排序方式: 共有19条查询结果,搜索用时 15 毫秒
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This report focuses on a theoretical study of the cobalt-cabon bond activation mechanism in Vitamin B12, its co enzyme complexes, and model compounds such as cobalamins (Cbl), cobaloximes and cobalt porphyrins. In particular, emphasis is placed on the nucleotide loop and its role in the base on and base off mechanism. 相似文献
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应用程序电位扫描法和电化学原位FTIR反射光谱从定量角度在分子水平 上研究了CO2在Rh电极上的电催化还原性能。红外光谱结果指出CO2还原的吸附产物为线型和桥式吸附态CO物种。在所研究和还原电位范围(-0.15-0.40V)和相同还原时间,CO2还原吸附物种的氧化电量随还原电位的负移而增大,在每个还原电位下,时间超过250s时都可达到一个相应的饱和值。原位红外光谱和电化学研究结果表明,CO2的还原与Rh电极表面氢吸附反应密切相关,同时需要一定数量相邻表面位的参与。因此生成的CO不能在Rh电极表面达到满单层吸附,而是形成均匀的亚单层分布。 相似文献
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NO在Er2O3/Bi2O3催化剂上的程序升温分解 总被引:3,自引:0,他引:3
NOx是造成大气污染的化学物质之一,因此,消除NOx是环境保护的一项重要任务,目前比较成熟的消除NOx工艺是用氨为还原剂和V2O5/TiO2为催化剂的选择催化还原(SCR)法[1],但其成本过高. 相似文献
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A simple 10 ps KrF laser system consisting of quenched dye laser oscillator pumped by a XeCl laser, a distributed feedback dye laser (DFDL), a three-stage dye amplifier and a two-stage KrF amplifier are described. The output of the laser system is 140 mJ with 10 ps pulse width by using polarization-multiplexing amplification. A focused output laser intensity of about 4×1015 W/cm2 is obtained. The saturation fluence for KrF laser is obtained with this laser. 相似文献
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A GROUP OF EXACT (3+1) DIMENSIONAL CYLINDRICALLY SYMMETRIC WAVE SOLUTIONS TO THE EINSTEIN GRAVITATIONAL FIELD EQUATION
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Starting with the diagonal spacetime metric tensor, the Einstein gravitational field equation is solved, and a set of exact (3+1) dimensional cylindrically symmetric wave solutions with two arbitrary functions are found. In these solutions all nonvanishing components of spacetime metric tensor are varying with the same propagating factor (ct-z) while the waves are travelling along z axis. The physical picture and the condition of positive energy density of the wave solutions are discussed. 相似文献
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La2NiO4/Al2O3催化剂上CH4/CO2的重整 总被引:8,自引:1,他引:8
通过溶胶-凝胶方法制备了尖晶石结构的La2NiO4/Al2O3催化剂,采用BET,XRD和TG表征了催化剂的孔分布、比表面积、体相组成以及凝胶样品的热失重和热分解过程.将催化剂应用于CH4/CO2重整反应制合成气,考察了惰性气体和反应温度对转化率、选择性以及积碳的影响.结果表明,在高空速(GHSV=4.8×104ml/(g·h))下,CH4和CO2转化率分别为51%和60%,CO和H2的选择性约为98%和92%,惰性气体He的引入明显地提高了CH4和CO2的转化率. 相似文献
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STRUCTURAL DAMAGE DETECTION BASED ON A MICRO-GENETIC ALGORITHM USING INCOMPLETE AND NOISY MODAL TEST DATA 总被引:2,自引:0,他引:2
This paper describes a procedure for detecting structural damage based on a micro-genetic algorithm using incomplete and noisy modal test data. As the number of sensors used to measure modal data is normally small when compared with the degrees of freedom of the finite element model of the structure, the incomplete mode shape data are first expanded to match with all degrees of freedom of the finite element model under consideration. The elemental energy quotient difference is then employed to locate the damage domain approximately. Finally, a micro-genetic algorithm is used to quantify the damage extent by minimizing the errors between the measured data and numerical results. The process may be either of single-level or implemented through two-level search strategies. The study has covered the use of frequencies only and the combined use of both frequencies and mode shapes. The proposed method is applied to a single-span simply supported beam and a three-span continuous beam with multiple damage locations. In the study, the modal test data are simulated numerically using the finite element method. The measurement errors of modal data are simulated by superimposing random noise with appropriate magnitudes. The effectiveness of using frequencies and both frequencies and mode shapes as the data for quantification of damage extent are examined. The effects of incomplete and noisy modal test data on the accuracy of damage detection are also discussed. 相似文献
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IntroductionTheutilizationofalkanetoproduceintermediatechemicalsisalwaysatractive.Thefunctionalizationoflightparafinbycatalyt... 相似文献