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1.
Akira Yanagisawa Prof. Dr. Takahiro Suzuki Takanori Koide Shogo Okitsu Takayoshi Arai Prof. Dr. 《化学:亚洲杂志》2008,3(10):1793-1800
A Barbier‐type regioselective propargylation of aldehydes and ketones with (3‐bromobut‐1‐ynyl)trimethylsilane has been achieved using reactive barium as a low‐valent metal in THF. Especially in the case of ketones, the corresponding homopropargylic alcohols form almost exclusively. In the reaction of α,β‐unsaturated carbonyl compounds, only 1,2‐adducts have been observed. This method is also applicable to propargylation of imines, and the corresponding homopropargylic amines are obtained regiospecifically in good yields with diastereomeric ratios of up to 87:13. 相似文献
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Synthesis and structures of the title compounds 2a–d are described. In spite of non-parallel orientation of the two base rings, fairly large hypochromism was observed for 2a–d. 相似文献
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Akitomo Tachibana Yoshihiro Asai Shogo Ikeuchi Shigeru Ishikawa Tokio Yamabe 《Theoretical chemistry accounts》1990,78(1):1-9
Summary The vibronic character of this molecular device has been studied using isomorphic electron orbitals. The leading role of the softest vibrational mode for the electron transport process is stressed by the quantum mechanical treatment of the rearrangement operator. The theory was used to investigate the possible function of the soliton valve, which has been suggested as a switching tip. The electronic flexibility of the cyclopropenyl radical with respect to molecular vibrations, which is important for the function of the molecular device, is well characterized by the hardness and softness of the electron structure in terms of the orbital energy-occupation number correlation diagram. 相似文献
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Makoto Minato Takefumi Kaneko Shogo Masauji Takashi Ito 《Journal of organometallic chemistry》2006,691(11):2483-2488
We describe the synthesis of a new asymmetric P,N,N′-tridentate ligand (bis(pyrid-2-ylethyl) menthylphosphine, BPEMP), containing two pyridyl rings and (1S,2R,5S)-menthylphosphino group. The ligand is obtained in five steps from natural abundant l-menthol. The coordination behavior of the ligand toward cationic (allylic)Pd(II) moiety and its first application in palladium-catalyzed asymmetric allylic alkylation are presented. Crystallographic and spectroscopic analyses reveal that [(η3-allylic)Pd(BPEMP)]+ complex forms only one isomer in the solid state as well as in solution. 相似文献
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We have developed a Cd2+ fluorescent chemosensor with high selectivity as well as sensitivity by tethering a 4,7-bis(2-hydroxyethyl)-9-hydroxy-1,4,7-triazanonyl chelator to anthracene. This sensor features the ability to discriminate Cd2+ from Zn2+ to a high degree (KdZn/KdCd = 560) in a pH 7.2 buffer. 相似文献
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This paper presents an evaluation method for measuring the sound pressure level and mode shapes of tire cavity resonance by using a multi-microphone system. Two commercial tires were evaluated to compare abilities of noise suppression by means of this method in the range of the first resonance from 200 to 260 Hz. One tire was a special tire that suppresses tire cavity resonance with polyurethane foam mounted on the tire’s inner liner. The other tire was a normal tire with no polyurethane foam. The mode shape change from vertical to horizontal direction in both tires. However, the sound pressure level of the special tire was lower than the normal tire at all frequencies. 相似文献
10.
The formation of carbon-carbon bond by sulfur extrusion such as pyrolysis of cyclic sulfones is well known as an important synthetic method, especially for the synthesis of cyclophane framework.1) Little is known about selenium extrusion as the counterpart, though organoseleniums have been properly appreciated as a useful tool for manipulating a functional group.2) Lardon reported that the thermal decomposition of dibenzyl diselenide led to a mixture of dibenzyl selenide and polyselenides.3) In contrast, recent reports showed that at 210°C, heating bis(diphenylmethyl) diselenide resulted in ready selenium extrusion to 1,1,2,2-tetraphenylethane4), and dianthrylmethyl mono- and diselenides to 1,2-dianthrylethane.5) Therefore,- it is worthwhile to study the thermal behavior of dibenzyl selenide itself. 相似文献