制备方法对Al2O3掺杂Pt/WO3-ZrO2催化剂上正庚烷异构化反应的影响

采用恒pH法和非恒pH法制备了Al₂O₃掺杂的Pt/WO₃/ZrO₂催化剂,并用N₂吸附-脱附、X射线衍射、紫外-可见漫反射、CO化学吸附、X射线光电子能谱、²⁷Al魔角旋转核磁共振和吡啶吸附红外等技术对催化剂进行了表征.结果表明,相比于非恒pH法制备的催化剂,恒pH法制备的催化剂具有较高的比表面积和Pt分散度,在H₂气氛中产生更多的B酸位,从而表现出更高的催化正庚烷临氢异构化反应活性; 在200℃和质量空速0.9h^-1的反应条件下,正庚烷转化率达70.0%,明显高于非恒pH法制备的催化剂(43.5%).     

气相色谱-三重四极杆串联质谱法快速测定蔬菜水果中129种农药的残留量

采用QuEChERS方法结合气相色谱-串联质谱法(GC-MS/MS)建立了蔬菜、水果中129种农药残留同时检测的分析方法。试样用1%乙酸乙腈均质提取,采用混合型固相分散萃取剂净化后,用GC-MS/MS在多反应离子监测(MRM)模式下进行检测,外标法定量。结果表明,129种药物在一定的含量范围内线性关系良好,相关系数(r2)均大于0.98;不同基质在10 μg/kg添加水平下大部分农药的平均回收率为66.2%～124.7%,相对标准偏差(RSD)为0.9%～24.4%;方法的定量限(LOQ)为0.03～16.7 μg/kg。结果表明,该方法简便快速、灵敏可靠、经济有效,适用于蔬菜、水果中农药多残留的同时快速筛查测定。     

重离子治癌引出BUMP电源控制器设计

引出凸轨(BUMP)电源是负责医用重离子加速器束流引出的关键设备,其电流上升的同步性影响束流的引出效率,而电流波形的多样性与治疗模式和治疗精度密切相关.要在凸轨磁铁(0.2～0.4 mH)上产生1～5 ms上升且精确同步的励磁电流,并确保电流的跟踪性和波形的多样性,采用了实时调整强励电压及基于特征参数的电流波形控制方法...     

压缩感知在宽带声学多普勒测速技术中的应用

为降低宽带声学多普勒测速技术中宽带回波信号处理系统的采样和数据存储压力,研究了压缩感知的回波信号重构算法,并将其应用于宽带声学多普勒测速的回波信号分析中.在点回波模型下进行宽带回波信号的仿真实验,利用复协方差法计算频移.仿真实验结果表明,在无噪声的理想条件下,利用压缩感知理论处理宽带多普勒测速的回波信号,能够达到理想的...     

Linearly constrained global optimization via piecewise-linear approximation

This paper considers the problem of optimizing a continuous nonlinear objective function subject to linear constraints via a piecewise-linear approximation. A systematic approach is proposed, which uses a lattice piecewise-linear model to approximate the nonlinear objective function on a simplicial partition and determines an approximately globally optimal solution by solving a set of standard linear programs. The new approach is applicable to any continuous objective function rather than to separable ones only and could be useful to treat more complex nonlinear problems. A numerical example is given to illustrate the practicability.     

Stochastic Order and Generalized Weighted Mean Invariance

In this paper, we present order invariance theoretical results for weighted quasi-arithmetic means of a monotonic series of numbers. The quasi-arithmetic mean, or Kolmogorov–Nagumo mean, generalizes the classical mean and appears in many disciplines, from information theory to physics, from economics to traffic flow. Stochastic orders are defined on weights (or equivalently, discrete probability distributions). They were introduced to study risk in economics and decision theory, and recently have found utility in Monte Carlo techniques and in image processing. We show in this paper that, if two distributions of weights are ordered under first stochastic order, then for any monotonic series of numbers their weighted quasi-arithmetic means share the same order. This means for instance that arithmetic and harmonic mean for two different distributions of weights always have to be aligned if the weights are stochastically ordered, this is, either both means increase or both decrease. We explore the invariance properties when convex (concave) functions define both the quasi-arithmetic mean and the series of numbers, we show its relationship with increasing concave order and increasing convex order, and we observe the important role played by a new defined mirror property of stochastic orders. We also give some applications to entropy and cross-entropy and present an example of multiple importance sampling Monte Carlo technique that illustrates the usefulness and transversality of our approach. Invariance theorems are useful when a system is represented by a set of quasi-arithmetic means and we want to change the distribution of weights so that all means evolve in the same direction.     

优化设计理论在抗滑桩工程中的应用

采用数学规划方法中的直接最优化方法———复合形法,对已知荷载或内力的抗滑桩,以结构成本为目标函数进行满足工程使用要求的有约束最优化设计,编制了相应的程序,并用VisualBasic6 .0开发了应用程序界面,将优化以后所得结果与使用传统设计方法结果比较,有较大降低结构成本的效果。     

应用增量理论考虑应变硬化效应包辛格效应和温度对机械性质影响的自增强厚壁圆筒分析

本文提出的采用增量理论的分析模型和方法可以定量分析应变硬化、包辛格效应和材料机械性质随温度变化等因素对自增强厚壁圆筒中残余应力和操作应力分布的影响.厚壁圆筒看成由N个同轴薄壁圆筒套在一起组成的构件;采用包括弹性、塑性和温度应变的增量型本构关系和相容条件导出了自增强圆筒的基本方程;设计了计算机程序并给出了分析实例。分析结果表明,应变硬化会减小塑性区并降低残余应力;包辛格效应使反向屈服容易出现;温度升高将使残余应力和热应力松驰.     

MDD函数在单机总误工排序问题中的作用

本文把工件的修正工期（MDD：Modified Due Date）看成工件关于时间的函数，通过研究该函数在一定区间的性质建立了一个具有全局意义的定理，利用这个定理可以方便地导出有关单机总误工排序问题的一些重要结论．这些工作既能够很好地解释常用的MI）D规则的有效性，同时也说明MDD函数可以成为解决单机总误工排序问题的基本工具．