New laves phase in the ternary Nb-Cr-Re system

A new ternary Laves phase Nb(Cr,Re)₂ with a hexagonal MgZn₂-type structure and a rhenium concentration of 6.0–33.0 at % was revealed in the Nb-Cr-Re system.     

Copper and iron interactions with angiotensin-converting enzyme inhibitors. A study by fast-atom bombardment tandem mass spectrometry

Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd.     

Sulfur and sulfur compounds in plant defence

The multiplicity of chemical structures of sulfur containing compounds, influenced in part by the element's several oxidation states, directly results in diverse modes of action for sulfur-containing natural products synthesized as secondary metabolites in plants. Sulfur-containing natural products constitute a formidable wall of defence against a wide range of pathogens and pests. Steady progress in the development of new technologies have advanced research in this area, helping to uncover the role of such important plant defence molecules like endogenously-released elemental sulphur, but also deepening current understanding of other better-studied compounds like the glucosinolates. As studies continue in this area, it is becoming increasingly evident that sulfur and sulfur compounds play far more important roles in plant defence than perhaps previously suspected.     

Sub-barrier interaction between deuterons and 58, 62Ni nuclei

The interaction between deuterons and ^{58, 62}Ni nuclei at energies of E _d = 3.5, 4.5 and 5.16 MeV is investigated. The discrepancy between measured scattering elastic cross section and the Rutherford ones is higher than the value calculated theoretically by considering deuterons polarization and Coulomb breakup. Analysis of measured cross section of ^{58, 62}Ni(d, p) reaction and the results of calculation of Coulomb breakup cross section integrated over neutron emission angles shows that that the dominant mechanism of proton formation is the reaction of neutron transfer to the target nucleus.