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1.
The electronic effect on the regioselectivity in the alkynylation of phenyloxiranes was investigated using three kinds of metal acetylides. BF3 mediated lithium acetylide provided either the α- or β-alkynylated products by controlling the effect of the para-substituents of the phenyloxiranes. LiClO4 mediated lithium acetylide and titanium acetylide, on the other hand, afforded predominantly the β- and α-products, respectively. 相似文献
2.
Takaki K Itono Y Nagafuji A Naito Y Shishido T Takehira K Makioka Y Taniguchi Y Fujiwara Y 《The Journal of organic chemistry》2000,65(2):475-481
Three-component coupling of acylphosphonates and two carbonyl compounds leading to beta-hydroxyphosphonates has been achieved with low-valent samariums. Thus, acylphosphonates reacted with aldehydes in the presence of semicatalytic amounts of samarium metal or SmI(2) to give acyloxyphosphonates in good yields. The second coupling reaction of the acyloxyphosphonates with aldehydes or ketones promoted by SmI(2) afforded beta-hydroxyphosphonates instead of olefins. Moreover, these two reactions could be carried out in one pot. 相似文献
3.
Electrolytic coupling reaction of laudanosine (1) gave the O-methylflavinantine (II). N-Ethoxycarbonylated dihydrostilbene (IVa) gave a rearranged dienone (Va) and N-trifluoro-acetylated dihydrostilbene (IVb) contrastively gave an unrearranged dienone (Vb). 相似文献
4.
5.
Shindo M Yoshikawa T Itou Y Mori S Nishii T Shishido K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,12(2):524-536
Ynolates were found to react with alpha-alkoxy-, alpha-siloxy-, and alpha-aryloxyketones at room temperature to afford tetrasubstituted olefins with high Z selectivity. Since the geometrical selectivity was determined in the ring opening of the beta-lactone enolate intermediates, the torquoselectivity was controlled by the ethereal oxygen atoms. From experimental and theoretical studies, the high Z selectivity is induced by orbital and steric interactions rather than by chelation. In a similar manner, alpha-dialkylamino ketones provided olefins with excellent Z selectivity. These products can be easily converted into multisubstituted butenolides and gamma-butyrolactams in good yield. 相似文献
6.
Masaoki Oku Toetsu Shishido Takeshi Shinohara Qiang Sun Yoshiyuki Kawazoe Kazuo Nakajima Kazuaki Wagatsuma 《Journal of solid state chemistry》2004,177(2):457-460
The solid solutions of ScBRh3-ScRh3 and CeBRh3-CeRh3 are synthesized by the arc melting method, where RBRh3 and RRh3 (R=rare earth element) have perovskite and AuCu3 type structures, respectively. The binding energy of Sc 2p3/2 for ScBxRh3 increases with the boron concentration. The Knight shift of 45Sc observed by nuclear magnetic resonance spectroscopy decreases with increase of boron concentration. The decrement of the Knight shift corresponds the Sc 4s electron density at the Fermi level. The intensity ratio of f2: f1: f0 of Ce 3d XPS spectrum changes with boron concentration of CeBxRh3. It is concluded that in both cases of ScBxRh3 and CeBxRh3 the charge on the atoms on A-site changes with the concentration of the atoms on B-site, where the atoms are not directly bound. 相似文献
7.
N-Heterocyclic carbene-catalyzed transformation of 4-formylbenzoates and α,β-unsaturated aldehydes to cyclic hemiacetals is described. The reaction proceeded smoothly when the sulfopropyl-substituted imidazolium salt was used as the catalyst. Various substrates were converted to the corresponding cyclic hemiacetals in a stereoselective manner. 相似文献
8.
9.
Izawa K Yamaguchi H Matsuda Y Shishido H Settai R Onuki Y 《Physical review letters》2001,87(5):057002
The thermal conductivity of the heavy-fermion superconductor CeCoIn5 has been studied in a magnetic field rotating within the 2D planes. A clear fourfold symmetry of the thermal conductivity which is characteristic of a superconducting gap with nodes along the ( +/- pi,+/- pi) directions is resolved. The thermal conductivity measurement also reveals a first-order transition at H(c2), indicating a Pauli limited superconducting state. These results indicate that the symmetry most likely belongs to d(x(2)-y(2)), implying that the anisotropic antiferromagnetic fluctuation is relevant to the superconductivity. 相似文献
10.
All-optical image processing by means of a photosensitive nonlinear liquid-crystal film: edge enhancement and image addition-subtraction 总被引:4,自引:0,他引:4
We demonstrate two simple yet efficient all-optical image-processing techniques that use nonlinear photosensitive dye-doped nematic liquid-crystal films, namely, edge enhancement and image addition-subtraction operations. These films require no external bias and function at much lower optical powers and shorter response times than other conventional methods. 相似文献