Effect of Temperature and Water Content on the Properties of Solid Protic Electrolyte of Tetra Calixarene Sulfonic Acid: NMR Study

Russian Journal of Electrochemistry - The methods of 1H NMR and pulsed field gradient NMR are used to study the protic solid electrolyte of calix[4]arene-para-sulfonic acid in the temperature range...     

Aspects of proton transport in calix[6]arene sulfonic acid

The features of proton transport and proton hydration shell structure of calix[6]arene sulfonic acid were studied. XRD and NMR data indicate the existence of crystalline and amorphous phases and various conformations in the acid structure. The hydration process occurs in three stages by thermal analysis and IR spectroscopy. The change in the composition of the hydrate affected the conductivity only at low humidity; an inverse relationship between the water uptake and the activation energy of conductivity is observed in the entire investigated range of humidity.     

Conducting properties of nanocomposite polymer electrolytes based on polyethylene glycol diacrylate and SiO<Subscript>2</Subscript> nanoparticles at the interface with a lithium electrode

Nanocomposite polymer electrolytes based on polyethylene glycol diacrylate and 1 M LiBF₄ solution in γ-butyrolactone with addition of SiO₂ nanoparticles were synthesized and studied. Resistance measurement at the Li/electrolyte and Li/nanocomposite electrolyte interface by the time-resolved electrochemical impedance showed its significant decrease in the presence of SiO₂ nanoparticles. Charge-discharge cycling of prototypes of Li/LiFePO₄ batteries for 50 cycles also showed the advantage of using nanocomposite polymer electrolytes over electrolytes without SiO₂ additives.     

Performance of a Li-Polyimide Battery with Electrolytes of Various Types

Russian Journal of Electrochemistry - —The effect of various types of electrolyte on the behavior of lithium-polyimide batteries was studied. The electrolyte systems used included the liquid...     

Elastic Wave Propagation in Soft Microstructured Composites Undergoing Finite Deformations

We consider the propagation of elastic waves in soft composite materials undergoing large deformations. The analysis is performed in terms of small amplitude motions superimposed on a deformed state. By consideration of 2D periodic laminates and 3D fiber composites, we find that an applied deformation influences the elastic waves through the change in the microstructure, and through the change in the local material properties. These effects can be significantly amplified by the deformation induced elastic instability phenomenon leading to microstructure transformations. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Specific Features of Ion Transport in New Nanocomposite Gel Electrolytes Based on Cross-Linked Polymers and Silica Nanoparicles

Russian Journal of Electrochemistry - The spesific features of ion transport are studied in the nanocomposite system based on a network matrix synthesized by radical polymerization of polyethylene...     

Numerical simulation of equilibrium of an elastic two-layer structure with a through crack

In this paper, a problem of equilibrium of two elastic bodies pasted together along a curve is considered. It is assumed that there is a through crack on a part of the curve. Nonlinear boundary conditions providing mutual non-penetration between the crack faces are set. The main objective of the paper is to construct and test a numerical algorithm for solving the equilibrium problem. The algorithm is based on two approaches: a domain decomposition method and Uzawa method for solving variational inequalities. A numerical experiment illustrates the efficiency of the algorithm.     

Influence of the reticular polymeric gel—electrolyte structure on ionic and molecular mobility of an electrolyte system salt—ionic liquid: LiBF4—1-ethyl-3-methylimidazolium tetrafluoroborate

Russian Chemical Bulletin - Peculiarities of the formation of a reticular polymeric gel—electrolyte matrix based on polyethylene glycol diacrylate in a medium of ionic liquid...     

Mathematical and Numerical Simulation of Equilibrium of an Elastic Body Reinforced by a Thin Elastic Inclusion

A boundary value problem describing the equilibrium of a two-dimensional linear elastic body with a thin rectilinear elastic inclusion and possible delamination is considered. The stress and strain state of the inclusion is described using the equations of the Euler–Bernoulli beam theory. Delamination means the existence of a crack between the inclusion and the elastic matrix. Nonlinear boundary conditions preventing crack face interpenetration are imposed on the crack faces. As a result, problem with an unknown contact domain is obtained. The problem is solved numerically by applying an iterative algorithm based on the domain decomposition method and an Uzawa-type algorithm for solving variational inequalities. Numerical results illustrating the efficiency of the proposed algorithm are presented.