排序方式: 共有24条查询结果,搜索用时 31 毫秒
1.
G. E. Malashkevich V. N. Sigaev G. I. Semkova B. Champagnon 《Physics of the Solid State》2004,46(3):552-556
The spectral-luminescent properties of silica gel glasses coactivated by Ce4+ and Eu3+ ions are investigated. The structure of the glasses is studied using x-ray powder diffraction and small-angle neutron scattering. The inference is drawn that Ce4+-Eu3+ centers with high-symmetry Eu(III) oxo complexes, which are formed in the glasses, have nanocrystalline nature. These centers are characterized by a weak vibronic interaction of Eu3+ ions with the matrix. The size of nanocrystallites formed under the synthesis conditions and at coactivator concentrations used is approximately equal to 10 nm. 相似文献
2.
3.
4.
Bergese P Alessandri I Bontempi E Depero LE Aronne A Fanelli E Pernice P Ballaran TB Miyajima N Sigaev VN 《The journal of physical chemistry. B》2006,110(51):25740-25745
In potassium niobiosilicate (KNS) glasses, nanostructuring can be driven and controlled by thermal treatments at the glass transition temperature and/or by modulation of the chemical composition. The tight relationship between nanostructure and nonlinear optical properties suggests these bulk nanomaterials as an appealing route to nanophotonics. The focus of this paper is placed on assessing the phase transformations which occur in these materials upon annealing at the glass transition temperature and subsequent heating. High-temperature resolved X-ray diffraction (HTXRD) and high-resolution transmission electron microscopy (HRTEM) experiments are integrated with previously published results for in-depth insight. It will be shown that nanostructuring evolves from nucleation of niobium-rich nanocrystals, which are up to 20 nm large, uniformly distributed in the matrix bulk, and metastable. Formation kinetics as well as phase transformation of the nanocrystals are determined by the glass composition. Depending on it, nanocrystal nucleation can be preceded or not by phase separation, and the nanocrystals' phase transition can be of first or second order. 相似文献
5.
V.N. Sigaev N.V. Golubev S.Yu. Stefanovich T. Komatsu Y. Benino P. Pernice A. Aronne E. Fanelli B. Champagnon V. Califano D. Vouagner T.E. Konstantinova V.A. Glazunova 《Journal of Non》2008,354(10-11):873-881
Amorphous nanoheterogeneities of the size less than 100 Å have been formed in glasses of the Li2O–Nb2O5–SiO2 (LNS) and Li2O–ZnO–Nb2O5–SiO2 (LZNS) systems at the initial stage of phase separation and examined by transmission electron microscopy, small-angle X-ray and neutron scattering. Both LNS and LZNS nanoheterogeneous glasses exhibit second harmonic generation (SHG) even when they are characterized by fully amorphous X-ray diffraction (XRD) patterns. Chemical differentiation and ordering of glass structure during heat treatments at appropriate temperatures higher Tg lead to drastic increase of SHG efficiency of LNS glasses contrary to LZNS ones in the frame of amorphous state of samples. Following heat treatments of nanostructured glasses result in crystallization of ferroelectric LiNbO3 and non-polar LiZnNbO4 in the LNS and LZNS glasses, respectively. Taking into account similar polarizability of atoms in LNS and LZNS glasses, the origin of the principal difference in the second-order optical non-linearity of amorphous LNS and LZNS samples is proposed to connect predominantly with the internal structure of formed nanoheterogeneities and with their polarity. Most probably, amorphous nanoheterogeneities in glasses may be characterized with crystal-like structure of polar (LiNbO3) phase initiating remarkable SHG efficiency or non-polar (LiZnNbO4) phase, which do not initiate SHG activity. It gives an opportunity to vary SHG efficiency of glasses in a wide rage without remarkable change of their transparency by chemical differentiation process at the initial stage of phase separation when growth of nanoheterogeneities is ‘frozen’. At higher temperatures, LiNbO3 crystals identified by XRD precipitate in LNS glasses initiating even more increase of SHG efficiency but visually observable transparency is impaired. 相似文献
6.
Transparent glasses composition of which can be expressed by the formula: (100−x) · (K2O · 2TiO2 · P2O5) · x(K2O · 2B2O3 · 7SiO2), where x=5, 10, 15 and 20 mol% (KTP-xKBS), were obtained by melt quenching technique. The structure and crystallization behavior of these glasses have been examined by Fourier transform infrared spectroscopy, differential thermal analysis and X-ray diffraction. In spite of their nominal composition, the studied glasses exhibit a similar oxygen polyhedra distribution. However, significant differences were found in the trigonal BO3 units amount. During DTA runs all the examined glasses devitrify in two steps. In the former, very small crystals of an unknown crystalline phase are produced. In KTP-5KBS and KTP-10KBS glasses anatase phase was also detected. Attempts were made in order to identify the unknown phase (UTP) for which a AB3(XO4)2(OH)6 Crandallite-type structure was proposed where the A, B and X sites were occupied by K, Ti and/or Al, and P, respectively. In the second devitrification step the crystallization of the KTiOPO4 phase occurs while the UTP phase previously formed disappears. Isothermal heat treatments performed at temperature just above Tg have allowed one to obtain transparent crystal-glass nanocomposites, formed by crystalline nanostructure of the UTP phase uniformly dispersed in the amorphous matrix. 相似文献
7.
Mashinsky VM Karatun NM Bogatyrev VA Sigaev VN Golubev NV Ignat'eva ES Lorenzi R Mozzati MC Paleari A Dianov EM 《Microscopy and microanalysis》2012,18(2):259-265
A spectroscopic protocol is proposed to implement confocal microfluorescence imaging to the analysis of microinhomogeneity in the nanocrystallization of the core of fibers belonging to a new kind of broadband fiber amplifier based on glass with embedded nanocrystals. Nanocrystallization, crucial for achieving an adequate light emission efficiency of transition metal ions in these materials, has to be as homogeneous as possible in the fiber to assure optical amplification. This requirement calls for a sensitive method for monitoring nanostructuring in oxide glasses. Here we show that mapping microfluorescence excited at 633 nm by a He-Ne laser may give a useful tool in this regard, thanks to quasi-resonant excitation of coordination defects typical of germanosilicate materials, such as nonbridging oxygens and charged Ge-O-Ge sites, whose fluorescence are shown to undergo spectral modifications when nanocrystals form into the glass. The method has been positively checked on prototypes of optical fibers--preventively characterized by means of scanning electron microscopy and energy dispersive spectroscopy--fabricated from preforms of Ni-doped Li?O-Na?O-Sb?O?-Ga?O?-GeO?-SiO? glass in silica cladding and subjected to heat treatment to activate gallium oxide nanocrystal growth. The method indeed enables not only the mapping of the crystallization degree but also the identification of drawing-induced defects in the fiber cladding. 相似文献
8.
9.
G. A. Komandin V. I. Torgashev V. N. Sigaev V. I. Savinkov S. V. Lotarev O. E. Porodinkov I. E. Spektor 《Physics of the Solid State》2014,56(3):442-448
Experimental spectra of the dielectric response function of glasses with the composition LnBGeO5 (Ln = La, Pr, Tb, Er, Sm) in the terahertz and infrared ranges are compared. Absorption bands are identified, and their contributions to permittivity are established. The contours of the boson peak and the dependence of the dielectric loss on the type of rare-earth ion are determined. 相似文献
10.
A. Dolgui A. Eremeev A. Kolokolov V. Sigaev 《Journal of Mathematical Modelling and Algorithms》2002,1(2):89-104
In this paper, we consider a flow-line manufacturing system organized as a series of workstations separated by finite buffers. The failure and repair times of machines are supposed to be exponentially distributed. The production rate of each machine is deterministic, and different machines may have different production rates. The buffer allocation problem consists in determining the buffer capacities with respect to a given optimality criterion, which depends on the average production rate of the line, the buffer acquisition and installation cost, and the inventory cost. For this problem we propose a genetic algorithm where the tentative solutions are evaluated with an approximate method based on the Markov-model aggregation approach. 相似文献