排序方式: 共有3条查询结果,搜索用时 15 毫秒
1
1.
[reaction: see text] Styrenic TADDOL and L-prolinol-derived monomers were immobilized on polyethylene fibers by electron beam induced preirradiation grafting using styrene as comonomer. The polymer-supported chiral ligands were utilized as catalysts in the asymmetric addition of diethylzinc to benzaldehyde. Fiber-bound titanium TADDOLate gave a quantitative conversion of benzaldehyde to 1-phenylpropan-1-ol in a 97:3 S/R enantiomeric ratio. The catalyst was successfully regenerated and employed in subsequent reactions with retention of high enantioselectivities. 相似文献
2.
J.C. Hilico J. Degni J.P. Champion G. Guelachvili 《Journal of Molecular Spectroscopy》1980,81(2):277-302
The ν2 + ν3 bands of 12CH4 and 13CH4 occurring in the region 4400–4650 cm?1 have been studied from spectra recorded with a high-resolution Fourier transform spectrometer (resolution better than 0.01 cm?1). Champion's Hamiltonian expansion, Canad. J. Phys.55, 1802 (1977), is applied to the problem of the two interacting F1 and F2 vibrational sublevels of this type of a band. As the P branch of ν2 + ν3 is strongly overlapped by neighboring bands, a combination-difference method, adapted to tetrahedral XY4 molecules has been developed to help assignments of lines. A fit of 700 transitions has been performed using 13 new effective constants in the case of 12CH4. In the case of 13CH4, 532 transitions have been fit to 18 constants. The known parameters, relative to the vibrational ground state and the ν3 state for both methanes, and the ν2 state for 12CH4 were fixed throughout. Most of the perturbed levels, up to J′ = 12, are well reproduced and the general agreement between experimental and calculated transitions is satisfactory with standard deviations of 0.047 cm?1 (12CH4) and 0.041 cm?1 (13CH4). The results (order of magnitude of obtained (ν2 + ν3) parameters and comparison of observed and computed intensities) indicate that the ν2 + ν3 band is perturbed by many other bands. 相似文献
3.
Boitumelo Mudabuka Dezzline Ondigo Slyvestre Degni Sibulelo Vilakazi Nelson Torto 《Mikrochimica acta》2014,181(3-4):395-401
We report on a colorimetric probe based on copper-gold alloy nanoparticles (NPs). The probe is capable of selectively detecting ascorbic acid (AA) as a result of the distance-dependent colour change of the nanoparticles immobilized in an electrospun nylon-6 nanofiber. The resulting white nanofibres undergo a colour change to blue as a result of the aggregation of the NPs induced by AA in the pH range 2–7. The probe is selective for AA even in the presence of dopamine, uric acid, saccharides, amino acids and certain organic acids. It covers the 1.76 x10?2 mg L?1 to 1.76 x105 mg L?1 concentration range, and exhibits a limit of detection of 1.76 x10?2 mg L?1 based on visual detection. Its application was demonstrated by the determination of ascorbic acid in fruit juices, urine, serum, and vitamin C tablets. Figure
An electrospun colorimetric probe based on the growth of copper-gold alloy nanoparticles induced by ascorbic acid was developed. The white nanofiber turns blue in the pH range 2–7 and is selective for AA in the presence of possible interferences. Its limit of detection is 1.76 x10?2 mg L?1. 相似文献
1