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排序方式: 共有72条查询结果,搜索用时 15 毫秒
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Polysubstituted indoles can be prepared directly from functionalized nitroalkanes under very mildly acidic conditions in a simple, one-pot, two-stage procedure. 相似文献
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Enisa Omanovic-Miklicanin Sandro Valzacchi Catherine Simoneau Douglas Gilliland Francois Rossi 《Analytical and bioanalytical chemistry》2014,406(26):6629-6636
A complete characterization of the different physico-chemical properties of nanoparticles (NPs) is necessary for the evaluation of their impact on health and environment. Among these properties, the surface characterization of the nanomaterial is the least developed and in many cases limited to the measurement of surface composition and zetapotential. The biological surface adsorption index approach (BSAI) for characterization of surface adsorption properties of NPs has recently been introduced (Xia et al. Nat Nanotechnol 5:671–675, 2010; Xia et al. ACS Nano 5(11):9074–9081, 2011). The BSAI approach offers in principle the possibility to characterize the different interaction forces exerted between a NP's surface and an organic—and by extension biological—entity. The present work further develops the BSAI approach and optimizes a solid-phase microextraction gas chromatography–mass spectrometry (SPME/GC-MS) method which, as an outcome, gives a better-defined quantification of the adsorption properties on NPs. We investigated the various aspects of the SPME/GC-MS method, including kinetics of adsorption of probe compounds on SPME fiber, kinetic of adsorption of probe compounds on NP's surface, and optimization of NP's concentration. The optimized conditions were then tested on 33 probe compounds and on Au NPs (15 nm) and SiO2 NPs (50 nm). The procedure allowed the identification of three compounds adsorbed by silica NPs and nine compounds by Au NPs, with equilibrium times which varied between 30 min and 12 h. Adsorption coefficients of 4.66?±?0.23 and 4.44?±?0.26 were calculated for 1-methylnaphtalene and biphenyl, compared to literature values of 4.89 and 5.18, respectively. The results demonstrated that the detailed optimization of the SPME/GC-MS method under various conditions is a critical factor and a prerequisite to the application of the BSAI approach as a tool to characterize surface adsorption properties of NPs and therefore to draw any further conclusions on their potential impact on health. Graphical Abstract
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硅基材料是新一代高容量锂离子蓄电池负极材料的典型代表,近年来已成为理论研究和应用研究的热点.本文介绍了锂离子电池硅基负极材料的制备方法、电化学性能及其研究现状,分析了硅材料作为锂离子电池负极材料存在的问题;讨论了硅材料作为锂离子电池负极材料的研究前景.并指出若能克服目前存在问题,将有望成为新一代锂离子电池负极材料. 相似文献
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Liondas CA; Chrissoulidis DP 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(3):275-287
This paper is intended to clarify a misunderstanding concerningthe source singularity of the electric Green's tensor for aperfectly conducting semi-infinite cone of circular cross-section.Tai's series expansion of the Green's tensor is known to lacka singular term at the source region. Jones has reconstructedthe solution to this problem and has pointed out the differencebetween his result and that of Tai. The aim of our paper isto demonstrate that, although Jones's closed-form solution iscorrect, there is a mistake in his comparison with Tai's seriessolution. We conclude that one of the two additional singularterms that Jones claims as missing from Tai's formula must beomitted. Besides, we compare Jones's closed-form solution withSmyshlyaev's solution to the very same problem. We concludethat the magnetic field expressions given by Jones and Smyshlyaevcoincide, but a singular term is missing from Smyshlyaev's expressionfor the electric field. 相似文献
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Goodman TNT; Micchelli CA; Rodriguez G; Seatzu S 《IMA Journal of Numerical Analysis》1998,18(3):331-354
It is shown that, under certain conditions, orthonormalizingthe positive integer shifts of an exponentially decaying functionon the half line by the Gram-Schmidt process leads to a limitingprofile given by orthonormalizing all their integer shifts onthe whole line. These results derive from properties of Choleskyfactorization of bi-infinite and semi-infinite matrices. Anexample is provided by the negative exponential function andconjectures are given, supported by numerical evidence, forthe Gaussian and Lorentz function. 相似文献
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New four- and five-component Ugi condensations have been developed based on the reaction of organometallic reagents with nitriles. These variations expand both the range of inputs and overall dimensionality of the method. 相似文献
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从烟草(品种革新一号)单倍体花粉植株的叶和茎产生的愈伤组织,结合悬浮培养,获得的细胞分离出原生质体。在液体培养基中静置培养,12小时后原生质体开始变为卵圆形,细胞壁明显可见,24小时后完成第一次细胞分裂。以后继续分裂形成浅黄色的愈伤组织,在培养四星期后可达1毫米大小,再放到转床上进行旋转培养18天左右,愈伤组织可达3—4毫米大小。当转移到分化培养基后,分别分化出苗及根,长成完整的植株。 原生质体再生细胞的分裂与分化,不仅受不同器官来源的愈伤组织及其年龄的影响;还受分化培养基的基本成份及所用细胞分裂素的类型等的影响。 相似文献