首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   535篇
  免费   17篇
  国内免费   3篇
化学   348篇
晶体学   6篇
力学   7篇
数学   84篇
物理学   110篇
  2023年   5篇
  2022年   31篇
  2021年   26篇
  2020年   18篇
  2019年   20篇
  2018年   16篇
  2017年   16篇
  2016年   33篇
  2015年   15篇
  2014年   24篇
  2013年   65篇
  2012年   27篇
  2011年   23篇
  2010年   26篇
  2009年   19篇
  2008年   24篇
  2007年   23篇
  2006年   23篇
  2005年   17篇
  2004年   17篇
  2003年   9篇
  2002年   16篇
  2001年   7篇
  2000年   5篇
  1999年   4篇
  1998年   3篇
  1997年   2篇
  1996年   4篇
  1994年   2篇
  1993年   1篇
  1992年   2篇
  1991年   3篇
  1990年   1篇
  1988年   1篇
  1987年   1篇
  1986年   1篇
  1985年   1篇
  1984年   3篇
  1982年   2篇
  1981年   4篇
  1980年   2篇
  1979年   3篇
  1977年   2篇
  1976年   4篇
  1970年   1篇
  1969年   1篇
  1968年   1篇
  1966年   1篇
排序方式: 共有555条查询结果,搜索用时 31 毫秒
1.
2.
Journal of Thermal Analysis and Calorimetry - This work introduces the determination of the optimum values of the design parameters in a tube with loose-fit perforated twisted tapes. The effects of...  相似文献   
3.
Abstract

In the present study, the reactions of 2,3-dichloro-1,4-naphthoquinone (DCNQ) with amino-1,2-propanediol and some thiols were investigated. Novel N-, N,S-, and S,O- substituted derivatives were obtained and the structures of all compounds were characterized by spectroscopic methods (FT-IR, 1H NMR, 13 Baker, R. A.; Tatum, J. H.; Nemec, S. Antimicrobial Activity of Naphthoquinones from Fusaria. Mycopathologia 1990, 111, 915. DOI: 10.1007/BF02277294.[Crossref], [PubMed], [Web of Science ®] [Google Scholar]C NMR, Mass spectroscopy) and microanalysis. The absorption behaviors of novel compounds were also investigated with UV-Vis spectroscopy in different solvents, such as ethanol, tetrahydrofuran and chloroform.  相似文献   
4.
For hard optimization problems, it is difficult to design heuristic algorithms which exhibit uniformly superior performance for all problem instances. As a result it becomes necessary to tailor the algorithms based on the problem instance. In this paper, we introduce the use of a cooperative problem solving team of heuristics that evolves algorithms for a given problem instance. The efficacy of this method is examined by solving six difficult instances of a bicriteria sparse multiple knapsack problem. Results indicate that such tailored algorithms uniformly improve solutions as compared to using predesigned heuristic algorithms.  相似文献   
5.
The centrosymmetric title compound, [Cd2{CH3OC6H4P(OC5H9)S2}4], features an eight‐membered [? Cd? S? P? S? ]2 ring owing to the presence of bridging dithiolate ligands. Tetrahedral coordination geometries for cadmium are completed by chelating ligands. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
6.
A simple experimental approach was developed to determine the adhesion rate of particles onto massive substrate. Turbidimetry measurements are used to follow the evolution of particle concentration in a suspension in dynamic contact with the walls of a vessel made of different materials. This method allows to rapidly obtain qualitative results about the adhesion of metallic oxides particles on massive substrates. Adhesion of particles of charged latex onto glass was used to validate the approach and was shown to be a method to determine isoelectric points (IEP) of massive substrates. Then, the adhesion of an iron oxide (hematite) particles onto several substrates was studied to determine the reactivity of current labware (glass, polypropylene) and on a metal (aluminum) commonly found in industrial fouling problems. Adhesion of hematite was found to be pH-dependant, and occurs only below ca. 6 (glass) or 7 (polypropylene), and above 7 (aluminum). DLVO calculations were performed to model the hematite/water/glass system and are consistent with the experimental results. Experiments at temperature 7–50 °C have shown an increasing of the adhesion rate from 7 to 40 °C, then a constant value until 50 °C.  相似文献   
7.
8.
In this work, some results related to superatomic Boolean interval algebras are presented, and proved in a topological way. Let x be an uncountable cardinal. To each I x, we can associate a superatomic interval Boolean algebra B I of cardinality x in such a way that the following properties are equivalent: (i) I I x, (ii) B I is a quotient algebra of B J, and (iii) there is an homomorphism f from B J into B I such that for every atom b of B I, there is an atom a of B J satisfying f(a)=b. As a corollary, there are 2 x isomorphism types of superatomic interval Boolean algebras of cardinality x. This case is quite different from the countable one.  相似文献   
9.
The Carbo(3-phenylpyrazol-5-yl-hydrazonoyl) halides 1a , b react with active methylene compounds to yield the 1-(3-phenylpyrazol-5-yl)-pyrazole derivatives 2a – k (Scheme 1). The acyclic intermediates 3a , b could be isolated from reaction of 1a , b with acetylacetone, thus establishing the substitution mechanism for these reactions. Compounds 1a , b reacted with carbon disulfide, phenyl isothiocyanate, methyl cyanide, and with p-chlorobenzaldehyde to yield the corresponding heterocyclic derivatives 5 – 8 , respectively (Scheme 2). The behaviour of compounds 2 with hydrazine hydrate is reported.  相似文献   
10.
In the present paper, we study the Cauchy problem in a Banach spaceE for an abstract nonlinear differential equation of form $$\frac{{d^2 u}}{{dt^2 }} = - A\frac{{du}}{{dt}} + B(t)u + f(t,W)$$ whereW = (A 1(t)u,A 2(t)u,?,A ?(t)u), (A i (t),i = 1, 2, ?,?), (B(t),tI = [0,b]) are families of closed operators defined on dense sets inE intoE, f is a given abstract nonlinear function onI ×E ? intoE and ?A is a closed linear operator defined on dense set inE intoE, which generates a semi-group. Further, the existence and uniqueness of the solution of the considered Cauchy problem is studied for a wide class of the families (A i(t),i = 1, 2, ?,?), (B(t),tI). An application and some properties are also given for the theory of partial diferential equations.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号