetric designs with v < 2500 , up to a few unsolved cases. Complementary to the designs with prime power number of points published previously, here we give 55 primitive symmetric designs with v ≠ p ^m , p prime and m positive integer, together with the analysis of their full automorphism groups. The research involves programming and wide‐range computations. We make use of the software package GAP and the library of primitive groups which it contains. © 2011 Wiley Periodicals, Inc. J Combin Designs 19:463‐474, 2011     

Spectral methods for growth curve clustering

Central European Journal of Operations Research - The growth curve clustering problem is analyzed and its connection with the spectral relaxation method is described. For a given set of growth...     

Comparative regional GDP analysis: case study of Croatia

The focus of this paper is the regional GDP analysis of Croatian Counties. It is a part of an extensive on-going scientific research about Croatian economic challenges within the global recession environment. Although, as EU accession country, Croatia is divided into three NUTS 2 regions, twenty one Croatian Counties show significant economic and social disproportions. In multiple regression model it is researched to what extent regional GDP per capita depends on a set of regional variables (employment, gross investment, production of more important agricultural products, GVA per person employed, construction works value, exports, imports, foreign tourists arrivals, foreign tourist nights, ecology...). Subsequently parameters are evaluated by Monte Carlo simulations which are used for the first time in comparative regional analysis. Also Croatian Counties are classified using Cluster analysis to make a comparative analysis with official spacing into three NUTS 2 regions which are geographical and political areas rather than real and homogenous socio-economic areas.     

Primitive symmetric designs with prime power number of points

In this paper we either prove the non‐existence or give explicit construction of primitive symmetric (v, k, λ) designs with v=p^m<2500, p prime and m>1. The method of design construction is based on an automorphism group action; non‐existence results additionally include the theory of difference sets, multiplier theorems in particular. The research involves programming and wide‐range computations. We make use of software package GAP and the library of primitive groups which it contains. © 2009 Wiley Periodicals, Inc. J Combin Designs 18: 141–154, 2010     

ESI‐MS studies of the non‐covalent interactions between biologically important metal ions and N‐sulfonylcytosine derivatives

The aim of this report is to present the electrospray ionization mass spectrometry results of the non‐covalent interaction of two biologically active ligands, N‐1 ‐ (p‐toluenesulfonyl)cytosine, 1‐TsC, 1 and N‐1 ‐ methanesulfonylcytosine, 1‐MsC, 2 and their Cu(II) complexes Cu(1‐TsC‐N3)₂Cl₂, 3 and Cu(1‐MsC‐N3)₂Cl₂ and 4 with biologically important cations: Na⁺, K⁺, Ca²⁺, Mg²⁺ and Zn²⁺. The formation of various complex metal ions was observed. The alkali metals Na⁺ and K⁺ formed clusters because of electrostatic interactions. Ca²⁺ and Mg²⁺ salts produced the tris ligand and mixed ligand complexes. The interaction of Zn²⁺ with 1–4 produced monometal and dimetal Zn²⁺ complexes as a result of the affinity of Zn²⁺ ions toward both O and N atoms. Copyright © 2016 John Wiley & Sons, Ltd.     

Comparative study of homogeneous hydrogenation of d-glucose and d-mannose catalyzed by water soluble [Ru(tri(m-sulfophenyl) phosphine)] complex

Homogeneous hydrogenation of two epimeric aldoses, d-glucose (d-Glc) and d-mannose (d-Man) was performed in water, with molecular hydrogen and by transfer hydrogenation catalyzed by [Ru-TPPTS] complex (TPPTS = trisodium salt of tri(m-sulfophenyl)phosphine). Both method proved effective, and revealed d-Man as more reactive aldose. Hydrogen transfer has been studied with various hydrogen donors: the most effective, but highly pH-dependent system has been found in Et₃N/formic acid (azeotropic mixture 2:5) as the source of hydrogen.