全文获取类型
收费全文 | 93篇 |
免费 | 0篇 |
专业分类
化学 | 77篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 5篇 |
物理学 | 9篇 |
出版年
2024年 | 1篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 7篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 4篇 |
2012年 | 3篇 |
2011年 | 2篇 |
2010年 | 4篇 |
2009年 | 8篇 |
2008年 | 3篇 |
2007年 | 3篇 |
2006年 | 4篇 |
2005年 | 1篇 |
2004年 | 1篇 |
2003年 | 4篇 |
2002年 | 1篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1996年 | 2篇 |
1990年 | 2篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1963年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有93条查询结果,搜索用时 359 毫秒
1.
2.
O.A. Shilova S.V. Hashkovsky L.A. Kuznetsova 《Journal of Sol-Gel Science and Technology》2003,26(1-3):687-691
The brief review, based on long-term experience of authors on preparation of temperature-resistant electric insulating and optical light-reflecting ceramic coatings on metal surface is offered. The main components of TEOS-, H3PO4- and alkali silicates-derived sols and suspensions for deposition of ceramic coatings are listed. Some features of preparation of the coatings from the sols containing fillers are analysed. Two approaches to improve bending and electrical strength of flexible insulation are developed. The techniques of synthesis of modified fillers for preparing gas-proof and anticorrosive coatings are offered. The wide functional possibility and extensive list of application areas of the coatings and some materials prepared from sols with fillers, including on far prospect are given. 相似文献
3.
V. F. Ivanov D. A. Gordon I. A. Shilova V. A. Lesnichaya A. I. Mikhailov E. Ya. Misochko 《Russian Journal of Applied Chemistry》2016,89(8):1292-1295
New composite lignocellulose materials were prepared using modified lignin and nanocellulose. The materials were studied by elemental and thermal gravimetric analysis, and their tensile tests were performed. The results obtained show that addition of nanocellulose to modified lignin makes possible its use as filler in paper production. 相似文献
4.
The association of chitosan in aqueous-alcohol solutions is studied via probe fluorescence spectroscopy and dynamic light scattering. It is shown that, if a certain critical concentration is reached, the associates of macromolecules 12–38 nm in size are formed in chitosan solutions. The addition of 5–60 vol % ethanol to the solvent leads to reduction in the critical association concentration. The tendency of chitosan macromolecules toward association is the most pronounced at 34 vol % alcohol. 相似文献
5.
O. A. Shilova N. N. Gubanova A. G. Ivanova M. Yu. Arsent’ev V. A. Ukleev 《Russian Journal of Inorganic Chemistry》2017,62(5):645-653
Chemical processes that can occur during aging of sols based on water–alcohol solutions of tetraethoxysilane (TEOS) and hexachloroplatinic acid and during formation of films from these sols are analyzed by the results of visible and UV spectroscopy and X-ray powder diffraction. The sizes and compositions of the platinum particles that are formed in xerogels and in thin films on the nanometer and submicron levels are estimated based on X-ray crystallography, energy dispersive spectral analysis, high-resolution scanning and transmission electron microscopy, and grazing incidence small-angle X-ray scattering studies. 相似文献
6.
7.
Ekaterina A. Shilova Valery P. Perevalov Corinne Moustrou 《Tetrahedron letters》2008,49(21):3453-3457
The novel photochromic [2]rotaxane based on chromene molecule introduced into a crown-containing macrocyclic receptor was synthesized. The photochemical properties of rotaxane could be modified by the complexation of the crown ether moiety. 相似文献
8.
A. I. Mikhailov V. F. Ivanov I. A. Shilova A. A. Kozlovskii V. S. Veselov V. F. Razumov 《High Energy Chemistry》2008,42(4):251-254
The interrelation between the resource-forming and environment-forming functions of the phytosphere, on the one hand, and their consumption by the current civilization, on the other hand, is considered. It was shown that the world technogenic consumption of oxygen in excess of its influx to the atmosphere is 1010 t per annum, the globe average vegetation cover has gradually passed from forest to steppe, and the critical movement from steppe to desert is going now. The ecological-economic harmonization of the consumption of the environment-and resource-forming functions of the forest is needed. 相似文献
9.
Photometric analysis of mixtures by Firordt’s method yields relative errors that do not exceed the specified limits only if
the deviations from additivity at the analytical wavelengths do not exceed (in their numerical value) their own critical values
(δA
crit). These deviations depend on the ratio of component concentrations. By virtue of the analytical geometry technique, we derived
equations for the evaluation of δA
crit. These equations allow one to predict the possibility of the precise determination of two components in a mixture under investigation
at one and the same set of wavelengths. The developed algorithm was verified on 40 model mixtures of organic compounds. 相似文献
10.
Ekaterina A. Shilova Valery P. Perevalov Corinne Moustrou 《Tetrahedron letters》2007,48(23):4127-4130
A convenient new synthetic route to p-aminophenylaminobenzo- and naphthopyrans was developed via palladium-catalyzed C-N coupling. It was demonstrated that novel targeted aminoderivatives reveal photochromic properties. The structure of intermediate p-nitrophenylaminochromenes was confirmed by X-ray crystallographic analysis. 相似文献