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排序方式: 共有57条查询结果,搜索用时 15 毫秒
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Silvio Aime Mauro Botta Giancarlo Cravotto Luca Frullano GiovanniB. Giovenzana Simonetta GeninattiCrich Giovanni Palmisano Massimo Sisti 《Helvetica chimica acta》2005,88(3):588-603
Four new ligands for lanthanide ions based on the H3do3a (=1,4,7,10‐tetraazacyclododecane‐1,4,7‐triacetic acid) structure and bearing one N‐sulfonylacetamide arm were synthesized, i.e., H4dota‐NHSO2R=10‐{2‐[(R)sulfonylamino]‐2‐oxoethyl}‐1,4,7,10‐tetraazacyclododecane‐1,4,7‐triacetic acids 1a – e . A 15N‐NMR study of the 15N‐labelled Eu3+ complex of one such ligands, 1d , showed that the coordination of the N‐sulfonylacetamide arm involves the carbonyl O‐atom rather than the N‐atom. The relaxometric properties of the corresponding Gd3+ complexes were investigated as a function of pH and temperature. These complexes have relaxivities in the range 4.5–5.3 mM ?1 s?1, at 20 MHz and 25°, and are characterized by a single H2O molecule in their inner coordination sphere. The mean residence lifetime of this molecule is relatively long (500–700 ns) compared to other anionic complexes. The slow rate of H2O exchange can be justified by the extensive delocalization of the negative charge on the N‐sulfonylacetamide arm. The long residence time of the coordinated H2O allowed the observation of the effect of the prototropic exchange on the relaxivity. The study of the interaction between the complex [Gd( 1e )]‐ and HSA revealed a weak affinity constant highlighting the importance of a localized negative charge on the complex to promote a strong interaction with the protein. 相似文献
3.
1,3-Dipolar cycloadditions of azomethine ylides with dipolarophiles. II. Synthesis of pyrrolizidines
F. Orsini F. Pelizzoni M. Forte M. Sisti F. Merati P. Gariboldi 《Journal of heterocyclic chemistry》1988,25(6):1665-1673
Substituted pyrrolizidines have been synthesized by 1,3-dipolar cycloaddition of various dipolarophiles with the azomethine ylide generated by treatment of proline with benzaldehyde in dimethylsulfoxide. The regio- and stereochemical outcome of the reaction as well as the stability of the isomers obtained are discussed. 相似文献
4.
A Practical Synthesis of 1,4,7,10-Tetraaza-Cyclododecane,A Pivotal Precursor for MRI Contrast Agents
A practical preparation of the versatile macrocycle 1,4,7,10-tetraazacyclododecane (cyclen) was developed starting from cheap and easily available starting materials as ethylenediamine and glyoxal. 相似文献
5.
A new entry to the drimane-related sesquiterpene Confertifolin is reported. The key step involves the conversion of a β-phenylthio-α, β-unsaturated ketone into the corresponding silylcyanohydrin followed by diisobutylaluminum hydride reduction to the homologous α,β-unsaturated aldehyde. 相似文献
6.
Aime S Calabi L Cavallotti C Gianolio E Giovenzana GB Losi P Maiocchi A Palmisano G Sisti M 《Inorganic chemistry》2004,43(24):7588-7590
An innovative MRI contrast agent based on the unprecedented and easily obtained ligand AAZTA is described. The simple and straightforward synthesis of the ligand, together with the potentiometric and relaxometric behavior of the corresponding Gd(III) chelate, is reported. The complex [Gd(AAZTA)]- shows outstanding magnetic properties connected with high thermodynamic stability in aqueous solution and a nearly complete inertness toward the influence of bidentate endogenous anions, placing this compound as one of the most promising candidates for the development of high performance MRI contrast agents. 相似文献
7.
Measurements of synchrotron radiation emitted by 30-MeV runaway electrons in the TEXTOR-94 tokamak show that the runaway population decays after switching on neutral beam injection (NBI). The decay starts only with a significant delay, which decreases with increasing NBI heating power. This delay provides direct evidence of the energy dependence of runaway confinement, which is expected if magnetic modes govern the loss of runaways. Application of the theory by Mynick and Strachan [Phys. Fluids 24, 695 (1981)] yields estimates for the "mode width" (delta) of magnetic perturbations: delta<0.5 cm in Ohmic discharges, increasing to delta = 4.4 cm for 0. 6 MW NBI. 相似文献
8.
A. Alessandrello C. Arnaboldi F. T. Avignone III J. Beeman M. Barucci M. Balata C. Brofferio C. Bucci S. Cebrian R. J. Creswick S. Capelli L. Carbone O. Cremonesi A. de Ward E. Fiorini H. A. Farach G. Frossati A. Giuliani D. Giugni E. E. Haller I. G. Irastorza R. J. McDonald A. Morales E. B. Norman P. Negri A. Nucciotti M. Pedretti C. Pobes V. Palmieri M. Pavan G. Pessina S. Pirro E. Previtali C. Rosenfeld A. R. Smith M. Sisti G. Ventura M. Vanzini L. Zanotti 《Physics of Atomic Nuclei》2003,66(3):452-457
CUORE is a proposed tightly packed array of 1000 TeO2 bolometers, each being a cube 5 cm on a side with a mass of 750 g. The array consists of 25 vertical towers, arranged in a square of 5 towers by 5 towers, each containing ten layers of four crystals. The design of the detector is optimized for ultralow-background searches for neutrinoless double beta decay of 130Te (33.8% abundance), cold dark matter, solar axions, and rare nuclear decays. A preliminary experiment involving 20 crystals of various sizes (MIBETA) has been completed, and a single CUORE tower is being constructed as a smaller scale experiment called CUORICINO. The expected performance and sensitivity, based on Monte Carlo simulations and extrapolations of present results, are reported. 相似文献
9.
Arnaboldi C Benedek G Brofferio C Capelli S Capozzi F Cremonesi O Filipponi A Fiorini E Giuliani A Monfardini A Nucciotti A Pavan M Pedretti M Pessina G Pirro S Previtali E Sisti M 《Physical review letters》2006,96(4):042503
The mixed occurrence of s-wave and p-wave contributions in a first forbidden unique Gamow-Teller beta decay has been investigated for the first time by measuring the beta environmental fine structure (BEFS) in a 187Re crystalline compound. The experiment has been carried out with an array of eight AgReO4 thermal detectors operating at a temperature of approximately 100 mK. A fit of the observed BEFS spectrum indicates the p-wave electron emission as the dominant channel. The complete understanding of the BEFS distortion of the 187Re beta decay spectrum is crucial for future experiments aiming at the precise calorimetric measurement of the antineutrino mass. 相似文献
10.
An online temperature‐controlled vacuum‐equilibration preparation system for the measurement of δ2H values of non‐exchangeable‐H and of δ18O values in organic materials by isotope‐ratio mass spectrometry
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