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1.
Hiroto Kudo Nobuhito Ito Keiji Nakajima Masami Ochiai Tadatomi Nishikubo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4421-4429
The polyaddition of fluorine‐containing bis(epoxide)s and fluorine‐containing triazine di(aryl ether)s were examined to give the corresponding fluorine‐containing poly(cyanurate)s. It was observed that the synthesized fluoropolymers had good thermal stabilities and good film‐forming properties. The glass transition temperatures (Tg's) and refractive‐indices (nD's) of synthesized polymers were determined by differential scanning calorimetry and ellipsometry, respectively, and it was found that the values of Tg's and nD's were supported by their fluorine containing ratios and skeletons. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4421–4429, 2007 相似文献
2.
Investigation of one step synthesis of 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals has been carried out using versatile aldehydes, tri- or di-fluoroacetaldehyde ethyl hemiacetal in the presence of diethylaminotrimethylsilane (DEATMS) in an ionic liquid, and it was demonstrated that this route enabled us to successfully construct 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals with the high level selectivity of geometric isomers. 相似文献
3.
Yoshio Moriya Shinichi Nakata Hirotaka Morimoto Nobuaki Ogawa 《Analytical sciences》2004,20(11):1533-1536
Analysis by reflection spectrometry was performed to clarify the interfacial adsorption of protonated lipophilic tetraphenylporphyrin derivatives in a dodecane-aqueous sulfuric acid system, and to confirm the utility of partial reflection spectroscopy. Interfacial adsorption was not observed for porphyrins substituted at the 2,6 positions of meso-phenyl groups, suggesting that the substituents prevent porphyrins from forming aggregates by steric hindrance. Polymorphous J-aggregates of acid dications were produced by tetra-p-tolylporphyrin with a saturated interfacial molecular density of 1.0 x 10(-10) mol cm(-2), which could yield 48 degrees as a mean tilting angle of the pyrrole ring plane from the interface normal. Partial-reflection spectrometry can provide sensitive detection and molecular orientation analysis of interfacial adsorbates. 相似文献
4.
T. Mihara K. Miyamoto M. Kida T. Sasaki N. Aoki Y. Ochiai 《Superlattices and Microstructures》2003,34(3-6):383
A multiwall carbon nanotube crossroads has been fabricated by a manipulation technique using a glass microcapillary, and the low temperature transport properties investigated. The two-terminal conductance of an individual tube shows Tomonaga–Luttinger liquid behavior G∝Tα at high temperature and dI/dV ∝V α at low temperature. However, no evidence of such a power-law behavior is obtained in the four-terminal conductance at the junction, where the conductance shows an almost metallic behavior ‘corrected’ by weak localization. Weak localization would essentially appear in electron states at the junctions of MWNTs. 相似文献
5.
The propagation characteristics of shear horizontally polarized (SH) waves passing through (Ni42Nb28Zr30)100–x Hx (x = 0–15.2) glassy alloys were investigated as a function of hydrogen content. With an increase in hydrogen content, the propagation time and main frequency of the receiving waves show increase and decrease, respectively, indicating expan‐ sion in average atomic distance which comes from solution of hydrogen. In sharp contrast to crystalline alloys, the decrease in damping ratio and the delay in phase with increasing hydrogen suggest a strong settlement of hydrogen into four‐coordination sites surrounded tetrahedrally by four Zr atoms and the resulting increase in dynamic elasticity, respectively. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
6.
Hisatoyo Morinaga Bungo Ochiai Hideharu Mori Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(5):736-744
Natural human hair was successfully modified by the graft polymerization of trimethylene carbonate, β‐propiolactone, ε‐caprolactone, glycidol, ε‐caprolactam, and 5,5‐dimethyl‐1,3‐dioxane‐2‐thione. In contrast, we could not modify natural human hair by the graft polymerization of oxetane under similar conditions. The model reaction suggested that the main initiating species in these polymerizations were the amino, thiol, and hydroxyl groups in hair, which could induce ring‐opening polymerization. Among the tested monomers, β‐propiolactone was most effective for hair modification with its graft polymer, whose concentration was as high as 0.5 g/g of hair though polymerization under mild conditions. The effects of the hair pretreatment and polymerization temperature on the weight ratio of the grafted polymers were also investigated. Hair modified by grafted polymers was characterized with scanning electron microscopy and Fourier transform infrared measurements. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 736–744, 2007 相似文献
7.
Ozao R. Yoshida H. Inada T. Ochiai M. 《Journal of Thermal Analysis and Calorimetry》2003,72(1):113-118
Nanoporous alumina membrane prepared by anodic oxidation using sulfuric acid electrolyte was subjected to TG-DTA and X-ray
Photoelectron Spectroscopy (XPS or ESCA) to further study the distribution of sulfur. In XPS study, Ar+ ion bombardment was performed on the sample to etch the surface at a rate of 3 nm min-1. As a result, sulfur was found to be concentrated within a depth of 3nm from the surface. The S content of the surface was
found to be 2.7±0.5 wt%, and that at a depth of ca. 3 nm and ca. 10 nm was found to be as low as about 0.6±0.11 wt% (5.37±1.0
wt%→ 1.26±0.2wt% SO2). In TG-DTA, the mass loss of 7.3% was in fair agreement with that calculated on XPS results (7.1±1.2%).
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
8.
Hatsuo Yamamura Kousuke Satake Rieko Hirasawa Shinichi Yamada Masao Kawai 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):261-264
A novel cyclodextrin (CD) dimer linked with a bis(picolinyl)cystine (Cys) moiety was prepared by the coupling of Boc-protected
Cys with amino-modified CDs, followed by deprotection of the Boc groups and bispicolinylation. The dimer showed less affinity
to an organic guest molecule compared to that of a native CD monomer. It was attributed to an intramolecular inclusion of
the pyridine moiety into CD cavity. The dimer caused significant increase of its organic guest affinity by an addition of
a copper ion. The included pyridine group may come out of a CD cavity to bind the copper ion and the two CDs included cooperatively
and intermolecularly a guest molecule with high affinity. 相似文献
9.
Makoto Kume Atsunori Hirano Bungo Ochiai Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3666-3673
A spiro orthoester with an exomethylene group (exoSOE) was radically copolymerized with acrylonitrile or vinyl acetate at several feed ratios to obtain the corresponding copolymers having spiro orthoester moieties in the side chain. The obtained copolymers could be crosslinked via the double ring‐opening polymerization of the spiro orthoester moieties in their side chain by a treatment with BF3OEt2. The volume changes upon the crosslinking of the copolymers were evaluated by density measurements with a micromeritics gas pycnometer. The copolymers experienced less than 1% volume expansion instead of volume shrinkage during typical cationic crosslinking, regardless of the copolymer compositions. Negligible shrinkage was observed during the thermal cationic crosslinking of a film cast from a nitrobenzene solution of the copolymers containing a benzylthiophenium salt as a thermally latent cationic initiator. The constantly low volume changes during the crosslinking of the copolymers from exoSOE probably depended on the almost zero volume change during the cationic polymerizations of spiro orthoester derivatives. This indicates that exoSOE is an effective monomer for crosslinkable polymers without volume changes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3666–3673, 2006 相似文献
10.
Hisatoyo Morinaga Bungo Ochiai Hideharu Mori Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2006,44(12):3778-3786
Natural human hair was modified by the graft polymerization of propylene sulfide in an aqueous medium. The amount of the polymer grafted onto the reduced hair was 0.15–0.19 g on 1.0 g of hair. The grafted polymer was isolated by the hydrolysis of the hair in the polymer‐grafted hair under basic conditions and was confirmed to be poly(propylene sulfide) by 1H NMR, 13C NMR, and Fourier transform infrared spectra. The number‐average molecular weights of the isolated polymers from the grafted products were 10,000–12,000. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3778–3786, 2006 相似文献