An efficient synthesis and cytotoxic activity of 2‐(4‐chlorophenyl)‐1H–benzo[d]imidazole obtained using a magnetically recyclable Fe3O4 nanocatalyst‐mediated white tea extract

A simple and efficient procedure has been developed for the synthesis of biologically relevant 2‐substituted benzimidazoles through a one‐pot condensation of o‐phenylenediamines with aryl aldehydes catalysed by iron oxide magnetic nanoparticles (Fe₃O₄ MNPs) in short reaction times with excellent yields. In the present study, Fe₃O₄ MNPs synthesized in a green manner using aqueous extract of white tea (Camelia sinensis) (Wt‐Fe₃O₄ MNPs) were applied as a magnetically separable heterogeneous nanocatalyst to synthesize 2‐(4‐chlorophenyl)‐1H–benzo[d]imidazole which has potential application in pharmacology and biological systems. Fourier transform infrared and NMR spectroscopies were used to characterize the 2‐(4‐chlorophenyl)‐1H–benzo[d]imidazole. In vitro cytotoxicity studies on MOLT‐4 cells showed a dose‐dependent toxicity with non‐toxic effect of 2‐(4‐chlorophenyl)‐1H–benzo[d]imidazole, up to a concentration of 0.147 µM. The green synthesized Wt‐Fe₃O₄ MNPs as recyclable nanocatalyst could be used for further research on the synthesis of therapeutic materials, particularly in nanomedicine, to assist in the treatment of cancer.     

Two criteria to check whether ideals are direct sums of cyclically presented modules

A famous theorem of commutative algebra due to I. M. Isaacs states that “if every prime ideal of R is principal, then every ideal of R is principal”. Therefore, a natural question of this sort is “whether the same is true if one weakens this condition and studies rings in which ideals are direct sums of cyclically presented modules?” The goal of this paper is to answer this question in the case R is a commutative local ring. We obtain an analogue of Isaacs's theorem. In fact, we give two criteria to check whether every ideal of a commutative local ring R is a direct sum of cyclically presented modules, it suffices to test only the prime ideals or structure of the maximal ideal of R. As a consequence, we obtain: if R is a commutative local ring such that every prime ideal of R is a direct sum of cyclically presented R-modules, then R is a Noetherian ring. Finally, we describe the ideal structure of commutative local rings in which every ideal of R is a direct sum of cyclically presented R-modules.     

Structure and Mechanical Properties of 50/50 NR/SBR Blend/Pristine Clay Nanocomposites

A blend/clay nanocomposites of 50/50 (wt%) NR/SBR was prepared via mixing the latex of a 50/50 NR/SBR blend with an aqueous clay dispersion and co‐coagulating the mixture. The structure of the nanocomposite was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Nanocomposites containing less than 10 phr clay showed a fully exfoliated structure. After increasing the clay content to 10 phr, both nonexfoliated (stacked layers) and exfoliated structures were observed in the nanocomposites. The results of mechanical tests showed that the nanocomposites presented better mechanical properties than clay‐free NR/SBR blend vulcanizate. Furthermore, tensile strength, tensile strain at break, and hardness (shore A) increased with increasing clay content, up to 6 phr, and then remained almost constant.     

On FC-Purity and I-Purity of Modules and Köthe Rings

In this article, several characterizations of certain classes of rings via FC-purity and I-purity are considered. Among others results, it is shown that every I-pure injective left R-module is projective if and only if every FC-pure projective left R-module is injective, if and only if, R is a semisimple ring. In particular, the structures of FC-pure projective and I-pure projective modules over a left Artinian ring are completely described. Also, it is shown that every left R-module is FC-pure projective if and only if every indecomposable left R-module is a finitely presented cyclic R-module, if and only if, R is a left Köthe ring. Finally, we introduce FC-pure flatness and I-pure flatness of modules and several characterizations of these notions are given. In particular, we show that a commutative ring R is quasi-Frobenius if and only if R is an Artinian ring and I-pure injective, if and only if, R is an Artinian ring and the injective envelope E(R) is an FC-pure projective R-module.     

Optimal domain decomposition via -median methodology using ACO and hybrid ACGA

In this paper an efficient method is developed for decomposing large-scale finite element meshes. A weighted incidence graph is used to transform the connectivity properties of finite element models into those of graphs. A graph G_c of manageable size is obtained from the main graph model by a coarsening algorithm. The p-medians of this graph are selected using two approaches. The first algorithm uses an ant colony optimization and the second algorithm employs a hybrid ant colony together with genetic algorithm. Here, p is the number of subdomains which the finite element meshes is intended to be decomposed. Once the medians are obtained, the nodes in G_c associated with each median are selected. In an expansion process, the nodes of the subdomains in G are obtained. The capabilities of both ant colony optimization, and hybrid ant colony and genetic algorithm are evaluated using many examples of different topology.     

Commutative Local Rings Whose Ideals are Direct Sums of Cyclic Modules

A well-known result of Köthe and Cohen-Kaplansky states that a commutative ring R has the property that every R-module is a direct sum of cyclic modules if and only if R is an Artinian principal ideal ring. This motivated us to study commutative rings for which every ideal is a direct sum of cyclic modules. Recently, in Behboodi et al. Commutative Noetherian local rings whose ideals are direct sums of cyclic modules (J. Algebra 345:257–265, 2011) the authors considered this question in the context of finite direct products of commutative Noetherian local rings. In this paper, we continue their study by dropping the Noetherian condition.     

Character Connes-amenability of dual Banach algebras

The concept of left character Connes-amenability for a dual Banach algebra \({\mathcal {A}}\) is introduced. We obtain a cohomological characterization of left character Connes-amenability as well as the relation between left \(\varphi \)-Connes-amenability and existence of left \(\varphi \)-normal virtual diagonals for a \(\omega ^{*}\)-continuous character \(\varphi \). We prove that left character amenability of \({\mathcal {A}}\) is equivalent to left character Connes-amenability of \({\mathcal {A}}^{**}\) when \({\mathcal {A}}\) is Arens regular. Moreover for a locally compact group G, we show that M(G) is left character Connes-amenable. In addition by means of some examples we show that for the new notion, the corresponding class of dual Banach algebras is larger than Connes-amenable dual Banach algebras.     

The study of thiazole adsorption upon BC2N nanotube: DFT/TD-DFT investigation

Structural Chemistry - Herein, we evaluated the adsorption of thiazole over the surface of BC2N nanotube using PBE and M06-2X functionals and 6-311G** standard basis set. We considered one and two...     

Interpretation of Rotation Curves of Spiral Galaxies in Modified Teleparallel Gravity

There is a significant difference between the calculation based on the theory of general relativity and observation of rotation curves of spiral galaxies. To describe this discrepancy, two distinct theories have been proposed so far： existence of dark matter and modification of underlying gravitational theory. In the absence of dark matter, it is assumed that the theory of general relativity on galactic scales needs to be modified. This letter is devoted to explaining this difference in a modified teleparMIeI gravity. We show that modified teleparallel gravity favors flatness of rotation curves of spiral galaxies much in the same way as observation shows.     

C-Pure Projective Modules

This paper investigates the structure of cyclically pure (or C-pure) projective modules. In particular, it is shown that a ring R is left Noetherian if and only if every C-pure projective left R-module is pure projective. Also, over a left hereditary Noetherian ring R, a left R-module M is C-pure projective if and only if M = N ⊕ P, where N is a direct sum of cyclic modules and P is a projective left R-module. The relationship C-purity with purity and RD-purity are also studied. It is shown that if R is a local duo-ring, then the C-pure projective left R-modules and the pure projective left R-modules coincide if and only if R is a principal ideal ring. If R is a left perfect duo-ring, then the C-pure projective left R-modules and the pure projective left R-modules coincide if and only if R is left Köthe (i.e., every left R-module is a direct sum of cyclic modules). Also, it is shown that for a ring R, if every C-pure projective left R-module is RD-projective, then R is left Noetherian, every p-injective left R-module is injective and every p-flat right R-module is flat. Finally, it is shown that if R is a left p.p-ring and every C-pure projective left R-module is RD-projective, then R is left Noetherian hereditary. The converse is also true when R is commutative, but it does not hold in the noncommutative case.